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公开(公告)号：US20110077435A1
公开(公告)日：2011-03-31
申请号：US12993564
申请日：2009-06-12
IPC分类号： C07C21/18
摘要： A polyfluoro-1-alkene represented by the general formula: CF3(CF2)nCH2(CF2)mCH═CH2[I], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, is produced by reacting a polyfluoroalkyl iodide represented by the general formula: CF3(CF2)nCH2(CF2)m(CH2CH2)I [II], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, with an inorganic basic compound in the presence of a phase transfer catalyst. Alternatively, the polyfluoro-1-alkene is produced by reacting the polyfluoroalkyl iodide [II] with a nitrogen-containing organic basic compound, and is obtained product [I] as one fraction thereof. By the copolymerization of the polyfluoro-1-alkene with other fluorinated olefin monomers, a fluorine-containing copolymer having excellent light transmittance in the visible light range is formed.
摘要翻译： 由通式CF 3（CF 2）n CH 2（CF 2）m CH = CH 2 [I]表示的多氟-1-烯烃，其中n为0〜5的整数，m为1〜7的整数，由 使由通式CF 3（CF 2）n CH 2（CF 2）m（CH 2 CH 2）I [II]表示的多氟烷基碘反应，其中n为0〜5的整数，m为1〜7的整数，与无机 在相转移催化剂存在下的碱性化合物。 或者，通过使多氟烷基碘化物[II]与含氮有机碱性化合物反应来制造多氟-1-烯烃，得到作为其一部分的产物[I]。 通过多氟-1-烯烃与其它氟化烯烃单体的共聚，形成在可见光范围内具有优异的透光率的含氟共聚物。
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公开(公告)号：US07956225B2
公开(公告)日：2011-06-07
申请号：US12993564
申请日：2009-06-12
摘要： A polyfluoro-1-alkene represented by the general formula: CF3(CF2)nCH2(CF2)mCH═CH2 [I], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, is produced by reacting a polyfluoroalkyl iodide represented by the general formula: CF3(CF2)nCH2(CF2)m(CH2CH2)I [II], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, with an inorganic basic compound in the presence of a phase transfer catalyst. Alternatively, the polyfluoro-1-alkene is produced by reacting the polyfluoroalkyl iodide [II] with a nitrogen-containing organic basic compound, and is obtained product [I] as one fraction thereof. By the copolymerization of the polyfluoro-1-alkene with other fluorinated olefin monomers, a fluorine-containing copolymer having excellent light transmittance in the visible light range is formed.
摘要翻译： 由通式CF 3（CF 2）n CH 2（CF 2）m CH = CH 2 [I]表示的多氟-1-烯烃，其中n为0〜5的整数，m为1〜7的整数，由 使由通式CF 3（CF 2）n CH 2（CF 2）m（CH 2 CH 2）I [II]表示的多氟烷基碘反应，其中n为0〜5的整数，m为1〜7的整数，与无机 在相转移催化剂存在下的碱性化合物。 或者，通过使多氟烷基碘化物[II]与含氮有机碱性化合物反应来制造多氟-1-烯烃，得到作为其一部分的产物[I]。 通过多氟-1-烯烃与其它氟化烯烃单体的共聚，形成在可见光范围内具有优异的透光率的含氟共聚物。
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3.发明申请公开(公告)号：US20120090504A1
公开(公告)日：2012-04-19
申请号：US13376321
申请日：2010-06-03
CPC分类号： B29C33/62 , B29K2027/12 , B29K2096/02 , C08F283/06 , C08F214/182
摘要： Disclosed is a graft copolymer in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+(CH2CF2)a(CF2CF2)bCH═CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3). The graft copolymer is an oligomer compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms.
摘要翻译： 公开了一种接枝共聚物，其中聚亚烷基二醇或其烷基醚与下列通式表示的多氟-1-烯烃接枝共聚：CnF2n +（CH2CF2）a（CF2CF2）bCH = CH2（其中n为 1〜6，a为1〜4的整数，b为1〜3的整数）。 接枝共聚物是具有碳原子数6以下的全氟烷基的低聚物化合物，据说具有低的生物蓄积电位，作为脱模剂的活性成分使用时，脱模性能与 具有含有8个以上碳原子的全氟烷基的化合物。
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公开(公告)号：US08454738B2
公开(公告)日：2013-06-04
申请号：US13376335
申请日：2010-06-03
CPC分类号： B29C33/62 , B29K2027/12 , B29K2096/02 , C08F283/06 , C08G2261/128 , C08L27/12 , C08L71/02 , C08L2205/05 , C09D151/00 , C08F214/18 , C08L2666/04
摘要： Disclosed is a mold-releasing agent comprising, as active ingredients, a graft copolymer (A) in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)bCH═CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3), and a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3, and c is an integer of 1 to 3) or a salt thereof (B). The mold-releasing agent comprises, as an active ingredient, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having mold release performance equivalent to or more than that of a mold-releasing agent comprising a compound having a perfluoroalkyl group containing 8 or more carbon atoms as an active ingredient.
