公开(公告)号：US5774607A

公开(公告)日：1998-06-30

申请号：US718375

申请日：1996-09-27

Applicant: Kazuo Shiraishi ,  Kazuhito Matsumura ,  Isamu Ohishi

Inventor： Kazuo Shiraishi ,  Kazuhito Matsumura ,  Isamu Ohishi

IPC: G02B6/32 ,  G02B6/02 ,  G02B6/028 ,  G02B6/42

CPC classification number: G02B6/4203 ,  G02B6/4206

Abstract: A lensed-fiber including a single-mode fiber having a core and a cladding, a coreless fiber having a coreless isotropic refractive index and a convex surface at a first end thereof, and a square-law index fiber having a square-law index profile. The square-law index fiber is positioned between the single-mode fiber and the coreless fiber so as to connect an end of the single-mode fiber to a second end of the coreless fiber. The lensed-fiber may be arranged in a optical module facing an optical semiconductor element which emits a light beam to be propagated through the single-mode fiber.

Abstract translation: PCT No.PCT / JP96 / 00398 Sec。 371日期1996年9月27日第 102（e）1996年9月27日PCT PCT 1996年2月22日PCT公布。 公开号WO96 / 26459 日期1996年8月29日包括具有芯和包层的单模光纤的透镜光纤，具有无芯各向同性折射率的无芯光纤和其第一端的凸面，以及具有 平方律索引。 平方律索引光纤位于单模光纤和无芯光纤之间，以将单模光纤的一端连接到无芯光纤的第二端。 透镜光纤可以布置在面向发射要通过单模光纤传播的光束的光学半导体元件的光学模块中。

公开(公告)号：US6130972A

公开(公告)日：2000-10-10

申请号：US239432

申请日：1999-01-28

Applicant: Kazuo Shiraishi ,  Isamu Ohishi

Inventor： Kazuo Shiraishi ,  Isamu Ohishi

IPC: G02B6/32 ,  G02B6/02 ,  G02B6/028 ,  G02B6/42

CPC classification number: G02B6/4203 ,  G02B6/4206

Abstract: A lensed optical fiber and a semiconductor laser module, characterized in that first and second optical fibers, each including a core and a cladding, are connected to one end of a single-mode fiber, including a core and a cladding, in the order named. The core of the first optical fiber has a first square-low index distribution and a length substantially equal to 1/4 of the meandering period of light propagating through the core or an odd multiple thereof. The core of the second optical fiber has a second square-low index distribution and a meandering period different from that of the first optical fiber.

Abstract translation: 一种透镜光纤和半导体激光器模块，其特征在于，每个包括芯和包层的第一和第二光纤被连接到包括芯和包层的单模光纤的一端，其命名为 。 第一光纤的纤芯具有第一正方形低折射率分布和基本上等于通过芯传播的光的曲折周期的+ E，fra 1/4 + EE的长度或其奇数倍。 第二光纤的纤芯具有与第一光纤不同的第二平方低折射率分布和曲折周期。

公开(公告)号：US20130310604A1

公开(公告)日：2013-11-21

申请号：US13982808

申请日：2012-01-16

Applicant: Tatsuhiko Kurakami ,  Susumu Matsumoto ,  Atsushi Sudo ,  Kazuo Shiraishi ,  Masashi Hashiba

Inventor： Tatsuhiko Kurakami ,  Susumu Matsumoto ,  Atsushi Sudo ,  Kazuo Shiraishi ,  Masashi Hashiba

IPC: C07C51/25 ,  C07C45/38 ,  C07C51/235 ,  C07C45/35

CPC classification number: C07C51/235 ,  C07C45/35 ,  C07C45/38 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04

