Copolymer latex
    2.
    发明授权
    Copolymer latex 失效
    共聚物胶乳

    公开(公告)号:US4613650A

    公开(公告)日:1986-09-23

    申请号:US701500

    申请日:1985-02-14

    摘要: A copolymer latex is produced by the emulsion polymerization of 20 to 50% by weight of a conjugated diolefin, 15 to 50% by weight of an aromatic vinyl compound, 0 to 25% by weight of a vinyl cyanide, 5 to 40% by weight of an alkyl ester of an unsaturated carboxylic acid, and 0.5 to 10% by weight of an ethylenically unsaturated acid. First, a monomeric mixture composed of the entire aromatic vinyl compound, the entire vinyl cyanide, at least a part of the conjugated diolefin and at least a part of the ethylenically unsaturated acid, and optionally at least a part of the alkyl ester of an unsaturated carboxylic acid, the amount of the monomeric mixture being 55 to 95% by weight based on the weight of all the monomers used in the process, is polymerized in emulsion. Then, the remainder of the monomers which amounts to 5 to 45% by weight of the weight of all the monomers is added to the above polymerization system and the mixture is polymerized in emulsion.

    摘要翻译: 通过乳液聚合制备共聚物胶乳20至50重量%的共轭二烯烃,15至50重量%的芳族乙烯基化合物,0至25重量%的乙烯基氰,5至40重量% 的不饱和羧酸的烷基酯和0.5至10重量%的烯属不饱和酸。 首先,由全部芳族乙烯基化合物,全部乙烯基氰,至少一部分共轭二烯烃和至少一部分烯键式不饱和酸组成的单体混合物,以及任选的至少一部分不饱和的烷基酯 羧酸,基于该方法中使用的所有单体的重量,单体混合物的量为55至95重量%,在乳液中聚合。 然后,将相当于所有单体重量的5〜45重量%的剩余单体添加到上述聚合体系中,并将混合物乳化聚合。