摘要:
Increasing the endcap level to a level greater than about 90% for Optical Quality (OQ) Melt Polycarbonate significantly reduces the as-molded static charge for injection molded parts for Optical Disc applications. The use of resins with higher endcap levels in combination with antistatic additives provides a highly robust formulation suitable for even the most demanding emerging formats as Digital Versatile Disc (DVD) and in all commercial Optical media molding machines. Thus, optical quality polycarbonates are prepared by performing a base-catalyzed polymerization of a diaryl carbonate and a dihydric phenol under conditions effective to produce a polycarbonate product having an endcap level of 90% or greater.
摘要:
Increasing the endcap level to a level greater than about 90% for Optical Quality (OQ) Melt Polycarbonate significantly reduces the as-molded static charge for injection molded parts for Optical Disc applications. The use of resins with higher endcap levels in combination with antistatic additives provides a highly robust formulation suitable for even the most demanding emerging formats as Digital Versatile Disc (DVD) and in all commercial Optical media molding machines. Thus, optical quality polycarbonates are prepared by performing a base-catalyzed polymerization of a diaryl carbonate and a dihydric phenol under conditions effective to produce a polycarbonate product having an endcap level of 90% or greater.
摘要:
A polycarbonate production method, characterized in that a dihydroxy compound and a carbonic acid diester are subjected to melt polycondensation in the presence of a catalyst containing an alkali metal compound and/or alkaline-earth metal compound in an amount of 1×10−8 to 1×10−5 mol per mole of dihydroxy compound; wherein a sulfonic acid ester compound and a transition metal scavenger are also added to the reaction product; and wherein the polycarbonate is treated at a reduced pressure.
摘要:
This specification discloses polycarbonates for optical use. These polycarbonates are prepared by reacting a bisphenol and carbonic diester in the presence of an alkaline compound catalyst. These polycarbonates have: (i) an intrinsic viscosity (IV) as determined at 20° C. in methylene chloride of between 0.34 and 0.38; (ii) a glass transition temperature (Tg) as determined by DSC of between 143 and 147° C.; and (iii) an intrinsic viscosity (IV) and glass transition temperature (Tg) ratio complying with the following general formula (A): IV×95.888+107.9
摘要:
This specification describes an optical polycarbonate composition obtained by the melt polycondensation of a bisphenol and a carbonic diester in the presence of an alkaline compound catalyst, wherein said optical polycarbonate composition comprises (i) a compound expressed by the following Formula [A] in an amount of 30 to 2000 ppm; (ii) a compound expressed by the following Formula [B] in an amount of 30 to 4000 ppm; and (iii) a compound expressed by the following Formula [C] in an amount of 80 to 8000 ppm. The polycarbonate composition has a viscosity average molecular weight of between 12,000 and 18,000, and the portion with a molecular weight (as measured by GPC) of 1000 or less accounts for 0.5 to 1.5 wt %.
摘要:
A method of recycling fusible polycondensation resin waste in a fusion polymerization apparatus is disclosed. The method of recycling polycondensation resins comprises adding polycondensation resin waste directly to a fusion polymerization apparatus to carry out the polycondensation reaction. The polycondensation resin waste may be supplied from any point of the polycondensation apparatus to carry out the exchange reaction and/or the polycondensation reaction between the resin being prepared in the apparatus and the resin waste supplied. The method may be carried out in a continuous fusion polycondensation system with more than one polymerization reactor connected in series. The polycondensation resin waste may be supplied from the outlet of a polymerization reactor during the initial stage of the polycondensation process (oligomerisation process) to carry out the exchange reaction and/or the polycondensation reaction between the resin waste and the resin being prepared in the later stage of the polycondensation process in a continuous fusion polycondensation apparatus with more than one polymerization reactor connected in series.
摘要:
The present invention provides a method for making a polycarbonate composition. The polycarbonate is prepared by melt synthesis using a sulfur-containing acid compound to at least partially quench the melt catalyst. The polycarbonate composition comprises said polycarbonate, phosphorous acid, further sulfur-containing acid compound and an ester derived from a mono-fatty acid and a polyhydric alcohol.
摘要:
The present invention provides a method for making a polycarbonate composition. The polycarbonate is prepared by melt synthesis using a sulfur-containing acid compound to at least partially quench the melt catalyst. The polycarbonate composition comprises said polycarbonate, phosphorous acid, further sulfur-containing acid compound and an ester derived from a mono-fatty acid and a polyhydric alcohol.
摘要:
An aromatic polycarbonate composition contains aromatic polycarbonate in which a ratio of the phenolic end group to the non-phenolic end group is at least 1/19, and a copolymer having epoxy or oxazolinyl group, aromatic vinyl-diene-vinyl cyanide copolymer or aromatic polyester, or glass filler. Compatability between the specific aromatic polycarbonate and the other resin, weld strength, melt stability or adhesion to glass filler are improved.
摘要:
The ultraviolet ray irradiation devices are attached to a carriage having a print head that ejects the ultraviolet curable ink, and include a plurality of ultraviolet light sources that irradiate ultraviolet rays onto ink coating ejected on a print sheet by the print head. An ultraviolet ray of the ultraviolet light source that irradiates the ultraviolet ray onto the print sheet in the vicinity of the print head has a wavelength shorter than an ultraviolet ray of the ultraviolet light source that irradiates the ultraviolet ray onto the print sheet apart from the vicinity of the print head along the moving direction of the carriage. The ultraviolet ray irradiation device is capable of sufficiently curing a plurality of ultraviolet curable ink adhered on a recording medium without incurring a problem of blurring or color mixing for a multiple-color printing process such as a full-color printing process.