Abstract: There is provided a process for producing aerolein, acrylic acid, methacrolein, methacrylic acid in a safe and steady manner and in high yields, which avoids a phenomenon of occurrence of an abnormal reaction attributable to the fact that the temperature at a raw material gas outlet side becomes considerably higher than the temperature at a raw material gas inlet side, with regard to the temperature of a catalyst packed in a reaction tube at vapor-phase catalytic oxidation of propylene, isobutylene, or the like.In the process of using a reaction tube on which a plurality of catalyst layers formed in a raw material gas flow direction, a catalyst and a catalyst packing schedule are designed so that a relation between the raw material conversion rate at which the yield of the objective product becomes maximum and the raw material conversion rate at which a high and low correlation between maximum temperature of the catalyst layer present closest to a reaction gas inlet side Zin and maximum temperature of the catalyst layer present closest to a reaction gas outlet side Zout is reversed satisfies a specific condition of 0.5≦Cmax−Ccrs≦5, in which Cmax: a raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: a raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate is changed, a high and low correlation between Tin and Tout is reversed.

Abstract translation: 提供了以安全稳定的方式和高产率生产气溶胶，丙烯酸，甲基丙烯醛，甲基丙烯酸的方法，避免了由于原料气体出口处的温度导致的异常反应的发生现象 相对于在丙烯，异丁烯等的气相催化氧化反应管中填充的催化剂的温度，原料气体入口侧的温度显着高于原料气体入口侧的温度。 在使用在原料气体流动方向上形成有多个催化剂层的反应管的过程中，设计催化剂和催化剂填充进度，使得目的物的产率的原料转化率之间的关系 产物变得最大，并且最接近反应气体入口侧的催化剂层的最高温度和最接近反应气体出口侧的催化剂层的最高温度之间的高低相关性的原料转化率反转 满足0.5 @ Cmax-Ccrs @ 5的特定条件，其中Cmax：目标产物的产率变为最大的原料转化率; Ccrs：将催化剂层Zin的最高温度设为Tin时的原料转化率，将催化剂层Zout的最高温度设为Tout，将原料转化率变更为高，低相关 Tin和Tout之间是相反的。

公开(公告)号：US5929275A

公开(公告)日：1999-07-27

申请号：US853215

申请日：1997-05-09

Applicant: Koichi Wada ,  Akira Iwamoto ,  Yoshimasa Seo ,  Atsusi Sudo ,  Fumio Sakai ,  Kazuo Shiraishi ,  Hideaki Miki

Inventor： Koichi Wada ,  Akira Iwamoto ,  Yoshimasa Seo ,  Atsusi Sudo ,  Fumio Sakai ,  Kazuo Shiraishi ,  Hideaki Miki

IPC: B01J23/88 ,  B01J23/887 ,  B01J35/08 ,  B01J37/00 ,  B01J37/02 ,  C07B61/00 ,  C07C27/14 ,  C07C45/35 ,  C07C45/37 ,  C07C45/38 ,  C07C47/22 ,  C07C51/25 ,  C07C51/275 ,  C07C57/05 ,  C07C51/16 ,  B01J23/16 ,  C07C45/32

CPC classification number: C07C45/37 ,  B01J23/002 ,  B01J23/8876 ,  B01J37/0223 ,  C07C45/35 ,  C07C51/252 ,  B01J2523/00

Abstract: A catalyst for the production of unsaturated aldehyde and unsaturated acid, obtained by loading a catalytically active component on a carrier and calcining the loaded catalyst, characterized by an average particle diameter of the catalyst of 4 to 16 mm, an average particle diameter of the carrier of 3 to 12 mm, a calcining temperature of 520 to 600.degree. C. and an amount of the catalytically active component loaded on the carrier of 5 to 80% by weight �weight of the catalytically active component)/(weight of the catalytically active component+weight of the carrier+weight of a strength improver)!, and a process for producing unsaturated aldehyde and unsaturated acid with the catalyst.

