公开(公告)号：US5055373A

公开(公告)日：1991-10-08

申请号：US414342

申请日：1989-09-29

申请人： Keiso Saeki ,  Fumiaki Shinozaki ,  Toshiaki Endo

发明人： Keiso Saeki ,  Fumiaki Shinozaki ,  Toshiaki Endo

IPC分类号： G03F7/004 ,  B41M5/28 ,  B41M5/30 ,  G03C1/00 ,  G03C1/675 ,  G03C1/73 ,  G03C5/56 ,  G03F7/00

CPC分类号： G03C1/002 ,  G03F7/002 ,  Y10S430/114 ,  Y10S430/117 ,  Y10T428/2984 ,  Y10T428/2985

摘要： A multicolor recording material is disclosed, which comprises a support having provided thereon a coating layer comprising two or more kinds of microcapsules each containing at least a leuco dye capable of being colored by oxidation and a photo oxidizing agent outside said microcapsules, and a reducing agent as necessary components, with two or more leuco dyes capable of forming different colors from each other being retained in different kinds of said microcapusles respectively composed of walls of high polymers having different glass transition points.

摘要翻译： 公开了一种多色记录材料，其包括其上设置有包含两种或更多种微胶囊的涂层的载体，每个微胶囊至少包含能够通过氧化着色的无色染料和在所述微胶囊外部的光氧化剂，还原剂 作为必要组分，具有能够形成彼此不同颜色的两种或更多种无色染料保留在分别由具有不同玻璃化转变点的高聚合物壁组成的不同种类的所述微型碳氢化合物中。

公开(公告)号：US5035974A

公开(公告)日：1991-07-30

申请号：US366392

申请日：1989-06-15

申请人： Keiso Saeki ,  Toshiaki Endo

发明人： Keiso Saeki ,  Toshiaki Endo

IPC分类号： G03C1/00

CPC分类号： G03C1/002

摘要： A light-image forming material comprising a support having provided thereon a light-image forming layer comprising microcapsules containing an oxidative-developable leuco dye and a photo-oxidizing agent, and a reducing agent as essential ingredients, wherein the material also includes a covering layer or intermediate layer containing a film-forming high-molecular binder and/or an inorganic or organic pigment.

摘要翻译： 一种光图像形成材料，其包括在其上设置有包含含有氧化显影性无色染料和光氧化剂的微胶囊和作为必需成分的还原剂的光图像形成层的载体，其中所述材料还包括覆盖层 或含有成膜高分子粘合剂和/或无机或有机颜料的中间层。

公开(公告)号：US4962009A

公开(公告)日：1990-10-09

申请号：US257580

申请日：1988-10-14

申请人： Shintaro Washizu ,  Jun Yamaguchi ,  Fumiaki Shinozaki ,  Akihiro Shimomura ,  Toshimasa Usami ,  Toshiaki Endo ,  Keiso Saeki

发明人： Shintaro Washizu ,  Jun Yamaguchi ,  Fumiaki Shinozaki ,  Akihiro Shimomura ,  Toshimasa Usami ,  Toshiaki Endo ,  Keiso Saeki

IPC分类号： G03C1/00 ,  G03C1/73 ,  G03C5/56

CPC分类号： G03C1/732 ,  G03C1/002 ,  G03C5/56

摘要： An image-forming material comprising: (a) microcapsules, in which at least one leuco dye capable of developing a color by oxidation and at least one photooxidizing agent (preferably a combination of a lophine dimer and an organic halogeno-compound) are enclosed together, and (b) at least one reducing agent not enclosed in the microcapsules (preferably present in the form of an emulsified dispersion), thereby achieving image formation in a completely dried condition, and ensuring excellent freshness keeping property, image reproducibility and fixability.

摘要翻译： 一种图像形成材料，包括：（a）微胶囊，其中至少一种能够通过氧化形成颜色的至少一种无色染料和至少一种光氧化剂（优选的是二氢卟吩和有机卤代化合物的组合）被封闭在一起 ，和（b）未包封在微胶囊中的至少一种还原剂（优选以乳化分散体的形式存在），从而在完全干燥的条件下实现图像形成，并且确保优异的保鲜性，图像再现性和定影性。

公开(公告)号：US5051333A

公开(公告)日：1991-09-24

申请号：US541865

申请日：1990-06-21

申请人： Naoto Yanagihara ,  Ken Iwakura ,  Tosiaki Endo ,  Keiso Saeki

发明人： Naoto Yanagihara ,  Ken Iwakura ,  Tosiaki Endo ,  Keiso Saeki

IPC分类号： G03C1/00 ,  G03F7/004

CPC分类号： G03C1/002 ,  G03F7/002

摘要： An optical image-recording material comprising:(a) microcapsules, in which at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent are enclosed together, and (b) at least one reducing agent not enclosed in the microcapsules, or(c) microcapsules, in which at least one reducing agent is enclosed, and (d) both at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent not enclosed in the microcapsules,wherein the microcapsules have capsule walls made from a material which lowers its permeability barrier to at least one component selected from the photo-oxidizing agent and the reducing agent when the capsule wall material is heated above its glass transition temperature, and the leuco dye is a xanthene compound having an N-substituted anilino group substituted by an electron attracting group.

