METHOD FOR PRODUCING ETHYLENE AMINES AND ETHANOL AMINES BY THE HYDROGENATING AMINATION OF MONOETHYLENE GLYCOL AND AMMONIA IN THE PRESENCE OF A CATALYST
    5.
    发明申请
    METHOD FOR PRODUCING ETHYLENE AMINES AND ETHANOL AMINES BY THE HYDROGENATING AMINATION OF MONOETHYLENE GLYCOL AND AMMONIA IN THE PRESENCE OF A CATALYST 有权
    通过催化剂存在下单乙基甘氨酸和氨基甲酸的加氢胺化生产乙烯胺和乙醇胺的方法

    公开(公告)号:US20090030237A1

    公开(公告)日:2009-01-29

    申请号:US12279215

    申请日:2007-02-08

    IPC分类号: C07C209/14

    摘要: A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein a catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of

    摘要翻译: 一种在催化剂存在下通过单乙酰胺和氨的氢化胺化制备乙烯胺和乙醇胺的方法,其中具有包含钌和钴的活性组合物以及没有另外的另外的第VIII族金属以及也没有IB族金属的催化剂是 使用成形催化剂体的形式,在球形或棒状的情况下,每种情况具有<3mm的直径,在颗粒形状的情况下具有<3mm的高度,并且在全部情况下 每种情况下的其他几何形状具有等效直径L = 1 / a'<0.70mm,其中a'是每单位体积的外表面积(mms2 / mmp3),并且: a ' = 其中Ap是成形催化剂体的外表面面积(mms2),Vp是(mms2),其中Ap是成形催化剂体的外表面积(mms2),Vp是 提出了成形催化剂体的体积(mmp3)。

      Process for Producing Ethyleneamines
      7.
      发明申请
      Process for Producing Ethyleneamines 有权
      生产乙烯胺的方法

      公开(公告)号:US20080255360A1

      公开(公告)日:2008-10-16

      申请号:US12088715

      申请日:2006-09-25

      摘要: Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of

      摘要翻译: 方法包括:提供包含单乙醇胺的原料; 并在非均相过渡金属催化剂的存在下使原料与氨反应形成包含一种或多种亚乙基胺的反应产物; 其中所述催化剂包含催化活性组合物,其在用氢处理之前包括铝,铜,镍和钴的含氧化合物的混合物; 并且其中所述催化剂作为选自球体,挤出物,丸粒和其它几何形状的一种或多种成型催化剂颗粒存在,其中所述球体或挤出物的直径<3mm,所述颗粒具有<3mm的高度,而另一种 几何形状具有等效直径L = 1 / a'<0.70mm,其中a'是每单位体积的外表面积(mm×s×2 / 由 定义的 3 MI> a = A / MSUB> V p 其中A < SUB>是催化剂颗粒的外表面积(mm 2),V p是催化剂颗粒的体积(mm 3) 3&lt; 3&gt; 3&lt; 3&gt;)。

        Process for producing ethyleneamines
        8.
        发明授权
        Process for producing ethyleneamines 有权
        制备亚乙基胺的方法

        公开(公告)号:US07696384B2

        公开(公告)日:2010-04-13

        申请号:US12088715

        申请日:2006-09-25

        IPC分类号: C07C211/00

        摘要: Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of

        摘要翻译: 方法包括:提供包含单乙醇胺的原料; 并在非均相过渡金属催化剂的存在下使原料与氨反应形成包含一种或多种亚乙基胺的反应产物; 其中所述催化剂包含催化活性组合物,其在用氢处理之前包括铝,铜,镍和钴的含氧化合物的混合物; 并且其中所述催化剂作为选自球体,挤出物,丸粒和其它几何形状的一种或多种成型催化剂颗粒存在,其中所述球体或挤出物的直径<3mm,所述颗粒具有<3mm的高度,而另一种 几何形状具有等效直径L = 1 / a'<0.70mm,其中a'是每单位体积的外表面积(mms2 / mmp3),由'= A p V p定义,其中Ap是外表面积 的催化剂颗粒(mms2),Vp是催化剂颗粒的体积(mmp3)。