Abstract translation: 用于生产不饱和醛和不饱和酸的催化剂，其通过将催化活性组分负载在载体上并煅烧负载的催化剂而获得，其特征在于催化剂的平均粒径为4至16mm，载体的平均粒径 3至12mm，煅烧温度为520-600℃，负载在载体上的催化活性组分的量为5-80重量％[催化活性组分的重量] /（催化活性组分的重量） 组分+载体重量+强度改进剂的重量）]以及用催化剂生产不饱和醛和不饱和酸的方法。

公开(公告)号：US4892832A

公开(公告)日：1990-01-09

申请号：US127651

申请日：1987-12-02

Applicant: Kiyotaka Omote ,  Yuichi Matsushima ,  Masami Taki ,  Harutomo Oshio ,  Kazuo Shiraishi

Inventor： Kiyotaka Omote ,  Yuichi Matsushima ,  Masami Taki ,  Harutomo Oshio ,  Kazuo Shiraishi

IPC: B01D35/00 ,  C12M1/26 ,  G01N33/02 ,  C12M1/12

CPC classification number: G01N33/02 ,  B01D35/00

Abstract: There is here provided a convenient bag used at the time when microorganisms which adhere to a specimen containing a solid material are extracted with a saline solution and are then examined. In this bag, a filter sheet is stuck to plastic film sidewalls so as to extend from the opening inlet to the bottom portion of the sidewalls, so that the bag is divided into two chambers. A specimen and a saline solution are poured into one of the two chambers, and the resulting extract is taken out by a pipet from another chamber.

Abstract translation: 这里提供了当用含有固体物质的样品附着的微生物用盐水溶液萃取时使用的方便的袋子，然后进行检查。 在该袋中，将过滤片粘贴到塑料膜侧壁上，以从侧壁的开口入口延伸到底部，使得袋被分成两个室。 将样品和盐水溶液倒入两个室中的一个，并且通过移液管从所述另一个室取出所得到的提取物。

公开(公告)号：US6028220A

公开(公告)日：2000-02-22

申请号：US117461

申请日：1998-07-28

Applicant: Koichi Wada ,  Yoshimasa Seo ,  Akira Iwamoto ,  Atsushi Sudo ,  Fumio Sakai ,  Kazuo Shiraishi ,  Hiroyoshi Nowatari

Inventor： Koichi Wada ,  Yoshimasa Seo ,  Akira Iwamoto ,  Atsushi Sudo ,  Fumio Sakai ,  Kazuo Shiraishi ,  Hiroyoshi Nowatari

IPC: B01J23/88 ,  B01J8/06 ,  B01J23/31 ,  B01J23/887 ,  C07B61/00 ,  C07C27/14 ,  C07C45/35 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C205/00 ,  C07C51/16

CPC classification number: C07C45/35 ,  B01J23/002 ,  B01J23/31 ,  B01J23/8876 ,  B01J8/06 ,  C07C51/252 ,  B01J2208/025 ,  B01J2523/00

Abstract: The present invention concerns a method for producing acrolein and acrylic acid by carrying out vapor phase catalytic oxidation of propylene with molecular oxygen or a gas containing molecular oxygen using a oxidation catalysts comprising Mo, Bi and Fe as an essentially element and a fixed bed multitubular reactor, which comprisesa) using a plurality of supported catalysts having different activities, which was obtained, for example, by different calcination method in the production process of the supported catalysts,b) setting a catalyst layer in a reaction tube, which is formed by dividing it into plural portions in the tube axial direction, andc) arranging the aforementioned plural supported catalysts in such order that the activity becomes high toward the outlet from the inlet of the material gas in the reaction tube axial direction.According to the present invention, the generation of hot spot can be avoided and over oxidation reaction can be avoided and the acrolein and acrylic acid are produced constantly for a prolonged period of time.

