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    Photographic recording material for accelerated development
    2.
    发明授权
    Photographic recording material for accelerated development 失效
    用于加速发展的摄影记录材料

    公开(公告)号：US06756188B2

    公开(公告)日：2004-06-29

    申请号：US10244270

    申请日：2002-09-16

    申请人： John E. Keevert ,  Stephen P. Singer ,  Kenneth J. Reed ,  Kenneth J. Lushington ,  Mary C. Brick ,  James A. Friday

    发明人： John E. Keevert ,  Stephen P. Singer ,  Kenneth J. Reed ,  Kenneth J. Lushington ,  Mary C. Brick ,  James A. Friday

    IPC分类号： G03C746

    CPC分类号： G03C7/30594 ,  G03C1/0051 ,  G03C1/04 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/30541 ,  G03C2007/3034 ,  Y10S430/156

    摘要： This invention relates to a photographic element comprising a support and at least two silver halide emulsion layers further comprising, an electron transfer agent releasing compound represented by the formula (I): CAR1—(L)n—ETA  (I) wherein: CAR1 is a carrier moiety which is capable of releasing —(L)n-ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable 1-aryl-3-pyrazolidinone electron transfer agent having a calculated log partition coefficient (c log P) greater than or equal to 2.40 and the total sum of the Hammett sigma(para) values of the substituents on the 1-aryl ring is 0.51 or less, the ETA being bonded to L or CAR1 through either the nitrogen atom in the 2-position or the oxygen attached to the 3-position of the pyrazolidinone ring; and a development accelerator releasing compound represented by the formula (II): CAR2—(SAM)—NX1—NX2X3  (II) wherein: CAR2 is a carrier moiety which is capable of releasing —(SAM)—NX1—NX2X3 on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and —NX1—NX2X3 is a hydrazine group wherein X1, X2 and X3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl or sulfonyl groups with the proviso that at least one of X1, X2 and X3 is hydrogen.

    摘要翻译： 本发明涉及一种照相元件，其中包含支持体和至少两个卤化银乳剂层，还包含由式（I）表示的电子转移剂释放化合物：其中：CAR 1是能够释放的载体部分 - （L）n-ETA与氧化显影剂反应; L为二价连接基团，n为0,1或2; 和ETA是具有大于或等于2.40的计算对数分配系数（c log P）的可释放的1-芳基-3-吡唑烷酮电子转移剂，并且1-位的取代基的哈米特σ（对）值的总和， 芳基环为0.51以下，ETA通过2位的氮原子或与吡唑烷酮环的3位相连的氧键连接至L或CAR 1;以及由吡唑烷酮环的3位表示的显影促进剂释放化合物 式（II）：其中：CAR 2是能够与氧化显影剂反应释放 - （SAM）-NX 1 -XX 2 X 3的载体部分; SAM是银 与载体部分连接的可吸收部分，与氧化显影剂反应释放; 和-X 1 -NX 2 X 3是其中X 1，X 2和X 3独立地为氢或选自烷基，芳基，羰基或磺酰基的取代基的肼基团 条件是X 1，X 2和X 3中的至少一个是氢。

    Color photographic element containing speed improving compound in combination with reflecting material
    4.
    发明授权
    Color photographic element containing speed improving compound in combination with reflecting material 失效
    含有速度改善化合物与反射材料组合的彩色照相元件

    公开(公告)号：US06350564B1

    公开(公告)日：2002-02-26

    申请号：US09690310

    申请日：2000-10-17

    申请人： Joseph F. Bringley ,  James A. Friday ,  Stephen P. Singer ,  Marcello Vitale

    发明人： Joseph F. Bringley ,  James A. Friday ,  Stephen P. Singer ,  Marcello Vitale

    IPC分类号： G03C110

    CPC分类号： G03C7/39276 ,  G03C1/8255 ,  G03C7/3029 ,  G03C7/30541 ,  G03C7/30576 ,  G03C7/39256 ,  G03C7/3926 ,  G03C7/39272 ,  G03C2007/3034

    摘要： Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) a light reflecting silver halide material; provided that the heterocycle compound and the light reflecting material are located either (a) in different layers of the element located close enough to each other so that a super-additive speed increase is realized or (b) in the same light sensitive layer. The invention provides improved light sensitivity.

