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    Color photographic material
    5.
    发明授权
    Color photographic material 失效
    彩色照相材料

    公开(公告)号：US4163670A

    公开(公告)日：1979-08-07

    申请号：US462842

    申请日：1974-04-22

    申请人： Keisuke Shiba ,  Takeshi Hirose ,  Atsuaki Arai ,  Akio Okumura ,  Yukio Yokota

    发明人： Keisuke Shiba ,  Takeshi Hirose ,  Atsuaki Arai ,  Akio Okumura ,  Yukio Yokota

    IPC分类号： G03C7/38 ,  C09B26/02 ,  G03C7/333 ,  G03C1/76 ,  G03C1/40

    CPC分类号： G03C7/3335

    摘要： A color photographic material having on a support at least a photographic emulsion containing an excellent colored coupler represented by the general formula ##STR1## wherein R.sub.1 represents an aryl group or a heterocyclic group; R.sub.2 represents a phenyl group having a halogen atom, an alkoxy group, or an aryloxy group at the ortho-position to the imino group bonded to the 3-position of the pyrazolone ring of the coupler; and R.sub.3 represents a phenyl group having a hydroxyl group at the para-position to the azo group of the coupler; the coupler having a hydrophobic diffusion-resisting group in the molecule thereof.

    摘要翻译： 一种彩色照相材料，其在载体上至少含有由通式“IMAGE”表示的优异的着色成色剂的照相乳剂，其中R1表示芳基或杂环基; R2表示在与成色剂的吡唑啉酮环的3-位键合的亚氨基的邻位具有卤素原子，烷氧基或芳氧基的苯基; 并且R 3表示在耦合剂的偶氮基的对位具有羟基的苯基; 该成色剂在其分子中具有疏水性的抗扩散基团。

    Multi-layered color photographic light-sensitive material
    6.
    发明授权
    Multi-layered color photographic light-sensitive material 失效
    多层彩色摄影感光材料

    公开(公告)号：US3990899A

    公开(公告)日：1976-11-09

    申请号：US467539

    申请日：1974-05-06

    申请人： Keisuke Shiba ,  Takeshi Hirose ,  Jun Hayashi

    发明人： Keisuke Shiba ,  Takeshi Hirose ,  Jun Hayashi

    IPC分类号： G03C7/00 ,  G03C7/30 ,  G03C1/76 ,  G03C1/40 ,  G03C3/00

    CPC分类号： G03C7/30

    摘要： An incorporated-coupler multi-layered color photographic light-sensitive material which comprises a support having thereon at least two light-sensitive emulsion layer units which provide, upon color development, images having substantially different hues, at least one of the light-sensitive emulsion layer units comprising two or more unit layers in which at least one of which unit layers contain an ICC uncolored coupler alone or in combination with another coupler.

    摘要翻译： 一种并入成色剂多层彩色摄影感光材料，其包括其上具有至少两个感光乳剂层单元的支撑体，其在显色时提供具有基本不同色调的图像，至少一种感光乳剂 层单元，其包含两个或更多个单元层，其中至少一个单位层单独包含ICC未着色的偶联剂或与另一种偶联剂组合。

    Multilayer color photographic light-sensitive material
    7.
    发明授权
    Multilayer color photographic light-sensitive material 失效

    公开(公告)号：US4015988A

    公开(公告)日：1977-04-05

    申请号：US555314

    申请日：1975-03-04

    申请人： Keisuke Shiba ,  Takeshi Hirose ,  Jun Hayashi ,  Toshiaki Aono

    发明人： Keisuke Shiba ,  Takeshi Hirose ,  Jun Hayashi ,  Toshiaki Aono

    IPC分类号： G03C7/00 ,  G03C7/305 ,  G03C7/392 ,  G03C1/76 ,  G03C1/06 ,  G03C1/40

    CPC分类号： G03C7/39216 ,  G03C7/30558

    摘要： A multilayer color photographic light-sensitive material comprising a support having thereon at least two silver halide emulsion layer units, each of which is sensitive to radiation of a substantially different wavelength region within the wavelength region of from about 220 nm to about 800 nm and contains a color-forming coupler capable of forming a dye on coupling with an oxidized primary aromatic amine developing agent, with at least one of the emulsion layer units containing an ICC coupler represented by the general formula (I) ##STR1## wherein Cp represents a coupler residue; L and M each represents a nitrogen atom or a methine group, V represents a monocyclic or dicyclic aromatic ring of the benzene series, and at least one of L and M represnts a nitrogen atom; which releases a triazole derivative or a diazole derivative on coupling with an oxidized primary aromatic amine developing agent, and with the emulsion layer unit containing the ICC coupler represented by the general formula (I) or another layer containing a hydroquinone derivative represented by the general formula (II) ##STR2## wherein A and A' each represents a hydrogen atom or a group capable of being eliminated by an alkali, and A' can combine with R to Q to form a ring; P, Q and R each represents a hydrogen atom, an alkyl group, an aryl group, an alkylthio group, an arylthio group, a hydroxy group, a halogen atom, an alkoxy group, an aryloxy group, a heterocyclic ring or an --S--Z group, and P and Q can combine to form a ring; and Z represents a heterocyclic ring residue substantially photographically inert in a bonded state; which releases imagewise depending upon the development a compound having a mercapto group and/or a coupler which releases a compound having a mercapto group on coupling with an oxidized primary aromatic amine developing agent. The multilayer color photographic light-sensitive material provides color images having improved color reproduction, sharpness and graininess.