Abstract translation: PCT No.PCT / JP97 / 04402 Sec。 371日期：1998年7月28日 102（e）日期1998年7月28日PCT 1997年12月2日PCT PCT。 第WO98 / 24746号公报 日期1998年6月11日本发明涉及通过使用包含Mo，Bi和Fe作为基本元素的氧化催化剂，通过用分子氧或含有分子氧的气体进行丙烯的气相催化氧化来生产丙烯醛和丙烯酸的方法， 一种固定床多管反应器，其包括a）使用多种活性不同的负载催化剂，其通过例如在负载型催化剂的制备方法中通过不同的煅烧方法获得，b）将催化剂层设置在反应管 通过在管轴方向上分成多个部分而形成，以及c）按照反应管轴向从原料气体的入口出口的活性变高的顺序排列上述多个负载型催化剂。 根据本发明，可以避免产生热点，可以避免过度氧化反应，并且持续长时间地生产丙烯醛和丙烯酸。

公开(公告)号：US5959143A

公开(公告)日：1999-09-28

申请号：US737028

申请日：1996-10-30

Applicant: Hideki Sugi ,  Fumio Sakai ,  Koichi Wada ,  Kazuo Shiraishi ,  Toshitake Kojima ,  Atsushi Umejima ,  Yoshimasa Seo

Inventor： Hideki Sugi ,  Fumio Sakai ,  Koichi Wada ,  Kazuo Shiraishi ,  Toshitake Kojima ,  Atsushi Umejima ,  Yoshimasa Seo

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/887 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02 ,  C07B61/00 ,  C07C51/25 ,  C07C57/055 ,  C07C51/235 ,  B01J23/22

CPC classification number: B01J37/0045 ,  B01J23/002 ,  B01J23/8877 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/108 ,  C07C51/252 ,  B01J2523/00 ,  B01J37/0236

Abstract: A catalyst having a high activity and mechanical strength and a process for preparing it are provided. The catalyst comprises molybdenum, vanadium, copper and antimony as essential components. The peak in X-ray diffractometry of the catalytically active component with Cu--K.alpha. line is largest at 22.2.+-.0.30.degree. (2.theta.).

Abstract translation: PCT No.PCT / JP96 / 00506 Sec。 371日期1996年10月30日 102（e）1996年10月30日PCT PCT 1996年3月1日PCT公布。 公开号WO96 / 27437 日本1996年9月12日提供具有高活性和机械强度的催化剂及其制备方法。 催化剂包括钼，钒，铜和锑作为必需组分。 具有Cu-Kα线的催化活性组分的X射线衍射峰值在22.2±0.30°（2θ）处最大。

公开(公告)号：US5716895A

公开(公告)日：1998-02-10

申请号：US867283

申请日：1997-06-02

Applicant: Hideki Sugi ,  Kazuo Shiraishi ,  Atsushi Sudo

Inventor： Hideki Sugi ,  Kazuo Shiraishi ,  Atsushi Sudo

IPC: B01J27/28 ,  B01J38/74 ,  B01J20/34

CPC classification number: B01J27/285 ,  B01J38/74

Abstract: A simple and excellent process for the regeneration of heteropolyacid catalysts can be provided. A heteropolyacid catalyst, e.g. a phosphomolybdic acid catalyst, whose activity has been lowered can be regenerated by dissolving and/or suspending it in an aqueous medium and then treating with an inorganic ion-exchange material, e.g. crystalline antimonic acid.

Abstract translation: 可以提供简单且优异的杂多酸催化剂再生方法。 杂多酸催化剂，例如 其活性降低的磷钼酸催化剂可以通过将其溶解和/或悬浮在水性介质中再生，然后用无机离子交换材料，例如， 结晶锑酸。

公开(公告)号：US06852203B1

公开(公告)日：2005-02-08

申请号：US09402112

申请日：1998-03-24

Applicant: Shojiro Kawakami ,  Hiroyuki Sakaki ,  Kazuo Shiraishi

Inventor： Shojiro Kawakami ,  Hiroyuki Sakaki ,  Kazuo Shiraishi

IPC: G02B5/18 ,  G02B6/12 ,  G02B6/122 ,  G02B6/13 ,  H01S5/00 ,  H01S5/10 ,  H01S5/20 ,  C23C14/34 ,  B32B3/12

CPC classification number: B82Y20/00 ,  G02B6/12002 ,  G02B6/1225 ,  Y10T428/24165