摘要翻译： 公开了一种脱模剂，其包含作为活性成分的接枝共聚物（A），其中聚亚烷基二醇或其烷基醚与由下列通式表示的多氟-1-烯烃接枝共聚：CnF2n + 1（ CH 2 CF 2）a（CF 2 CF 2）b CH = CH 2（其中n为1至6的整数，a为1至4的整数，b为1至3的整数）和由通式表示的多氟烷基膦酸： CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）（OH）2（其中n为1〜6的整数，a为1〜4的整数，b为1〜 3，c为1〜3的整数）或其盐（B）。 脱模剂包含具有6个以下碳原子的全氟烷基的化合物作为活性成分，其被认为具有低的生物累积潜力，并且具有与脱模剂相当或更多的脱模性能 包含具有8个以上碳原子的全氟烷基的化合物作为活性成分的药剂。
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5.发明授权公开(公告)号：US08377187B2
公开(公告)日：2013-02-19
申请号：US13376321
申请日：2010-06-03
CPC分类号： B29C33/62 , B29K2027/12 , B29K2096/02 , C08F283/06 , C08F214/182
摘要： Disclosed is a graft copolymer in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+(CH2CF2)a(CF2CF2)bCH═CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3). The graft copolymer is an oligomer compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms.
摘要翻译： 公开了一种接枝共聚物，其中聚亚烷基二醇或其烷基醚与下列通式表示的多氟-1-烯烃接枝共聚：CnF2n +（CH2CF2）a（CF2CF2）bCH = CH2（其中n为 1〜6，a为1〜4的整数，b为1〜3的整数）。 接枝共聚物是具有碳原子数6以下的全氟烷基的低聚物化合物，据说具有低的生物蓄积电位，作为脱模剂的活性成分使用时，脱模性能与 具有含有8个以上碳原子的全氟烷基的化合物。
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6.发明申请公开(公告)号：US20120180696A1
公开(公告)日：2012-07-19
申请号：US13395186
申请日：2010-09-08
CPC分类号： C07F9/3808 , B29C33/62 , C07F9/4006 , C08G65/007 , C08G65/3353 , C08G65/3355 , C08G65/337
摘要： Disclosed is a polyfluoroalkylphosphonic acid oxyalkylene ester of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)[O(RO)mR′]d(OH)2−d (RO is a C2-C6 linear or branched oxyalkylene group, R′ is a hydrogen atom or a C1-C20 alkyl group or aralkyl group, n is 1 to 6, a is 1 to 4, b is 1 to 3, c is 1 to 3, d is 1 or 2, and m is 1 to 100), which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms and referred to as having low bioaccumulation potential, and exhibiting, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms. This compound is produced by subjecting a polyfluoroalkylphosphonic acid of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 and a polyalkyleneglycol or a monoether thereof of the formula: HO(RO)mR′ to a condensation reaction.
摘要翻译： 公开了下式的多氟烷基膦酸氧化烯酯：CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）[O（RO）mR'] d（OH）2-d（RO是C2- C6直链或支链氧化烯基，R'为氢原子或C1-C20烷基或芳烷基，n为1至6，a为1至4，b为1至3，c为1至3，d为 1或2，m为1〜100），其为具有6以下碳原子的全氟烷基且被认为具有低生物蓄积电位的化合物，并且当用作脱模剂的活性成分时 脱模性能与具有8个以上碳原子的全氟烷基的化合物相当。 该化合物是通过使式CnF 2 n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OH）2的多氟烷基膦酸和式HO（RO）的聚亚烷基二醇或其单醚进行 mR'进行缩合反应。
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7.发明申请公开(公告)号：US20110315050A1
公开(公告)日：2011-12-29
申请号：US13255332
申请日：2010-03-09
CPC分类号： B29C33/62 , C07F9/3808 , C07F9/4006
摘要： Disclosed is a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2, wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, or a salt thereof, which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and being usable as an active ingredient of a mold-releasing agent. The polyfluoroalkylphosphonic acid is produced by hydrolyzing a polyfluoroalkylphosphonic acid diester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP (O)(OR)2, wherein R is a C1-C4 alkyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3.