    Processing for silver halide color photographic materials
    8.
    发明授权
    Processing for silver halide color photographic materials 失效
    加工卤化银彩色照相材料

    公开(公告)号：US4968591A

    公开(公告)日：1990-11-06

    申请号：US919538

    申请日：1986-10-16

    申请人： Takatoshi Ishikawa ,  Takeshi Hirose ,  Nobuo Furutachi

    发明人： Takatoshi Ishikawa ,  Takeshi Hirose ,  Nobuo Furutachi

    IPC分类号： G03C7/38 ,  G03C7/30 ,  G03C7/384 ,  G03C7/42 ,  G03C7/44 ,  G03C11/00

    CPC分类号： G03C7/42 ,  G03C7/3046

    摘要： A process for processing a silver halide color photographic material is described comprising subjecting a silver halide color photographic material comprising a support having provided thereon at least one photographic emulsion layer containing at least one kind of pyrazoloazole series magenta coupler represented by general formula (I) to photographic processing using a bath containing at least 1.times.10.sup.-4 mol/liter of a soluble iron salt as the final bath: ##STR1## wherein Za and Zb each represents .dbd.CH--, (wherein R.sub.2 represents a hydrogen atom or a substituent) or =N-; R.sub.1 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group releasably upon coupling with the oxidation product of an aromatic primary amine developing agent; when Za=Zb is a carbon-carbon double bond, the double bond may be a part of an aromatic ring; the magenta coupler may form a dimer or polymer at R.sub.1, R.sub.2 or X; when at least one of said Za and Zb is ##STR2## at least one of the R.sub.1 and R.sub.2 represents a methylene group directly bonded to the skeleton of general formula (I), at least one of the hydrogen atoms of which is substituted; when both Za and Zb are .dbd.N--, R.sub.1 is a methylene group directly bonded to the skeleton, at least one of the hydrogen atoms of which is substituted; and the R.sub.1 or R.sub.2 has at least one --NHSO.sub.2 -- as a substituent.

    摘要翻译： 描述了一种用于处理卤化银彩色照相材料的方法，其包括将包含其上提供的支持体的卤化银彩色照相材料经受至少一种含有通式（I）表示的至少一种吡唑并唑系品红成色剂的照相乳剂层至 使用含有至少1×10 -4 mol /升可溶性铁盐作为最终浴的浴的照相处理：其中Za和Zb各自表示= CH-，其中R2表示氢原子 或取代基）或= N-; R1表示氢原子或取代基; X表示与芳族伯胺显影剂的氧化产物偶联时可释放的氢原子或基团; 当Za = Zb是碳 - 碳双键时，双键可以是芳环的一部分; 品红成色剂可以在R1，R2或X形成二聚体或聚合物; 当所述Za和Zb中的至少一个为“IMA”时，R 1和R 2中的至少一个表示直接键合到通式（I）的骨架上的亚甲基，其中至少一个氢原子被取代; 当Za和Zb均为= N-时，R1是与骨架直接键合的亚甲基，其中至少一个氢原子被取代; 并且R 1或R 2具有至少一个-NHSO 2 - 作为取代基。

    Silver halide color photographic light-sensitive material
    9.
    发明授权
    Silver halide color photographic light-sensitive material 失效
    卤化银彩色摄影感光材料