Abstract: A three-dimensional periodical structure whose period is about 1 μm or smaller is provided. At least two kinds of films which have two-dimensionally substantially periodical projections are successively formed in layers substantially periodical to construct structure which is substantially three-dimensionally periodical. For instance, the films are made of materials different in refractive index. The three-dimensional periodical structure whose period is about 1 μm or smaller can be obtained by a simple fabricating method. By this structure, the propagation of a wave with a specific wavelength in many solid angular directions including several axial directions parallel to the plane and the thickness direction of the layers can be cut off.

Abstract translation: 提供了周期为1m或更小的三维周期结构。 至少两种具有二维基本上周期性的突起的膜基本周期地依次形成，以构造基本上三维周期的结构。 例如，膜由折射率不同的材料制成。 周期约为1um或更小的三维周期结构可以通过简单的制造方法获得。 通过这种结构，可以切断具有特定波长的波在许多固体角方向上的传播，包括平行于平面的几个轴向和层的厚度方向。

公开(公告)号：US5446816A

公开(公告)日：1995-08-29

申请号：US283959

申请日：1994-08-01

Applicant: Kazuo Shiraishi ,  Kazuhito Matsumura ,  Isamu Oishi ,  Katsuo Ebine

Inventor： Kazuo Shiraishi ,  Kazuhito Matsumura ,  Isamu Oishi ,  Katsuo Ebine

IPC: G02B6/02 ,  G02B6/255 ,  G02B6/32 ,  G02B6/42

CPC classification number: G02B6/322 ,  G02B6/2552 ,  G02B6/4203

Abstract: An optical fiber having a lens formed at an end thereof comprises a fiber body including a core and a cladding, and an incident light guide portion having a uniform refractive index and integrally formed at an end portion of the fiber body, wherein the incident light guide portion has a convex surface, and the core has a distal end located within the incident light guide portion at a position close to a focal point of the incident light guide portion. When the incident light guide portion is arranged in alignment with a light source such that an extremity of the convex surface of the incident light guide portion faces a light-emitting surface of the light source, assuming that an X-Y coordinate system is established wherein the X axis coincides with the optical axis of the fiber body and the Y axis coincides with a radius direction of the fiber body, the relationship expressed by the following equation is fulfilled: ##EQU1## where coordinates of the extremity of the convex surface of the incident light guide portion are (0, 0), coordinates of the light-emitting surface of the light source are (-k, 0), coordinates of the distal end of the core are (L, 0), coordinates of an incident point at which light from the light-emitting surface of the light source falls upon the convex surface of the incident light guide portion are (z, r), and the refractive index of the incident light guide portion is n. Accordingly, no phase difference of laser beams occurs when the optical fiber is connected to a semiconductor laser, making it possible to provide a high coupling efficiency optical fiber.

Abstract translation: 具有在其端部形成的透镜的光纤包括具有芯和包层的纤维体和具有均匀折射率并且一体地形成在纤维体的端部的入射光导部，其中入射光导 所述芯具有位于所述入射光导部内的远端，所述远端位于所述入射光导部的焦点附近的位置。 当入射光导部分与光源对准地布置，使得入射光导部分的凸表面的末端面向光源的发光表面时，假设建立XY坐标系，其中X 轴与光纤体的光轴重合，Y轴与纤维体的半径方向一致，满足下式所表示的关系：入射光的凸面的末端的坐标 引导部分为（0,0），光源的发光面的坐标为（-k，0），芯的前端的坐标为（L，0），入射点的坐标为 来自入射光导部的凸面的光源的发光面的光为（z，r），入射导光部的折射率为n。 因此，当光纤连接到半导体激光器时，不会发生激光束的相位差，使得可以提供高耦合效率的光纤。