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公开(公告)号：US5854386A
公开(公告)日：1998-12-29
申请号：US918081
申请日：1997-08-25
CPC分类号： C08G18/635 , C08F2/40 , C08G18/636 , C08G65/10 , C08G65/2609 , C08G65/2615 , C08G65/2663 , C08G65/2696
摘要： Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.
摘要翻译： 含有羟基官能度和不饱和官能度的独特的，明确定义的聚醚通过在有效量的双金属氰化物配合物催化剂存在下，任选地，在必要时在存在下，使存在有至少一个可氧化烷基化氢的不饱和单体进行烷氧基化， 的自由基聚合抑制剂。 所得聚醚特别适用于聚合物多元醇稳定剂或稳定剂前体以及热塑性塑料的原位和非原位冲击改性剂。
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公开(公告)号：US5990232A
公开(公告)日：1999-11-23
申请号：US918207
申请日：1997-08-25
CPC分类号： C08G65/2663 , C08G18/4866 , C08G18/633 , C08G18/636 , C08G65/2615 , C08G65/2642 , C08L71/02
摘要： Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least two free carboxylic acid groups in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.
摘要翻译： 含有羟基官能度和不饱和官能度的独特的，明确定义的聚醚通过在有效量的双金属氰化物配合物催化剂存在下，任选地，必要时，在至少两个游离羧酸基团的存在下，在 存在自由基聚合抑制剂。 所得聚醚特别适用于聚合物多元醇稳定剂或稳定剂前体以及热塑性塑料的原位和非原位冲击改性剂。
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公开(公告)号：US5780584A
公开(公告)日：1998-07-14
申请号：US780659
申请日：1997-01-07
申请人： Bi Le-Khac , Harry R. Hinney , Paul T. Bowman
发明人： Bi Le-Khac , Harry R. Hinney , Paul T. Bowman
IPC分类号： B01J31/26 , B01J27/26 , C08G59/00 , C08G59/68 , C08G65/02 , C08G65/10 , C08G65/26 , C07C41/03 , C07C43/10
CPC分类号： C08G65/2663 , B01J27/26
摘要： Highly active double metal cyanide (DMC) complex catalysts and methods for making them are disclosed. The catalysts contain less than about 0.2 moles of metal salt per mole of DMC compound in the catalyst, and unlike other highly active DMC catalysts, are substantially crystalline. Polyether polyols made from the catalysts have low unsaturation and are useful for making many types of polyurethane products.
摘要翻译： 公开了高活性双金属氰化物（DMC）复合催化剂及其制备方法。 该催化剂在催化剂中每摩尔DMC化合物含有小于约0.2摩尔金属盐，并且与其它高活性DMC催化剂不同，其基本上是结晶的。 由催化剂制成的聚醚多元醇具有低不饱和度，可用于制备许多类型的聚氨酯产品。
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公开(公告)号：US5627122A
公开(公告)日：1997-05-06
申请号：US505938
申请日：1995-07-24
申请人： Bi Le-Khac , Harry R. Hinney , Paul T. Bowman
发明人： Bi Le-Khac , Harry R. Hinney , Paul T. Bowman
CPC分类号： C08G65/2663 , B01J27/26
摘要： Highly active double metal cyanide (DMC) complex catalysts and methods for making them are disclosed. The catalysts contain less than about 0.2 moles of metal salt per mole of DMC compound in the catalyst, and unlike other highly active DMC catalysts, are substantially crystalline. Polyether polyols made from the catalysts have low unsaturation and are useful for making many types of polyurethane products.
摘要翻译： 公开了高活性双金属氰化物（DMC）复合催化剂及其制备方法。 该催化剂在催化剂中每摩尔DMC化合物含有小于约0.2摩尔金属盐，并且与其它高活性DMC催化剂不同，其基本上是结晶的。 由催化剂制成的聚醚多元醇具有低不饱和度，可用于制备许多类型的聚氨酯产品。
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公开(公告)号：US5712216A
公开(公告)日：1998-01-27
申请号：US435116
申请日：1995-05-15
申请人： Bi Le-Khac , Paul T. Bowman , Harry R. Hinney
发明人： Bi Le-Khac , Paul T. Bowman , Harry R. Hinney
IPC分类号： C08G65/10 , B01J27/26 , C01C3/11 , C08G59/40 , C08G59/70 , C08G65/02 , C08G65/26 , C08G65/28
CPC分类号： C08G65/2663 , B01J27/26 , C08G65/2642
摘要： Improved double metal cyanide catalysts are disclosed. The substantially amorphous catalysts of the invention are more active for polymerizing epoxides than conventional DMC catalysts, which have a substantial crystalline component. Polyol products made with the catalysts are unusually clear, have exceptionally low unsaturations, and contain no detectable amount of low molecular weight polyol impurities. Methods of making the improved DMC catalysts are also disclosed. In one method, the reactants are intimately combined to produce a catalyst of the invention. In another method, an organic complexing agent is initially present in the reactant solutions.