摘要翻译： 一种光学图像记录材料，包括：（a）微胶囊，其中至少一种能够通过氧化形成颜色的无色染料和至少一种光氧化剂被包封在一起，和（b）至少一种不包含的还原剂 在微胶囊中，或（c）其中封闭有至少一种还原剂的微胶囊，和（d）能够通过氧化形成颜色的至少一种无色染料和不包封在微胶囊中的至少一种光氧化剂 其中，所述微胶囊具有由将所述胶囊壁材料加热到高于其玻璃化转变温度时将其对所述光氧化剂和还原剂中的至少一种成分的透过性阻挡性降低的材料制成的胶囊壁，所述无色染料为 具有被吸电子基团取代的N-取代苯胺基的呫吨化合物。

公开(公告)号：US4870048A

公开(公告)日：1989-09-26

申请号：US179356

申请日：1988-04-08

申请人： Katsumi Matsuoka ,  Shojiro Sano ,  Keiso Saeki ,  Masanobu Takashima ,  Ken Iwakura

发明人： Katsumi Matsuoka ,  Shojiro Sano ,  Keiso Saeki ,  Masanobu Takashima ,  Ken Iwakura

IPC分类号： B41M5/333 ,  B41M5/155 ,  C07F15/04 ,  C07F15/06

CPC分类号： B41M5/155 ,  Y10S428/914 ,  Y10T428/277

摘要： A color developer sheet which brings about color development by contact with a substantially colorless electron-donating color former, where said sheet contains an organometallic compound represented by the following general formula (I), (II) or (III) to enhance light resistance and stability of the color product obtained by the color development: ##STR1## wherein M represents a nickel atom, a copper atom, a cobalt atom, or a zinc atom; X.sub.1 and X.sub.2 each represents an oxygen atom, a sulfur atom, or --NR.sub.5 --, in which R.sub.5 represents a hydrogen atom, an alkyl group, an aryl group, or a hydroxyl group; X.sub.3 represents a hydroxyl group, or a mercapto group; Y represents an oxygen atom, a sulfur atom, or --CHR.sub.6, in which R.sub.6 represents a hydrogen atom, an alkyl group, or an aryl group; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, a halogen atom, a cyano group, or an alkyl, aryl, cycloalkyl or heterocyclyl group attached to the carbon atom directly or via a divalent linkage group, or at least either combination of R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 may be connected to each other to form a 5- or 6-membered ring together with the carbon atoms; and Z represents an organic ligand which forms a complex by binding to M via its hetero atom.

摘要翻译： 一种通过与基本上无色的给电子成色剂接触而引起显色的彩色显影片，其中所述片含有由以下通式（I），（II）或（III）表示的有机金属化合物，以提高耐光性， （II）其中M表示镍原子，铜原子，钴原子或锌原子;（III）其中M表示镍原子， X 1和X 2各自表示氧原子，硫原子或-NR 5 - ，其中R 5表示氢原子，烷基，芳基或羟基; X3表示羟基或巯基; Y表示氧原子，硫原子或-CHR6，其中R6表示氢原子，烷基或芳基; R 1，R 2，R 3和R 4各自表示直接或经由二价连接基团连接到碳原子上的氢原子，卤原子，氰基或烷基，芳基，环烷基或杂环基，或至少 R 1和R 2和/或R 3和R 4可以彼此连接以与碳原子一起形成5-或6-元环; Z表示通过其杂原子与M结合形成络合物的有机配体。

公开(公告)号：US4725315A

公开(公告)日：1988-02-16

申请号：US869769

申请日：1986-06-02

申请人： Shojiro Sano ,  Keiso Saeki

发明人： Shojiro Sano ,  Keiso Saeki

IPC分类号： B41M5/128 ,  B41M5/22

CPC分类号： B41M5/128

摘要： A desensitizer composition is described, comprising a desensitizer, a 2,2,6,6-tetramethylpiperidine derivative, and additives.

摘要翻译： 描述了一种脱敏剂组合物，其包含脱敏剂，2,2,6,6-四甲基哌啶衍生物和添加剂。

公开(公告)号：US4601920A

公开(公告)日：1986-07-22

申请号：US582500

申请日：1984-02-22

申请人： Hirofumi Mitsuo ,  Keiso Saeki

发明人： Hirofumi Mitsuo ,  Keiso Saeki

IPC分类号： B41M5/155 ,  B41M5/22

CPC分类号： B41M5/155

摘要： A process for preparing a color developer sheet for pressure-sensitive recording is disclosed. The sheet is comprised of a coating solution on a support, said coating solution being prepared by dissolving an aromatic carboxylic acid metal salt in an organic solvent and then emulsifying the resulting solution in water. The organic solvent is such that the viscosity of a 50% by weight solution of the aromatic carboxylic acid metal salt in the organic solvent falls within the range of from 200 to 4,000 centipoises. This color developer sheet shows a high color-forming rate and its coated surface is free of irregularity and includes a consistent amount of coating material.