    摘要翻译： 公开了一种彩色卤化银照相元件，其包括载体：（1）感光卤化银乳剂层;（2）具有至少三个不与氧化显影剂反应的杂原子的氮杂环不含游离硫醇取代基 并且具有足够的ClogP以增加与没有化合物的相同元件相比所述元件的照相速度，所述杂环化合物位于所述光敏层中或位于与其相邻的层中; 和（3）光反射卤化银材料;条件是杂环化合物和光反射材料位于元件的不同层中（a）位于彼此足够靠近的位置，从而实现超加速度增加，或 （b）在相同的光敏层。 本发明提供了改善的光敏度。

    Color photographic material with improved sensitivity
    6.
    发明授权
    Color photographic material with improved sensitivity 失效
    彩色感光材料，灵敏度提高

    公开(公告)号：US06811963B2

    公开(公告)日：2004-11-02

    申请号：US10346582

    申请日：2003-01-17

    申请人： Sharon G. Johnston ,  Stephen P. Singer ,  Drake M. Michno ,  James A. Friday ,  David R. Foster

    发明人： Sharon G. Johnston ,  Stephen P. Singer ,  Drake M. Michno ,  James A. Friday ,  David R. Foster

    IPC分类号： G03C146

    CPC分类号： G03C7/39276 ,  G03C1/0051 ,  G03C1/29 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/3835 ,  G03C7/39244 ,  G03C2007/3034

    摘要： This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, Dye 2, wherein the dye layers are held together by more than one non-covalent force; the outer dye layer absorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.

    摘要翻译： 本发明涉及一种卤化银照相元件，其包括载体，该载体具有青色染料成像单元，该单元由至少一种与其相关的感红卤化银乳剂层组成，所述感红卤化银乳剂层具有至少一种形成青色染料的成色剂，品红色成像剂 包含至少一个具有与其相关联的至少一种品红色染料形成成色剂的感绿卤化银乳剂层的黄色染料成像单元和包含至少一种感蓝卤化银乳剂层的黄色染料影像形成单元，所述感蓝卤化银乳剂层具有至少一种黄色 染料形成成色剂，其中至少一种染料成像单元含有不同灵敏度的层，并且最高灵敏度层含有如本文所述的显影促进剂或特定成色剂或其组合，以及卤化银乳剂 包括具有与其相关联的至少两个染料层的片状卤化银颗粒，其包含（a）内部染料层a 与卤化银颗粒相邻并且包含至少一种能够使卤化银光谱增感的染料D染料1和（b）邻近内部染料层的外部染料层，并且包含至少一种染料染料2，染料2 染料层通过多于一种非共价力保持在一起; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。

    Color photographic material with improved sensitivity comprising a pyrazolotriazole coupler
    7.
    发明授权
    Color photographic material with improved sensitivity comprising a pyrazolotriazole coupler 失效
    具有改进的灵敏度的彩色照相材料包括吡唑并三唑成色剂

    公开(公告)号：US06699652B1

    公开(公告)日：2004-03-02

    申请号：US10346273

    申请日：2003-01-17

    申请人： Sharon G. Johnston ,  Stephen P. Singer ,  Drake M. Michno ,  James A. Friday ,  David R. Foster

    发明人： Sharon G. Johnston ,  Stephen P. Singer ,  Drake M. Michno ,  James A. Friday ,  David R. Foster

    IPC分类号： G03C108

    CPC分类号： G03C1/29 ,  G03C1/0051 ,  G03C3/00 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/30541 ,  G03C7/30558 ,  G03C7/30594 ,  G03C7/3835 ,  G03C2003/006 ,  G03C2007/3034 ,  G03C2007/3039

    摘要： This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, Dye 2, wherein the dye layers are held together by more than one non-covalent force; the outer dye layer absorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.