摘要翻译： 公开了改进的双金属氰化物催化剂。 与具有大量结晶成分的常规DMC催化剂相比，本发明的基本上无定形的催化剂对聚合环氧化物更有活性。 用催化剂制成的多元醇产品异常清楚，具有非常低的不饱和度，并且不含可检测量的低分子量多元醇杂质。 还公开了制备改进的DMC催化剂的方法。 在一种方法中，将反应物紧密地组合以产生本发明的催化剂。 在另一种方法中，有机络合剂最初存在于反应物溶液中。
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公开(公告)号：US5639705A
公开(公告)日：1997-06-17
申请号：US588751
申请日：1996-01-19
IPC分类号： B01J31/18 , B01J27/26 , B01J31/20 , C07C29/141 , C07C29/16 , C07C31/20 , C07C45/58 , C07C45/80 , C08G18/48 , C08G59/68 , C08G65/26 , B01J27/24
CPC分类号： C07C45/58 , B01J27/26 , B01J31/0268 , B01J31/04 , B01J31/20 , B01J31/2234 , B01J31/26 , B01J31/4046 , C07C29/141 , C07C29/16 , C07C45/80 , C08G18/4866 , C08G65/2663 , B01J2231/48 , B01J2531/0211 , B01J2531/822 , B01J2531/845 , Y02P20/52 , Y02P20/584
摘要： Improved double metal cyanide (DMC) catalysts useful for making epoxide polymers are disclosed. One catalyst is a paste of a double metal cyanide (DMC) compound, an organic complexing agent, and water. The paste comprises at least about 90 wt. % of particles having a particle size within the range of about 0.1 to about 10 microns as measured by light scattering in polyether polyol dispersions of the catalyst particles. Preferred catalysts have a bimodal particle size distribution. The paste catalyst is more active and simpler to prepare than powder DMC catalysts. Polyols made from the paste catalyst have low unsaturations, low viscosities, and narrow molecular weight distributions, and are useful in making a variety of polyurethane products.
摘要翻译： 公开了用于制备环氧化物聚合物的改进的双金属氰化物（DMC）催化剂。 一种催化剂是双金属氰化物（DMC）化合物，有机络合剂和水的糊状物。 糊状物包含至少约90wt。 通过在聚醚多元醇分散体中的光散射测量，具有约0.1至约10微米范围内的粒度的颗粒的百分比。 优选的催化剂具有双峰粒度分布。 该糊状催化剂比粉末DMC催化剂更具活性且更容易制备。 由糊状催化剂制成的多元醇具有低的不饱和度，低粘度和窄的分子量分布，并且可用于制备各种聚氨酯产品。
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公开(公告)号：US5783513A
公开(公告)日：1998-07-21
申请号：US816611
申请日：1997-03-13
申请人： George Combs , Harry R. Hinney , Paul T. Bowman
发明人： George Combs , Harry R. Hinney , Paul T. Bowman
CPC分类号： C08G65/2663 , B01J27/26
摘要： A process for making substantially non-crystalline double metal cyanide (DMC) catalysts having improved activity and performance is disclosed. The process comprises using a metal salt having an alkalinity within the range of about 0.2 to about 2.0 wt. % as metal oxide based on the amount of metal salt to prepare the catalyst. Surprisingly, important polyol properties such as viscosity and unsaturation improve when the alkalinity of the metal salt used to make the DMC catalyst is properly controlled. The process allows catalyst producers to enjoy the benefits of substantially non-crystalline DMC catalysts even when relatively inexpensive, technical-grade metal salts are used to make the catalyst.