    公开(公告)号：US4929540A

    公开(公告)日：1990-05-29

    申请号：US380489

    申请日：1989-07-17

    申请人： Nobuo Furutachi ,  Takeshi Hirose

    发明人： Nobuo Furutachi ,  Takeshi Hirose

    IPC分类号： C07D403/12 ,  G03C7/305 ,  G03C7/384

    CPC分类号： C07D403/12 ,  G03C7/30552 ,  G03C7/384

    摘要： A silver halide color photographic light-sensitive material comprising a support and at least one silver halide photographic emulsion layer on the support, said emulsion layer containing a 5-pyrazolone coupler having a coupling eliminable group of the following general formula (I) at the coupling site thereof: ##STR1## wherein L.sub.1 represents a substituted or an unsubstituted methylene or ethylene group; l represents 0 or 1; m represents 0 or an integer from 1 to 3; R.sub.1 represents a hydrogen atom, or a substituted or an unsubstituted alkyl, aryl or heterocyclic group; Y represents ##STR2## Q represents a single bond or nonmetal atoms necessary to complete a 5- to 8-membered ring together with ##STR3## said 5- to 8-membered ring may further have a saturated or an unsaturated ring condensed thereto; R.sub.2 represents a halogen atom, an alkyl group; an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group, an acylamino group, an alkoxycarbonylamino group, a sulfonamide group, a sulfamoyl group, an ureido group, an alkoxycarbonyl group, an aryloxycarbonyl group, an acyl group, a cyano group, a trifluoromethyl group, an amino group, an N-alkylamino group, an N-arylamino group, an N,N-dialkylamino group, a diacylamino group, an imido group or a carbamoyl group, and when m represents 2 or 3, R.sub.2 groups may be the same or different; R.sub.2 ' represents a hydrogen atom, or has the same meaning as R.sub.2 and two R.sub.2 ' groups may be linked to form a 5- to 7-membered saturated or unsaturated ring; and --Y Q may be a substituted or an unsubstituted carbon-carbon or carbon-nitrogen double bond. The silver halide photographic material provides a magenta image having a high maximum density and light fastness.

    摘要翻译： 一种卤化银彩色照相感光材料，其在载体上包含载体和至少一个卤化银照相乳剂层，所述乳剂层含有在偶联下具有以下通式（I）的可脱离基团的5-吡唑啉酮偶联剂 （I）其中L 1表示取代或未取代的亚甲基或亚乙基; l表示0或1; m表示0或1〜3的整数， R 1表示氢原子，或取代或未取代的烷基，芳基或杂环基; Y表示 Q表示与一起完成5-至8-元环所需的单键或非金属原子，所述5-至8-元环可进一步具有稠合的饱和或不饱和的环; R2表示卤素原子，烷基， 芳基，烷氧基，芳氧基，烷硫基，芳硫基，烷基磺酰基，芳基磺酰基，酰氨基，烷氧基羰基氨基，磺酰胺基，氨磺酰基，脲基，烷氧基羰基 基团，芳氧基羰基，酰基，氰基，三氟甲基，氨基，N-烷基氨基，N-芳基氨基，N，N-二烷基氨基，二酰氨基，亚氨基或 氨基甲酰基，当m表示2或3时，R 2基可以相同或不同; R2'表示氢原子，或具有与R2相同的含义，并且两个R 2'基团可以连接形成5-至7-元饱和或不饱和环; 和-Y Q可以是取代或未取代的碳 - 碳或碳 - 氮双键。 卤化银照相材料提供具有高最大密度和耐光性的品红色图像。

    Silver halide color photographic light-sensitive material
    10.
    发明授权
    Silver halide color photographic light-sensitive material 失效
    卤化银彩色摄影感光材料

    公开(公告)号：US4900655A

    公开(公告)日：1990-02-13

    申请号：US125796

    申请日：1987-11-27

    申请人： Kiyoshi Nakazyo ,  Takeshi Hirose ,  Genichi Hurusawa ,  Osamu Takahashi ,  Nobuo Furutachi ,  Hidetoshi Kobayashi

    发明人： Kiyoshi Nakazyo ,  Takeshi Hirose ,  Genichi Hurusawa ,  Osamu Takahashi ,  Nobuo Furutachi ,  Hidetoshi Kobayashi

    IPC分类号： G03C7/30 ,  G03C7/38

    CPC分类号： G03C7/3835 ,  G03C7/301

    摘要： A silver halide color photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer, wherein at least one magenta coupler represented by the formula ##STR1## where the groups in the formula are defined in the specification; is dispersed in the silver halide emulsion layer in the presence of at least one high-boiling organic solvent represented by one of the formulae (II), (III), (IV) and (V): ##STR2## where the groups in the formulae are described in the specification. The a high boiling point organic solvent has a dielectric constant of not less than 4.00 at 25.degree. C. and 10 KHz.

    摘要翻译： 一种卤化银彩色照相感光材料，其包括在其上提供有至少一个卤化银乳剂层的载体，其中至少一种由式（VIII）表示的品红成色剂，其中式中的基团在说明书中定义 ; 在由式（II），（III），（IV）和（V）之一表示的至少一种高沸点有机溶剂的存在下分散在卤化银乳剂层中：R3COOR4（II） （IV）R3OR4（V）其中式中的基团在说明书中描述。 高沸点有机溶剂在25℃和10KHz下的介电常数不低于4.00。