摘要:
In a method for oxidizing 1,1-bis-(3,4-dimethylphenyl)-alkane with nitric acid in a pressure vessel to produce 3,3′,4,4′-benzophenone tetracarboxylic acid with concurrent formation of nitric oxide, passing nitric oxide from the pressure vessel into an absorption vessel and reacting nitric oxide in the absorption vessel with molecular oxygen and water to produce an aqueous nitric acid solution prevents discharge of nitric oxide, avoids the risk of oxygen inhibiting the nitric acid oxidation and reduces nitric acid consumption when the nitric acid from the absorption vessel is used for oxidizing the 1,1-bis-(3,4-dimethylphenyl)-alkane.
摘要:
A process for preparing a coal derivative comprising a mixture of monocyclic, polycyclic, multifunctional carboxylic acids which comprises contacting an aqueous slurry containing coal with aqueous nitric acid and then drying the resulting product to remove water therefrom.
摘要:
MIXTURES OF ALIPHATIC CARBOXYLIC ACIDS CONSISTING MAINLY OF ACETIC AND PROPIONIC ACIDS, WOTH SOME OXALIC ACID, ARE OBTAINED BY OXIDISING 1-BUTENE, ALONE OR WITH 2-BUTENE, WITH NITRIC ACID.
摘要:
A CONTINUOUS PROCESS FOR THE OXIDATION OF METHYL-BENZENE HYDROCARBONS TO BENZENECARBOXYLIC ACIDS CARRIED OUT AT ATMOSPHERIC PRESSURE IN THE PRESENCE OF AN AROMATIC SOLVENT AND NITROGEN DIOXIDE.
摘要:
ALKYL BENZENES IN WHICH THE ALKYL GROUP IS OF THE SECONDARY OR TERTIARY TYPE AND WHICH HAVE HALOGEN OR METHYL SUBSTITUENTS IN THE 2,4- OR 2,3,4-POSITIONS MAY BE CATALYTICALLY ISOMERIZED IN GOOD YIELD TO THE CORRESPONDING 3,5AND 3,4,5-SUBSTITUTED ALKYL BENZENES. CATALYSTS FOR THE ISOMERIZATION ARE HAIBRCL3, HALBR2CL2, HALBR3CL AND HALBR4. THE RESULTING PRODUCTS ARE OF PARTICULAR INTEREST AS PRECURSORS FOR THE CORRESPONDING BENZOIC ACIDS.