公开(公告)号：US20110223490A1

公开(公告)日：2011-09-15

申请号：US13042543

申请日：2011-03-08

申请人： Kazushi Andou ,  Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Kazushi Andou ,  Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M10/0564 ,  H01M10/056

CPC分类号： H01M10/0567 ,  H01M4/364 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0034 ,  H01M2300/0037 ,  H01M2300/004

摘要： In the nonaqueous electrolyte secondary battery, the positive electrode active material is composed of a mixture of a lithium-cobalt composite oxide containing at least both zirconium and magnesium, and a lithium-manganese-nickel composite oxide containing at least both manganese and nickel. The nonaqueous electrolyte includes fluoroethylene carbonate and dimethyl carbonate as a nonaqueous solvent and further includes an additive expressed by General Formula (1), which having a capability to form an SEI surface film, and a higher oxidation resistance than that of VC. Thus, the negative electrode active material is unlikely to react with the organic solvent. Therefore, decomposition of the organic solvent is suppressed. Thus the battery having a long cycling life even when it is charged at a positive electrode charging potential of 4.4 to 4.6 V based on lithium and having a high residual capacity after storage at high temperature in a charged state is provided.

摘要翻译： 在非水电解质二次电池中，正极活性物质由至少含有锆和镁两者的锂 - 钴复合氧化物和至少含有锰和镍两者的锂 - 锰 - 镍复合氧化物的混合物构成。 非水电解质包括氟代碳酸亚乙酯和作为非水溶剂的碳酸二甲酯，并且还包括具有形成SEI表面膜的能力和比VC更高的抗氧化性的由通式（1）表示的添加剂。 因此，负极活性物质不可能与有机溶剂发生反应。 因此，有机溶剂的分解被抑制。 因此，电池具有长的循环寿命，即使在基于锂的正极充电电位为4.4〜4.6V下充电，并且在充电状态下在高温下保存后具有高剩余容量。

公开(公告)号：US08568932B2

公开(公告)日：2013-10-29

申请号：US12064181

申请日：2006-08-10

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0037 ,  H01M2300/004 ,  H01M2300/0042

摘要： The present invention provides a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, containing 0.01% to 30% by weight of a 1,2-cyclohexanediol derivative having a specific structure; and a lithium secondary battery using the nonaqueous electrolytic solution. The lithium secondary battery exhibits excellent battery characteristics such as electrical capacity, cycle property, and storage property and can maintain excellent long-term battery performance.

摘要翻译： 本发明提供一种非水电解液，其中电解质盐溶解在非水溶剂中，其含有0.01重量％至30重量％的具有特定结构的1,2-环己二醇衍生物; 以及使用非水电解液的锂二次电池。 锂二次电池具有优异的电池特性，例如电容，循环特性和存储性能，并且可以保持优异的长期电池性能。

公开(公告)号：US08124273B2

公开(公告)日：2012-02-28

申请号：US12064337

申请日：2006-08-11

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo ,  Manabu Takase

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo ,  Manabu Takase

IPC分类号： H01M4/36

CPC分类号： H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/004

摘要： The present invention provides a nonaqueous electrolytic solution exhibiting excellent electrical capacity, long-term cycle property, and storage property in a charged state; and a lithium secondary battery using the nonaqueous electrolytic solution.The nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprises 0.001% to 5% by weight of a tin compound represented by the following general formula (I) and/or (II), on the basis of the weight of the nonaqueous electrolytic solution: R1R2R3Sn-MR4R5R6  (I) where R1 to R3 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or an aryloxy group; R4 to R6 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, or an aryl group; M represents Si or Ge; and SnX2  (II) where X represents β-diketonate.

摘要翻译： 本发明提供一种在充电状态下显示出优异的电容，长期循环性能和储存性能的非水电解液。 以及使用非水电解液的锂二次电池。 其中电解质盐溶解在非水溶剂中的非水电解液包含0.001重量％至5重量％的由以下通式（I）和/或（II）表示的锡化合物，基于重量 的非水电解液：R1R2R3Sn-MR4R5R6（I）其中R1至R3各自表示氢原子，卤素原子，烷基，烯基，炔基，芳基或芳氧基; R4至R6各自表示氢原子，卤素原子，烷基，烯基，炔基或芳基; M表示Si或Ge; 和SnX2（II），其中X表示＆bgr; - 酮。

公开(公告)号：US20110223489A1

公开(公告)日：2011-09-15

申请号：US13042552

申请日：2011-03-08

申请人： Masato Iwanaga ,  Noriko Yamashita ,  Atsushi Kaiduka ,  Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Masato Iwanaga ,  Noriko Yamashita ,  Atsushi Kaiduka ,  Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M10/056

