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公开(公告)号：US20170204031A1
公开(公告)日：2017-07-20
申请号：US15313606
申请日：2015-05-20
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
IPC分类号： C07C41/30
摘要： The present invention concerns a method for producing asymmetrical biphenols using selenium dioxide.
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公开(公告)号：US09950979B2
公开(公告)日：2018-04-24
申请号：US15313606
申请日：2015-05-20
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
IPC分类号： C07C41/30
摘要： A process for preparing unsymmetric biphenols, comprising: a) adding a first substituted phenol to the reaction mixture; b) adding a second substituted phenol having different substitution than the first phenol to the reaction mixture; c) adding selenium dioxide to the reaction mixture; d) adding a solvent; and e) heating the reaction mixture such that the first substituted phenol and the second phenol having different substitution are converted to an unsymmetric biphenol.
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3.发明申请PROCESS FOR PREPARING 2,2'-SELENOBIARYL ETHERS OR 4,4'-SELENOBIARYL ETHERS USING SELENIUM DIOXIDE 审中-公开使用二氧化二铱制备2,2'-二苯并噻唑或4,4'-己二醇的方法公开(公告)号：US20150336885A1
公开(公告)日：2015-11-26
申请号：US14720063
申请日：2015-05-22
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
IPC分类号： C07C391/02
CPC分类号： C07C391/02
摘要： A process for preparing a 2,2′-selenobiaryl ether or a 4,4′-selenobiaryl ether, proceeds by a) adding a first phenol to the reaction mixture, b) adding a second phenol to the reaction mixture, c) adding selenium dioxide to the reaction mixture, d) adding a base having a pKb in the range from 8 to 11 to the reaction mixture, and e) adjusting the reaction temperature of the reaction mixture such that the first phenol and the second phenol are converted to said 2,2′-selenobiaryl ether or said 4,4′-selenobiaryl ether.
摘要翻译： 一种制备2,2'-硒二芳基醚或4,4'-硒二芳基醚的方法是通过以下步骤：a）向反应混合物中加入第一酚，b）向反应混合物中加入第二酚，c）加入硒 二氧化碳反应混合物，d）向反应混合物中加入具有8至11范围内的pKb的碱，以及e）调节反应混合物的反应温度，使得第一酚和第二酚转化为所述 2,2'-硒二芳基醚或所述4,4'-硒二芳基醚。
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公开(公告)号：US20150336865A1
公开(公告)日：2015-11-26
申请号：US14719900
申请日：2015-05-22
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
IPC分类号： C07C37/11
摘要： A process for preparing a 2,2′-biphenol, proceeds by a) adding a first phenol to a reaction mixture, b) adding a second phenol to the reaction mixture, c) adding selenium dioxide to the reaction mixture, d) adding an acid having a pKa in the range from 0.0 to 5.0 to the reaction mixture, and e) heating the reaction mixture such that the first phenol and the second phenol are converted to said 2,2′-biphenol.
摘要翻译： 制备2,2'-联苯酚的方法是由a）向反应混合物中加入第一酚，b）向反应混合物中加入第二酚，c）向反应混合物中加入二氧化硒，d） 对反应混合物具有0.0-5.0的pKa的酸，以及e）加热反应混合物使得第一酚和第二酚被转化成所述的2,2'-联苯酚。
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5.发明申请PROCESS FOR PREPARING 2,2'-BIPHENOLS USING SELENIUM DIOXIDE AND HALOGENATED SOLVENT 审中-公开使用二氧化二锑和氢化溶剂制备2,2'-二苯酚的方法公开(公告)号：US20150336995A1
公开(公告)日：2015-11-26
申请号：US14719003
申请日：2015-05-21
申请人： Katrin Marie DYBALLA , Robert Farnke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
发明人： Katrin Marie DYBALLA , Robert Farnke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
摘要： 2,2′-biphenol is prepared in a process using selenium dioxide and a halogenated solvent.
摘要翻译： 在使用二氧化硒和卤化溶剂的方法中制备2,2'-联苯酚。
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公开(公告)号：US10266955B2
公开(公告)日：2019-04-23
申请号：US14773224
申请日：2014-02-26
摘要： An electrochemical method for coupling anilines. When coupling two different anilines, the difference of the oxidation potential of the substrates is in the region of between 10 mV to 450 mV, and the aniline with the highest oxidation potential is added in excess. The method allows biaryldiamines to be electrochemically produced, and can avoid the need for multi-step syntheses using metallic reagents.
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公开(公告)号：US10131628B2
公开(公告)日：2018-11-20
申请号：US15507970
申请日：2015-07-23
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Bernd Elsler , Mathias Enders
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Bernd Elsler , Mathias Enders
IPC分类号： C25B3/10 , C07C311/21 , C07C233/25 , C07C233/43 , C07C217/84 , C25B11/12
摘要： An electrochemical treatment of differently protected aniline or napthylamine results in the preparation of unsymmetrical 2, 2′-diaminebiaryls provided with different protecting groups. The treatment involves the protecting groups prior to the C, C coupling step. The co-reactants generally have different oxidation potentials which results from the selection of the protecting groups. The treatment also enables controlled access to the individual amino functions of the 2, 2′-diaminobiaryls by subsequent selective deprotection.
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公开(公告)号：US09879353B2
公开(公告)日：2018-01-30
申请号：US14772874
申请日：2013-12-10
摘要： Electrochemical process for coupling two phenols of different oxidation potential, and novel biphenols which can be prepared by this electrochemical coupling.
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公开(公告)号：US09670585B2
公开(公告)日：2017-06-06
申请号：US14773228
申请日：2013-12-10
摘要： The invention relates to an electrochemical method for the selective coupling of a phenol to a naphthol which differ in their oxidation potential. The invention also relates to compounds which can be produced by electrochemical coupling.
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公开(公告)号：US10422047B2
公开(公告)日：2019-09-24
申请号：US14773102
申请日：2014-02-19
摘要： An electrochemical method for C—C coupling a phenol and an aniline in a reaction vessel containing a suitable solvent or solvent mixture and a conductive salt to produce biaryls having both hydroxyl and amino functions, wherein the difference in the oxidation potentials ΔE of the substrates ranges from 10 mV to 450 mV and the substrate with the highest oxidation potential is in excess, which method dispenses with multi-step syntheses using metallic reagents.
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