摘要:
A diaryl carbonate with a high degree of purity is produced at a high yield by (A) subjecting (a) a diaryl oxalate and a phenol compound or (b) an alkylaryl oxalate to transesterification reaction in one or two stages in the presence of a catalyst to prepare a diaryl oxalate, while removing a by-product from the reaction system; (B) collecting the diaryl oxalate from the resultant reaction product mixture of the step (A); (C) subjecting the diaryl oxalate to a decarbonylation reaction, preferably in the presence of a phosphorous compound-containing catalyst, to convert the diaryl oxalate to a corresponding diaryl carbonate, while removing a reaction by-product comprising carbon monoxide from the reaction system; and (D) collecting the diaryl carbonate from the reaction product mixture of the step (C).
摘要:
A diaryl carbonate with a high degree of purity is produced at a high yield by (A) subjecting (a) a diaryl oxalate and a phenol compound or (b) an alkylaryl oxalate to transesterification reaction in one or two stages in the presence of a catalyst to prepare a diaryl oxalate, while removing a by-product from the reaction system; (B) collecting the diaryl oxalate from the resultant reaction product mixture of the step (A); (C) subjecting the diaryl oxalate to a decarbonylation reaction, preferably in the presence of a phosphorous compound-containing catalyst, to convert the diaryl oxalate to a corresponding diaryl carbonate, while removing a reaction by-product comprising carbon monoxide from the reaction system; and (D) collecting the diaryl carbonate from the reaction product mixture of the step (C).
摘要:
A novel crystalline adduct of diphenyl oxalate and phenol in a molar ratio of 1:2 and having a high purity is produced by melting a mixture containing diphenyl oxalate and phenol at a temperature of 100.degree. C. or more; cooling the melt to a temperature of less than 100.degree. C. to allow a resultant adduct of diphenyl oxalate and phenol in a molar ratio of 1:2 to crystallize and deposit from the melt; and collecting the crystalline adduct. Diphenyl oxalate with a high purity is produced by melting the crystalline adduct to dissociate it into diphenyl oxalate and phenol, and evaporating away the dissociated phenol from the melt to collect the dissociated diphenyl oxalate.
摘要:
The present invention relates to a process for producing a diaryl oxalate, characterized in that an alkylaryl oxalate is subjected to a disproportionation reaction in the presence of a disproportionation catalyst, thereby to produce a diaryl oxalate while removing a by-product comprising a dialkyl oxalate.The production process of the present invention is advantageous in that the kinds of the by-products are fewer than that in conventional production process for diaryl oxalate, and thus can be practically utilized in industry, and the diaryl oxalates such as diphenyl oxalate, produced by the production process of the present invention are very important industrial materials for producing chemical products such as carbamates.
摘要:
Disclosed is a process for preparing carbonic diester comprising the formation of carbonic diester by the vapor phase catalytic reaction of an alkyl nitrite and carbon monoxide in the presence of a solid catalyst, wherein platinum group metal ion in the solid catalyst is exchanged on an ion exchange zeolite carrier.
摘要:
An ester compound, for example, carbonic acid ester or succinic acid ester, is produced by catalytically reacting, in gas phase, carbon monoxide with a nitrous acid ester and optionally an olefin in the presence of a catalyst and in the presence of a chlorine-containing substance, bringing the reaction product-containing mixed gas into contact with a solid catalyst such as activated carbon or inorganic oxide to reduce the content of the chlorine-containing substance, cool-condensing the resultant mixed gas, and collecting the target ester compound from the condensed liquid.
摘要:
[Object] To control a protrusion amount which indicates an amount of protrusion of an image protruding to a surrounding portion of a sheet for printing when marginless printing is performed in accordance with the XHTML-print specification.[Solving Means] The UI processor 11 accepts designation of a size of a sheet for printing and designation of an amount of protrusion from the sheet for printing when marginless printing is performed. The XHTML document generation unit 12 generates an XHTML document including a size of an image to be printed which is specified in accordance with a scale factor used when marginless printing is performed in accordance with the XHTML-print specification, a print starting position of the image to be printed which is specified in accordance with the scale factor and the specified amount of protrusion, and designation of marginless printing.
摘要:
A variable displacement oil pump includes: a variable displacement mechanism that is able to change a discharge amount per rotation of an input shaft. The variable displacement mechanism includes a pump housing, an oil pressure chamber provided in the pump housing, and a capacity adjustment member displaced by oil pressure from the oil pressure chamber. The capacity adjustment member is configured to be operated when receiving control oil pressure that is supplied from a control valve to the oil pressure chamber. The pump housing has an oil release hole that is opened to face the oil pressure chamber and that penetrates a wall section of the pump housing to partially release oil.
摘要:
An oil pump includes: an inner rotor rotatable with a drive shaft in a unified manner on a drive-rotation axis; an outer rotor which has inner teeth configured to engage with outer teeth of the inner rotor and is rotatable about a driven axis eccentric to the drive-rotation axis; and an adjustment ring for rotatably supporting the outer rotor. A guide means which allows the adjustment ring to rotate about the driven axis, while allowing the driven axis to revolve about the drive-rotation axis, is formed of: first and second arm portions provided on the adjustment ring; and first and second guide faces with which the first and second arm portions are brought into slidable contact.
摘要:
A valve timing control device includes a driving side rotational member, a driven side rotational member, a fluid pressure chamber, a parting portion dividing the fluid pressure chamber into an advanced angle chamber and a retarded angle chamber, a restriction member, a restriction recessed portion for restricting a displacement of a relative rotational phase within a range between a most advanced angle phase or a most retarded angle phase and a predetermined phase when the restriction member is inserted into the restriction recessed portion, and a restriction cancellation passage, wherein a communication between the accommodation portion and one of the advanced angle chamber and the retarded angle chamber via the cancellation passage is interrupted at least when the restriction member contacts one of end portions of the restriction recessed portion, and the restriction member is restricted so as not to move over the other one of the end portions.