CPC分类号： H01M10/0567 ,  H01M4/525 ,  H01M10/052 ,  H01M10/4235 ,  H01M2300/0025 ,  Y02T10/7011

摘要： A positive electrode active material of a nonaqueous electrolyte secondary battery is composed of lithium-cobalt composite oxide containing at least one of zirconium, titanium, aluminum, and erbium, and the nonaqueous electrolyte includes an additive expressed by General Formula (1) having an acetylene group and a methylsulfonyl group at each end of the molecule. It has the effect of forming an SEI surface film as with the case of VC or the like, as well as having a higher oxidation resistance than that of VC or the like. Thus the nonaqueous electrolyte secondary battery employing as positive electrode active material a lithium-cobalt composite oxide with a particular dissimilar metallic element added, in which decomposition of the nonaqueous electrolytic solution during storage at high temperature in a charged state is suppressed, and there is little battery swelling is provided.

摘要翻译： 非水电解质二次电池的正极活性物质由含有锆，钛，铝，铒中的至少一种的锂钴复合氧化物构成，非水电解质含有通式（1）表示的添加剂，其具有乙炔 基团和分子的每个末端的甲基磺酰基。 与VC等的情况相同，具有形成SEI表面膜的效果，并且具有比VC等更高的抗氧化性。 因此，作为正极活性物质使用添加了特定的异种金属元素的锂 - 钴复合氧化物的非水电解质二次电池，其中抑制了在高温下在充电状态下储存期间非水电解液的分解，并且几乎没有 提供电池膨胀。

公开(公告)号：US20090170006A1

公开(公告)日：2009-07-02

申请号：US12064181

申请日：2006-08-10

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0037 ,  H01M2300/004 ,  H01M2300/0042

摘要： The present invention provides a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, containing 0.01% to 30% by weight of a 1,2-cyclohexanediol derivative having a specific structure; and a lithium secondary battery using the nonaqueous electrolytic solution. The lithium secondary battery exhibits excellent battery characteristics such as electrical capacity, cycle property, and storage property and can maintain excellent long-term battery performance.

摘要翻译： 本发明提供一种非水电解液，其中电解质盐溶解在非水溶剂中，其含有0.01重量％至30重量％的具有特定结构的1,2-环己二醇衍生物; 以及使用非水电解液的锂二次电池。 锂二次电池具有优异的电池特性，例如电容，循环特性和存储性能，并且可以保持优异的长期电池性能。

公开(公告)号：US09230746B2

公开(公告)日：2016-01-05

申请号：US13992106

申请日：2011-12-05

申请人： Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M6/16 ,  H01G9/025 ,  H01G11/60 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/052

CPC分类号： H01G9/025 ,  H01G11/60 ,  H01M6/164 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/13 ,  Y02T10/7022

摘要： The object of the present invention is to provide a nonaqueous electrolytic solution that can improve the electrochemical properties in a broad temperature range and an electrochemical device using the same. A nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, wherein the nonaqueous solvent includes 0.1 to 30% by volume of a fluorine atom-containing cyclic carbonate, and further the nonaqueous electrolytic solution includes 0.001 to 5% by mass of a branched dinitrile compound in which the main chain of an alkylene chain linking the two nitrile groups has 2 or more and 4 or less of the carbon number.

摘要翻译： 本发明的目的是提供一种能够在宽的温度范围内提高电化学性能的非水电解液和使用其的电化学装置。 通过将电解质盐溶解在非水溶剂中而制备的非水电解液，其中，所述非水溶剂含有0.1〜30体积％的含氟原子的环状碳酸酯，另外，所述非水电解液包含0.001〜5质量％ 支链二腈化合物，其中连接两个腈基的亚烷基链的主链具有2以上且4以下的碳数。

公开(公告)号：US20120301797A1

公开(公告)日：2012-11-29

申请号：US13576182

申请日：2011-02-02

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M10/056 ,  C07C309/70 ,  C07C309/68 ,  C07C309/67

CPC分类号： H01M10/0567 ,  C07C309/67 ,  C07F9/113 ,  C07F9/327 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it.The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2  (I) (In the formula, X1 represents a group —C(═O)—, a group —C(═O)—C(═O)—, a group —S(═O)2—, a group —P(═O) (—R3)—, or a group —X2—S(═O)2O—. R1 represents an alkenyl group, a formyl group, an alkyl group, an acyl group, an arylcarbonyl, an alkanesulfonyl group, an alkynyloxysulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkyl(alkoxy)phosphoryl group, or a dialkoxyphosphoryl group; R2 represents an alkynyl group or an alkynyloxy group; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.

