Aliphatic polyester resin composition, preparation method therefor, and molded article and foamed article produced from the resin composition
    5.
    发明申请
    Aliphatic polyester resin composition, preparation method therefor, and molded article and foamed article produced from the resin composition 失效
    脂肪族聚酯树脂组合物及其制备方法以及由树脂组合物制成的成型品和发泡体

    公开(公告)号:US20060276617A1

    公开(公告)日:2006-12-07

    申请号:US10560629

    申请日:2004-06-24

    IPC分类号: C08G63/02

    摘要: An aliphatic polyester resin composition is provided which is excellent in heat resistance, moldability and hydrolysis resistance. The aliphatic polyester resin composition comprises a biodegradable polyester resin (A) essentially including an α- and/or β-hydroxycarboxylic acid unit and crosslinked by at least one crosslinking agent (B) selected from the group consisting of (meth)acrylate compounds and polyvalent isocyanate compounds, wherein some or all of carboxyl groups of the resin (A) are blocked by 0.01 to 20 parts by mass of a terminal blocking agent (C) based on 100 parts by mass of the resin (A).

    摘要翻译: 提供耐热性,成型性和耐水解性优异的脂肪族聚酯树脂组合物。 脂肪族聚酯树脂组合物包含生物降解性聚酯树脂(A),其主要包含α-和/或β-羟基羧酸单元,并通过至少一种选自(甲基)丙烯酸酯化合物和多价的(甲基)丙烯酸酯化合物的交联剂 异氰酸酯化合物,其中树脂(A)的一部分或全部羧基基于100质量份树脂(A)被封端0.01〜20质量份的封端剂(C)。

    Biodegradable gas barrier container and process for producing the same
    9.
    发明授权
    Biodegradable gas barrier container and process for producing the same 有权
    可生物降解气体阻隔容器及其制造方法

    公开(公告)号:US07981957B2

    公开(公告)日:2011-07-19

    申请号:US11628625

    申请日:2005-06-08

    IPC分类号: C08K3/34

    摘要: A biodegradable gas barrier vessel comprising 100 parts of mass of a biodegradable polyester resin having a polylactic acid content of not less than 50% by mass and 0.1 to 10 parts by mass of a phyllosilicate. The degree of crystallization as measured by X-ray diffractometry is not less than 15%, and the coefficient of oxygen permeation as measured under conditions of 20° C. and relative humidity 90% is not more than 50 ml·mm/m2·day·MPa. Since the biodegradable polyester resin reinforced with the phyllosilicate has excellent heat resistance, the molded product can be heat treated at an elevated temperature. Such enhanced heat treatment conditions can further enhance the degree of crystallization of the polyester resin and thus can contribute to significantly improved gas barrier properties.

    摘要翻译: 一种生物降解性气体阻隔容器,其包含100质量份的聚乳酸含量为50质量%以上的生物降解性聚酯树脂和0.1〜10质量份的页硅酸盐。 通过X射线衍射测定的结晶度为15%以上,在20℃,相对湿度90%的条件下测定的透氧系数为50毫升/毫米2·m 2·天以下 ·MPa。 由于用页硅酸盐增强的可生物降解的聚酯树脂具有优异的耐热性,所以可以在升高的温度下对成型体进行热处理。 这种增强的热处理条件可以进一步提高聚酯树脂的结晶度,因此有助于显着提高阻气性。

    Biodegradable Gas Barrier Container And Process For Producing The Same
    10.
    发明申请
    Biodegradable Gas Barrier Container And Process For Producing The Same 有权
    可生物降解气体容器及其生产方法

    公开(公告)号:US20080069993A1

    公开(公告)日:2008-03-20

    申请号:US11628625

    申请日:2005-06-08

    IPC分类号: B32B1/08 C08J5/00

    摘要: A biodegradable gas barrier vessel comprising 100 parts of mass of a biodegradable polyester resin having a polylactic acid content of not less than 50% by mass and 0.1 to 10 parts by mass of a phyllosilicate. The degree of crystallization as measured by X-ray diffractometry is not less than 15%, and the coefficient of oxygen permeation as measured under conditions of 20° C. and relative humidity 90% is not more than 50 ml·mm/m2·day·MPa. Since the biodegradable polyester resin reinforced with the phyllosilicate has excellent heat resistance, the molded product can be heat treated at an elevated temperature. Such enhanced heat treatment conditions can further enhance the degree of crystallization of the polyester resin and thus can contribute to significantly improved gas barrier properties.

    摘要翻译: 一种生物降解性气体阻隔容器,其包含100质量份的聚乳酸含量为50质量%以上的生物降解性聚酯树脂和0.1〜10质量份的页硅酸盐。 通过X射线衍射法测定的结晶度为15%以上,在20℃,相对湿度90%的条件下测定的透氧系数为50毫升/毫升以下 > 2 .day.MPa。 由于用页硅酸盐增强的可生物降解的聚酯树脂具有优异的耐热性,所以可以在升高的温度下对成型体进行热处理。 这种增强的热处理条件可以进一步提高聚酯树脂的结晶度,因此有助于显着提高阻气性。