摘要翻译： 公开了由以下通式表示的多氟烷基膦酸：C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OH）2，其中n为1至6的整数，a为整数1 至4，b为1〜3的整数，c为1〜3的整数，或其具有碳原子数6以下的全氟烷基的化合物的盐，其生物蓄积电位低 ，可用作脱模剂的活性成分。 多氟烷基膦酸通过水解由通式C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OR）2表示的多氟烷基膦酸二酯制备，其中R是C 1 -C 4烷基， n为1〜6的整数，a为1〜4的整数，b为1〜3的整数，c为1〜3的整数。
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公开(公告)号：US08313573B2
公开(公告)日：2012-11-20
申请号：US13395189
申请日：2010-09-08
IPC分类号： B29C33/60 , B28B7/38 , C08L71/02 , C10M105/74 , C10M145/26 , C10N30/00 , C10N40/36
CPC分类号： B29C33/62 , C08G65/3353 , C08G65/337 , C08K5/5317 , C08K5/5337 , C10M173/02 , C10M2207/021 , C10M2213/06 , C10M2215/04 , C10M2223/04 , C10M2225/00 , C10N2240/58
摘要： Disclosed is a mold-releasing agent comprising, as active ingredients, a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 (n: an integer of 1 to 6, a: an integer of 1 to 4, b: an integer of 1 to 3, c: an integer of 1 to 3), or a salt thereof and a polyfluoroalkylphosphonic acid oxyalkylene ester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)[O(RO)mR′]d(OH)2−d (RO: a C2-C6 linear or branched oxyalkylene group, R′: a hydrogen atom, a C1-C20 alkyl group, or aralkyl group, n: an integer of 1 to 6, a: an integer of 1 to 4, b: an integer of 1 to 3, c: an integer of 1 to 3, d: an integer of 1 or 2, m: an integer of 1 to 100). This mold-releasing agent comprises, as an active ingredient, a polyfluoroalkylphosphonic acid oxyalkylene ester having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, but exhibits mold release performance equivalent to that of a mold-releasing agent comprising a compound having a perfluoroalkyl group containing 8 or more carbon atoms as an active ingredient.
摘要翻译： 公开了一种脱模剂，其包含作为活性成分的由以下通式表示的多氟烷基膦酸：CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）（OH）2（n： 1至6，a：1至4的整数，b：1至3的整数，c：1至3的整数）或其盐和由以下通式表示的多氟烷基膦酸氧化烯：CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）[O（RO）mR'] d（OH）2-d（RO：C2-C6直链或支链氧化烯基，R' ，C 1〜C 20的烷基或芳烷基，n：1〜6的整数，a：1〜4的整数，b：1〜3的整数，c：1〜3的整数，d： 1或2的整数，m：1〜100的整数）。 该脱模剂含有具有6个以下碳原子的全氟烷基的多氟烷基膦酸氧化烯作为活性成分，其被认为具有低的生物累积潜力，但是具有与脱模剂相当的脱模性能 包含具有8个以上碳原子的全氟烷基的化合物作为活性成分的药剂。
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9.发明授权Polyfluoroalkylphosphonic acid, method for producing the same and mold-releasing agent comprising the same as active ingredient 有权多氟烷基膦酸，其制造方法以及含有该脱模剂的活性成分的脱模剂公开(公告)号：US08197586B2
公开(公告)日：2012-06-12
申请号：US13255332
申请日：2010-03-09
CPC分类号： B29C33/62 , C07F9/3808 , C07F9/4006
摘要： Disclosed is a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2, wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, or a salt thereof, which is a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and being usable as an active ingredient of a mold-releasing agent. The polyfluoroalkylphosphonic acid is produced by hydrolyzing a polyfluoroalkylphosphonic acid diester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2, wherein R is a C1-C4 alkyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3.
摘要翻译： 公开了由以下通式表示的多氟烷基膦酸：C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OH）2，其中n为1至6的整数，a为整数1 至4，b为1〜3的整数，c为1〜3的整数，或其具有碳原子数6以下的全氟烷基的化合物的盐，其生物蓄积电位低 ，可用作脱模剂的活性成分。 多氟烷基膦酸通过水解由通式C n F 2n + 1（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）cP（O）（OR）2表示的多氟烷基膦酸二酯制备，其中R是C 1 -C 4烷基， n为1〜6的整数，a为1〜4的整数，b为1〜3的整数，c为1〜3的整数。
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公开(公告)号：US20120077930A1
公开(公告)日：2012-03-29
申请号：US13376335
申请日：2010-06-03
IPC分类号： C09D171/08
CPC分类号： B29C33/62 , B29K2027/12 , B29K2096/02 , C08F283/06 , C08G2261/128 , C08L27/12 , C08L71/02 , C08L2205/05 , C09D151/00 , C08F214/18 , C08L2666/04
摘要： Disclosed is a mold-releasing agent comprising, as active ingredients, a graft copolymer (A) in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)bCH═CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3), and a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3, and c is an integer of 1 to 3) or a salt thereof (B). The mold-releasing agent comprises, as an active ingredient, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having mold release performance equivalent to or more than that of a mold-releasing agent comprising a compound having a perfluoroalkyl group containing 8 or more carbon atoms as an active ingredient.
摘要翻译： 公开了一种脱模剂，其包含作为活性成分的接枝共聚物（A），其中聚亚烷基二醇或其烷基醚与由下列通式表示的多氟-1-烯烃接枝共聚：CnF2n + 1（ CH 2 CF 2）a（CF 2 CF 2）b CH = CH 2（其中，n为1〜6的整数，a为1〜4的整数，b为1〜3的整数），以及由以下通式表示的多氟烷基膦酸： CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cP（O）（OH）2（其中n为1〜6的整数，a为1〜4的整数，b为1〜 3，c为1〜3的整数）或其盐（B）。 脱模剂包含具有6个以下碳原子的全氟烷基的化合物作为活性成分，其被认为具有低的生物累积潜力，并且具有与脱模剂相当或更多的脱模性能 包含具有8个以上碳原子的全氟烷基的化合物作为活性成分的药剂。
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