摘要翻译： 本发明提供一种能够提高高温充电保存后的低温高温循环性能和负载特性的优异的非水电解液，使用它的电化学元件和用于其的炔基化合物。 本发明的非水电解液在非水电解液中含有0.01〜10质量％的由通式（I）表示的至少一种炔基化合物。 R 1（O）n -X 1 -R 2（I）（式中，X1表示-C（= O） - 基，-C（= O）-C（= O） - 基，-S（ = O）2-，基团-P（= O）（-R 3） - 或基团-X 2 -S（= O）2 O-，R 1表示链烯基，甲酰基，烷基，酰基 基团，芳基羰基，烷磺酰基，炔氧基磺酰基，芳基磺酰基，二烷基磷酰基，烷基（烷氧基）磷酰基或二烷氧基磷酰基; R2表示炔基或炔氧基; R3表示烷基， 烯基，炔基，芳基，烷氧基，烯氧基，炔氧基或芳氧基; n表示0或1。

公开(公告)号：US09647294B2

公开(公告)日：2017-05-09

申请号：US13576182

申请日：2011-02-02

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M10/056 ,  C07C309/70 ,  C07C309/68 ,  C07C309/67 ,  H01M10/0567 ,  H01M10/052 ,  C07F9/113 ,  C07F9/32

CPC分类号： H01M10/0567 ,  C07C309/67 ,  C07F9/113 ,  C07F9/327 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it.The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2  (I) (In the formula, X1 represents a group —C(═O)—, a group —C(═O)—C(═O)—, a group —S(═O)2—, a group —P(═O) (—R3)—, or a group —X3—S(═O)2O—. R1 represents an alkenyl group, a formyl group, an alkyl group, an acyl group, an arylcarbonyl, an alkanesulfonyl group, an alkynyloxysulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkyl(alkoxy)phosphoryl group, or a dialkoxyphosphoryl group; R2 represents an alkynyl group or an alkynyloxy group; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.

公开(公告)号：US20130337346A1

公开(公告)日：2013-12-19

申请号：US13992106

申请日：2011-12-05

申请人： Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01G9/025 ,  H01M10/052 ,  H01M10/0569

CPC分类号： H01G9/025 ,  H01G11/60 ,  H01M6/164 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/13 ,  Y02T10/7022

摘要： The object of the present invention is to provide a nonaqueous electrolytic solution that can improve the electrochemical properties in a broad temperature range and an electrochemical device using the same. A nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, wherein the nonaqueous solvent includes 0.1 to 30% by volume of a fluorine atom-containing cyclic carbonate, and further the nonaqueous electrolytic solution includes 0.001 to 5% by mass of a branched dinitrile compound in which the main chain of an alkylene chain linking the two nitrile groups has 2 or more and 4 or less of the carbon number.

摘要翻译： 本发明的目的是提供一种能够在宽的温度范围内提高电化学性能的非水电解液和使用其的电化学装置。 通过将电解质盐溶解在非水溶剂中而制备的非水电解液，其中，所述非水溶剂含有0.1〜30体积％的含氟原子的环状碳酸酯，另外，所述非水电解液包含0.001〜5质量％ 支链二腈化合物，其中连接两个腈基的亚烷基链的主链具有2以上且4以下的碳数。

公开(公告)号：US20090280404A1

公开(公告)日：2009-11-12

申请号：US12064337

申请日：2006-08-11

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo ,  Manabu Takase

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo ,  Manabu Takase

IPC分类号： H01M6/14 ,  H01M6/16

CPC分类号： H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/004

摘要： The present invention provides a nonaqueous electrolytic solution exhibiting excellent electrical capacity, long-term cycle property, and storage property in a charged state; and a lithium secondary battery using the nonaqueous electrolytic solution.The nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprises 0.001% to 5% by weight of a tin compound represented by the following general formula (I) and/or (II), on the basis of the weight of the nonaqueous electrolytic solution: R1R2R3Sn-MR4R5R6  (I) where R1 to R3 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or an aryloxy group; R4 to R6 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, or an aryl group; M represents Si or Ge; and SnX2  (II) where X represents β-diketonate.

摘要翻译： 本发明提供一种在充电状态下显示出优异的电容，长期循环性能和储存性能的非水电解液。 以及使用非水电解液的锂二次电池。 其中电解质盐溶解在非水溶剂中的非水电解液包含0.001重量％至5重量％的由以下通式（I）和/或（II）表示的锡化合物，基于重量 的非水电解液：R1R2R3Sn-MR4R5R6（I）其中R1至R3各自表示氢原子，卤素原子，烷基，烯基，炔基，芳基或芳氧基; R4至R6各自表示氢原子，卤素原子，烷基，烯基，炔基或芳基; M表示Si或Ge; 和SnX 2（II），其中X代表β-二酮。