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1.发明授权Polyether carbonate polyols made via double metal cyanide (DMC) catalysis 有权通过双金属氰化物（DMC）催化制备的聚醚碳酸酯多元醇公开(公告)号：US08134022B2
公开(公告)日：2012-03-13
申请号：US12880231
申请日：2010-09-13
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译： 本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001wt。 ％至约0.2wt。 ％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。 ％至约40wt。 ％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。 本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。
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2.发明授权Polyether carbonate polyols made via double metal cyanide (DMC) catalysis 有权通过双金属氰化物（DMC）催化制备的聚醚碳酸酯多元醇公开(公告)号：US07977501B2
公开(公告)日：2011-07-12
申请号：US11491680
申请日：2006-07-24
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译： 本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001wt。 ％至约0.2wt。 ％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。 ％至约40wt。 ％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。 本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。
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3.发明申请公开(公告)号：US20100331517A1
公开(公告)日：2010-12-30
申请号：US12880231
申请日：2010-09-13
IPC分类号： C08G64/02
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 Wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译： 本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001Wt的存在下。 ％至约0.2wt。 ％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。 ％至约40wt。 ％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。 本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。
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4.发明申请Polyether carbonate polyols made via double metal cyanide (DMC) catalysis 有权通过双金属氰化物（DMC）催化制备的聚醚碳酸酯多元醇公开(公告)号：US20080021154A1
公开(公告)日：2008-01-24
申请号：US11491680
申请日：2006-07-24
IPC分类号： C08G63/48
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译： 本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001wt。 ％至约0.2wt。 ％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。 ％至约40wt。 ％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。 本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。
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公开(公告)号：US5990232A
公开(公告)日：1999-11-23
申请号：US918207
申请日：1997-08-25
CPC分类号： C08G65/2663 , C08G18/4866 , C08G18/633 , C08G18/636 , C08G65/2615 , C08G65/2642 , C08L71/02
摘要： Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least two free carboxylic acid groups in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.
摘要翻译： 含有羟基官能度和不饱和官能度的独特的，明确定义的聚醚通过在有效量的双金属氰化物配合物催化剂存在下，任选地，必要时，在至少两个游离羧酸基团的存在下，在 存在自由基聚合抑制剂。 所得聚醚特别适用于聚合物多元醇稳定剂或稳定剂前体以及热塑性塑料的原位和非原位冲击改性剂。
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公开(公告)号：US5854386A
公开(公告)日：1998-12-29
申请号：US918081
申请日：1997-08-25
CPC分类号： C08G18/635 , C08F2/40 , C08G18/636 , C08G65/10 , C08G65/2609 , C08G65/2615 , C08G65/2663 , C08G65/2696
摘要： Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.
摘要翻译： 含有羟基官能度和不饱和官能度的独特的，明确定义的聚醚通过在有效量的双金属氰化物配合物催化剂存在下，任选地，在必要时在存在下，使存在有至少一个可氧化烷基化氢的不饱和单体进行烷氧基化， 的自由基聚合抑制剂。 所得聚醚特别适用于聚合物多元醇稳定剂或稳定剂前体以及热塑性塑料的原位和非原位冲击改性剂。
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公开(公告)号：US20130261207A1
公开(公告)日：2013-10-03
申请号：US13900814
申请日：2013-05-23
申请人： Jose F. Pazos , John E. Hayes
发明人： Jose F. Pazos , John E. Hayes
IPC分类号： C08G65/00
CPC分类号： C08G65/002 , C08G18/4866 , C08G18/632 , C08G65/26 , C08G65/2663 , C08G2101/00
摘要： The present invention provides a process for preparing a polymer polyol (PMPO) by alkoxylating a starter compound(s) having active hydrogen atoms in the presence of a double metal cyanide (DMC) catalyst, radical initiator(s) and optionally PMPO stabilizers and simultaneously polymerizing unsaturated monomer(s) with radical initiator(s). The polymer polyols (PMPOs) made by the inventive process may find use in the preparation of polyurethane foams and elastomers,
摘要翻译： 本发明提供一种通过在双金属氰化物（DMC）催化剂，自由基引发剂和任选的PMPO稳定剂的存在下烷氧基化具有活性氢原子的起始化合物来制备聚合物多元醇（PMPO）的方法，同时 用自由基引发剂聚合不饱和单体。 通过本发明方法制备的聚合物多元醇（PMPO）可用于制备聚氨酯泡沫和弹性体，
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公开(公告)号：US20080090966A1
公开(公告)日：2008-04-17
申请号：US11546882
申请日：2006-10-12
申请人： John E. Hayes , Albert Magnotta , Nigel Barksby
发明人： John E. Hayes , Albert Magnotta , Nigel Barksby
IPC分类号： C08F8/30
CPC分类号： C08J5/043 , C08G18/4812 , C08G18/4816 , C08G18/4866 , C08G18/7664 , C08J2375/04
摘要： The present invention provides a reaction system for the preparation of a fiber reinforced composite according to the pultrusion process made from continuous fiber reinforcing material and an immiscible polyurethane formulation containing a polyisocyanate component including at least one polyisocyanate and an isocyanate-reactive component including at least one isocyanate-reactive compound. The inventive polyurethane formulations and improved pultrusion processes offer better processing and may yield better reinforced composites.