摘要翻译： 公开了一种制备具有改进的活性和性能的基本上非结晶的双金属氰化物（DMC）催化剂的方法。 该方法包括使用碱度在约0.2至约2.0重量％范围内的金属盐。 ％作为金属氧化物，基于金属盐的量来制备催化剂。 令人惊奇的是，当适当控制用于制造DMC催化剂的金属盐的碱度时，重要的多元醇性质如粘度和不饱和度得到改善。 即使使用相对便宜的工业级金属盐来制造催化剂，该方法也允许催化剂生产者享受基本上非结晶的DMC催化剂的益处。
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公开(公告)号：US5714639A
公开(公告)日：1998-02-03
申请号：US803657
申请日：1997-02-21
IPC分类号： B01J31/18 , B01J27/26 , B01J31/20 , C07C29/141 , C07C29/16 , C07C31/20 , C07C45/58 , C07C45/80 , C08G18/48 , C08G59/68 , C08G65/26 , C08L63/00
CPC分类号： C07C45/58 , B01J27/26 , B01J31/0268 , B01J31/04 , B01J31/20 , B01J31/2234 , B01J31/26 , B01J31/4046 , C07C29/141 , C07C29/16 , C07C45/80 , C08G18/4866 , C08G65/2663 , B01J2231/48 , B01J2531/0211 , B01J2531/822 , B01J2531/845 , Y02P20/52 , Y02P20/584
摘要： Improved double metal cyanide (DMC) catalysts useful for making epoxide polymers are disclosed. One catalyst is a paste of a double metal cyanide (DMC) compound, an organic complexing agent, and water. The paste comprises at least about 90 wt. % of particles having a particle size within the range of about 0.1 to about 10 microns as measured by light scattering in polyether polyol dispersions of the catalyst particles. Preferred catalysts have a bimodal particle size distribution. The paste catalyst is more active and simpler to prepare than powder DMC catalysts. Polyols made from the paste catalyst have low unsaturations, low viscosities, and narrow molecular weight distributions, and are useful in making a variety of polyurethane products.
摘要翻译： 公开了用于制备环氧化物聚合物的改进的双金属氰化物（DMC）催化剂。 一种催化剂是双金属氰化物（DMC）化合物，有机络合剂和水的糊状物。 糊状物包含至少约90wt。 通过在聚醚多元醇分散体中的光散射测量，具有约0.1至约10微米范围内的粒度的颗粒的百分比。 优选的催化剂具有双峰粒度分布。 该糊状催化剂比粉末DMC催化剂更具活性且更容易制备。 由糊状催化剂制成的多元醇具有低的不饱和度，低粘度和窄的分子量分布，并且可用于制备各种聚氨酯产品。
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公开(公告)号：US5158922A
公开(公告)日：1992-10-27
申请号：US831117
申请日：1992-02-04
申请人： Harry R. Hinney , Don S. Wardius
发明人： Harry R. Hinney , Don S. Wardius
IPC分类号： C01C3/11 , B01J27/26 , C08G18/22 , C08G59/68 , C08G65/02 , C08G65/10 , C08G65/26 , C08G65/30
CPC分类号： B01J27/26 , C08G65/2663 , C08G65/30
摘要： Highly active double metal cyanide complex catalysts suitable for use in ring-opening polymerization reactions may be prepared in filterable form by controlling the order of reagent addition, the temperature of the reaction medium, and the stoichiometric ratio of the reactants.
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10.发明授权
公开(公告)号：US5248833A
公开(公告)日：1993-09-28
申请号：US948275
申请日：1992-09-22
申请人： Harry R. Hinney , Don S. Wardius
发明人： Harry R. Hinney , Don S. Wardius
CPC分类号： C07C41/44 , C08G65/2663
摘要： A process for purifying polyether polyols prepared using double metal cyanide (DMC) catalysts is disclosed. The process involves combining a mixture of the polyol and a C.sub.1 -C.sub.6 aliphatic alcohol with an amount of a chelating agent effective to form an insoluble complex with the catalyst, then filtering the polyol mixture to remove the insoluble complex. The process, which requires that the polyol and alcohol be present in a relative weight ratio of from 1:1 to 100:1, is effective for removing DMC residues and any cations introduced with the chelating agent.
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