摘要翻译： 公开了一种用于制备用于压敏记录的彩色显影片的方法。 片材由载体上的涂布溶液组成，所述涂布溶液通过将芳族羧酸金属盐溶解在有机溶剂中，然后将所得溶液乳化在水中来制备。 有机溶剂使得芳族羧酸金属盐在有机溶剂中的50重量％溶液的粘度在200至4,000厘泊的范围内。 该彩色显影片显示出高的成色速率，其涂布表面没有不规则性并且包括一定量的涂料。

公开(公告)号：US4016098A

公开(公告)日：1977-04-05

申请号：US532573

申请日：1974-12-13

申请人： Keiso Saeki ,  Hiroharu Matsukawa

发明人： Keiso Saeki ,  Hiroharu Matsukawa

IPC分类号： B41M5/165 ,  B01J13/10 ,  B01J13/20 ,  B01J13/02

CPC分类号： B01J13/206 ,  Y10S514/963 ,  Y10T428/2984 ,  Y10T428/2987

摘要： In a process for producing microcapsules which comprises microencapsulating hydrophobic oil droplets by complex coacervation using at least two hydrophilic colloids having opposite electric charges and being ionizable in water with at least one of the colloids being gellable, the improvement comprising hardening the coacervate wall by the presence of an oxidation product of a polysaccharide as a hardening agent and adjusting the pH.

摘要翻译： 在制备微胶囊的方法中，其包括使用至少两种具有相反电荷的亲水胶体通过复合凝聚来微胶囊化疏水性油滴，并且在水中可离子化，其中至少一种胶体是可凝胶化的，其改进包括通过存在下硬化凝聚壁 的多糖作为硬化剂的氧化产物并调节pH。

公开(公告)号：US3965033A

公开(公告)日：1976-06-22

申请号：US438518

申请日：1974-01-31

申请人： Hiroharu Matsukawa ,  Keiso Saeki

发明人： Hiroharu Matsukawa ,  Keiso Saeki

IPC分类号： A61K8/11 ,  A61K9/50 ,  A61Q13/00 ,  B01J13/08 ,  B01J13/02

CPC分类号： A61K8/11 ,  A61K9/50 ,  A61Q13/00 ,  B01J13/08 ,  A61K2800/412 ,  Y10T428/2984 ,  Y10T428/2987

摘要： In a process for producing oil-containing microcapsules by coacervation comprisingA. introducing a fine powder or hydrophobic liquid into a high molecular weight electrolytic wall-forming colloid;B. coacervating the resulting dispersion or emulsion;C. cooling the resulting coacervate to gel it and form the wall of said microcapsules; andD. hardening said wall of said microcapsules; the improvement which comprises adding a phenolic compound to the system.

摘要翻译： 在通过凝聚制备含油微胶囊的方法中，包括A.将精细粉末或疏水性液体引入高分子量的电解液形成胶体中; B.调整分散剂或乳化剂; C.冷却结晶剂，使其凝固，形成微生物的壁; 和D.硬化表面微球; 包含将酚醛化合物加入系统的改进。

公开(公告)号：US3956172A

公开(公告)日：1976-05-11

申请号：US380441

申请日：1973-07-18

申请人： Keiso Saeki ,  Hiroharu Matsukawa

发明人： Keiso Saeki ,  Hiroharu Matsukawa

IPC分类号： B01J13/10 ,  B01J13/20 ,  B41M5/165 ,  B01J13/02

CPC分类号： B01J13/206 ,  B01J13/10 ,  B41M5/165 ,  Y10T428/2984 ,  Y10T428/2987

摘要： In a process for hardening microcapsules produced by microencapsulating hydrophobic oil droplets using a complex coacervation process with gelatin as one of the hydrophilic colloids: including the steps of1. emulsifying a water-immiscible oil in an aqueous solution of at least one first hydrophilic colloid ionizable in water and admixing an aqueous solution of at least one second hydrophilic colloid having an electric charge opposite to that of said first colloid,2. causing coacervation of said colloids to occur by adding water thereto or adjusting the pH thereof to form coacervates,3. cooling said coacervates to cause gelling thereof,4. adjusting the pH to alkalinity and adding a hardening agent sequentially or simultaneously,5. increasing the temperature so as to cause hardening, the improvement wherein glyoxal or glutaraldehyde in combination with formaldehyde is present during step (4).

摘要翻译： 在通过使用明胶作为亲水胶体之一的复合凝聚方法微胶囊化疏水性油滴而制备的微胶囊的方法中，包括以下步骤：1.在至少一个第一亲水胶体酸性的水溶液中模拟水不溶性油 在水中并加入至少一个具有电荷充电器的第二个水凝胶的水溶液到达第一个胶体，2.通过添加水来引起凝胶的酸化，或调节其pH以形成凝聚层。 冷却保存原因导致凝胶化，4.将PH调节至碱度并依次或同时加入硬化剂; 5.增加温度，以致导致硬化，在步骤中存在与甲醛组合的GLOORA或GLUTARALDEHYDE的改进（ 4）。