摘要翻译： 本发明提供了一种根据由连续纤维增强材料制成的拉挤成型方法制备纤维增强复合材料的反应体系，以及含有至少一种多异氰酸酯和异氰酸酯反应性组分的多异氰酸酯组分的不混溶性聚氨酯制剂，所述多异氰酸酯组分包括至少一种 异氰酸酯反应性化合物。 本发明的聚氨酯配方和改进的拉挤成型方法提供更好的加工并且可以产生更好的增强复合材料。
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9.发明申请DMC-catalyzed polyol containing polyurethane pultrusion formulations and processes 审中-公开DMC催化的含多元醇的聚氨酯拉挤成型制剂和工艺公开(公告)号：US20080090921A1
公开(公告)日：2008-04-17
申请号：US11546639
申请日：2006-10-12
申请人： John E. Hayes , Albert Magnotta , Nigel Barksby
发明人： John E. Hayes , Albert Magnotta , Nigel Barksby
IPC分类号： C08J9/00
CPC分类号： C08G18/4866 , C08G18/246 , C08G18/4812 , C08G18/4816 , C08G18/6677 , C08G18/7664 , C08K7/02 , C08L75/04
摘要： The present invention provides a reaction system for the preparation of a fiber reinforced composite according to the pultrusion process made from continuous fiber reinforcing material and a polyurethane formulation containing a polyisocyanate component including at least one polyisocyanate and an isocyanate-reactive component containing at least one double metal cyanide (“DMC”)-catalyzed polyol. The inventive polyurethane formulations and improved pultrusion processes offer better processing and may yield better reinforced composites.
摘要翻译： 本发明提供了一种根据由连续纤维增强材料制成的拉挤成型方法制备纤维增强复合材料的反应体系，以及含有至少一种多异氰酸酯和含有至少一个双 金属氰化物（“DMC”） - 催化多元醇。 本发明的聚氨酯配方和改进的拉挤成型方法提供更好的加工并且可以产生更好的增强复合材料。
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公开(公告)号：US5070141A
公开(公告)日：1991-12-03
申请号：US226329
申请日：1988-07-29
申请人： Robert G. Gastinger , John E. Hayes
发明人： Robert G. Gastinger , John E. Hayes
IPC分类号： C08F283/06 , C08G18/63
CPC分类号： C08G18/636 , C08G18/638
摘要： Polyacrylate graft-polyols are found to be homogeneous liquids useful as dispersants in vinyl polymer polyols. The novel polyacrylate graft-polyols are made by polymerizing at least one acrylate monomer in a polyol where the resultant polyacrylate is soluble in the polyol used. The polyol may be a polyoxyalkylene polyether polyol. No copolymer or unsaturated polyol is required to make vinyl polymer polyols having high styrene/acrylonitrile ratios, good stability and improved viscosity properties when these polyacrylate graft-polyol dispersants are employed. The vinyl polymer polyols are in turn useful in reactions with polyisocyanates in the presence of suitable catalysts to make polyurethane products.
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