摘要:
Stable peroxyesters containing both conjugated diene and peroxidic groups in their molecule; e.g., t-butylperoxysorbate, t-hexylperoxysorbate, 1,1,3,3-tetra-methylbutylperoxysorbate, are copolymerizable with other polymerizable monomers and the said compounds are useful for polymerizing monomers as free radical initiators.
摘要:
A novel peroxy aryl carbonate which has the both properties of polymerization-initiating and regulating abilities, can be used as a radical polymerization initiator to regulate the polymerization rate, the polymerization degree and molecular weight distribution of the polymer and the like, and therefore produce superior styrene resin and methyl methacrylate syrup.
摘要:
An aqueous suspension of a solid organic peroxide is produced by mixing a solid organic peroxide having a difference of at least 5.degree. C. between the melting point and the thermal decomposition temperature thereof with a protective colloid, a surface active agent, and water thereby forming an aqueous emulsion and subsequently cooling this aqueous emulsion.
摘要:
A novel peroxy aryl carbonate which has the both properties of polymerization-initiating and regulating abilities, can be used as a radical polymerization initiator to regulate the polymerization rate, the polymerization degree and molecular weight distribution of the polymer and the like, and therefore produce superior styrene resin and methyl methacrylate syrup.
摘要:
A novel peroxy aryl carbonate which has the both properties of polymerization-initiating and regulating abilities, can be used as a radical polymerization initiator to regulate the polymerization rate, the polymerization degree and molecular weight distribution of the polymer and the like, and therefore produce superior styrene resin and methyl methacrylate syrup.
摘要:
Dicyclododecyl peroxydicarbonate of the formula: ##STR1## is stable and can be stored at room temperature. It has a high solubility in organic solvents and good compatibility with unsaturated polyester resins.This compound is an improved polymerization initiator for free radical polymerizations of ethylenically unsaturated monomers, including copolymerization with monomers capable of copolymerizing therewith.This compound also is a catalyst for curing unsaturated polyester resin compositions.
摘要:
A novel cyclic monoperoxyketal represented by the following general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 represent hydrogen atoms, or same or different alkyl groups having 1-3 carbon atoms, R.sup.4 represents an alkyl group having 1-5 carbon atoms, R.sup.5 represents an alkyl group having 1-3 carbon atoms, and R.sup.6 and R.sup.7 may be separate groups, in which R.sup.6 represents an alkyl group having 1-3 carbon atoms and R.sup.7 represents an alkyl group having 2-10 carbon atoms, a cycloalkyl group or an aryl group, or may be combined into a cylcoalkylene group having 3-12 carbon atoms, has high stability and excellent decomposition property, and is useful as a polymerization initiator of unsaturated monomers and as a curing agent of unsaturated polyester resin.
摘要:
A sizing agent for the treatment of glass fibers contains as principal components a film-forming agent, which is a copolymer of a specific unsaturated peroxycarbonate and an unsaturated monomer containing at least 70% by weight of vinyl acetate, and a coupling agent. A method for the treatment of glass fibers, which comprises causing said sizing agent to be deposited on glass fibers and subjecting the glass fibers coated with said sizing agent to heat treatment.
摘要:
Peroxycarbonates having the following formula are copolymerizable with non-conjugated ethylenically unsaturated monomers and have good storage stability, ##STR1## in which R.sub.1 represents a hydrogen atom or a lower alkyl group having one to four carbon atoms, R.sub.2 and R.sub.3 represent lower alkyl groups having one to four carbon atoms, and R.sub.4 represents an alkyl group having one to 12 carbon atoms or a cyclo alkyl group having three to 12 carbon atoms.
摘要:
A high molecular material and a medical material which is a mixed material containing a copolymer A produced by copolymerization of a monomer composition containing a monomer having a side chain represented by the formula (1) ##STR1## (R.sup.1, R.sup.2, R.sup.3 ; H or a C1-4 alkyl group) and a hydrophobic monomer, and one or more sorts of hydrophobic polymer B other than the copolymer A; wherein structure of said mixed material shows phase separation in which domains of several hundred micrometers or less in size consisting of the copolymer A are uniformly distributed in a phase consisting of said hydrophobic polymer B. A liquid high molecular composition in which the copolymer A and the hydrophobic polymer B are dissolved in a mixed solvent consisting of a halogenated hydrocarbon solvent and a lower alcohol solvent, which has turbidity of 60% or less.