    摘要翻译： 本发明涉及一种卤化银照相元件，其包括载体，该载体具有青色染料成像单元，该单元由至少一种与其相关的感红卤化银乳剂层组成，所述感红卤化银乳剂层具有至少一种形成青色染料的成色剂，品红色成像剂 包含至少一个具有与其相关联的至少一种品红色染料形成成色剂的感绿卤化银乳剂层的黄色染料成像单元和包含至少一种感蓝卤化银乳剂层的黄色染料影像形成单元，所述感蓝卤化银乳剂层具有至少一种黄色 染料形成成色剂，其中至少一种染料成像单元含有不同灵敏度的层，并且最高灵敏度层含有如本文所述的显影促进剂或特定成色剂或其组合，以及卤化银乳剂 包括具有与其相关联的至少两个染料层的片状卤化银颗粒，其包含（a）内部染料层a 与卤化银颗粒相邻并且包含至少一种能够使卤化银光谱增感的染料D染料1和（b）邻近内部染料层的外部染料层，并且包含至少一种染料染料2，染料2 染料层通过多于一种非共价力保持在一起; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。

    Color photographic element containing speed improving compound in combination with electron transfer agent releasing compound
    8.
    发明授权
    Color photographic element containing speed improving compound in combination with electron transfer agent releasing compound 失效
    含有速度改善化合物的彩色照相元件与电子转移剂释放化合物的组合

    公开(公告)号：US06426180B1

    公开(公告)日：2002-07-30

    申请号：US09690569

    申请日：2000-10-17

    申请人： Joseph F. Bringley ,  James A. Friday ,  Stephen P. Singer ,  Marcello Vitale

    发明人： Joseph F. Bringley ,  James A. Friday ,  Stephen P. Singer ,  Marcello Vitale

    IPC分类号： G03C106

    CPC分类号： G03C7/3924 ,  G03C7/3005 ,  G03C7/30558 ,  Y10S430/156

    摘要： Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a C log P sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) an ETARC, in or adjacent to said light sensitive silver halide emulsion layer, that releases, upon reaction with oxidized developer, an electron transfer agent having a C log P of at least 2.40. The invention provides improved light sensitivity.

    摘要翻译： 公开了一种彩色卤化银照相元件，其包括载体：（1）感光卤化银乳剂层;（2）具有至少三个不与氧化显影剂反应的杂原子的氮杂环不含游离硫醇取代基 并且具有足够增加所述元件的照相速度的C log P，与没有化合物的相同元素相比，所述杂环化合物位于所述光敏层中或位于与其相邻的层中; 和（3）在所述感光卤化银乳剂层中或其附近的ETARC，其与氧化显影剂反应时释放具有至少2.40的C log P的电子转移剂。 本发明提供了改善的光敏度。

    INFRARED DYE FOR SILVER HALIDE-BASED PHOTOGRAPHIC ELEMENTS
    9.
    发明申请
    INFRARED DYE FOR SILVER HALIDE-BASED PHOTOGRAPHIC ELEMENTS 审中-公开
    用于银基卤化物照相元件的红外线

    公开(公告)号：US20090233247A1

    公开(公告)日：2009-09-17

    申请号：US12047342

    申请日：2008-03-13

    申请人： Paul L. Zengerle ,  John W. Harder ,  Steven P. Szatynski ,  Stephen P. Singer

    发明人： Paul L. Zengerle ,  John W. Harder ,  Steven P. Szatynski ,  Stephen P. Singer

    IPC分类号： G03C1/005 ,  C07D417/08 ,  C09K19/34

    CPC分类号： G03C1/832 ,  C09B23/0066 ,  C09B23/04 ,  C09B23/06 ,  G03C1/8255 ,  G03C7/3022 ,  G03C2007/3025

    摘要： A non-infrared sensitized low silver photographic element with a non-light sensitive layer, preferably an antihalation layer, containing a diphenylaminocyclopentene heptacyanine benzothiazolium infrared dye where the benzothiazolium groups have electron-withdrawing substituents on the phenyl ring and solubilzed alkyl groups on the nitrogen. The infrared dye can be present as a liquid-crystalline dispersion. This class of infrared dyes form J-aggregated species in a liquid-crystalline or a solid particle dispersion with high IR density and low visible absorbance.

    摘要翻译： 一种具有非光敏层的非红外敏感低银照相元件，优选为防晕层，其含有二苯基氨基环戊烯七叶酸苯并噻唑鎓红外染料，其中苯并噻唑鎓基在苯环上具有吸电子取代基并在氮上溶解烷基。 红外染料可以作为液晶分散体存在。 这类红外染料在具有高IR密度和低可见光吸收度的液晶或固体颗粒分散体中形成J-聚集物。

    Photographic element with speed-enhancing compound
    10.
    发明授权
    Photographic element with speed-enhancing compound 失效
    具有加速化合物的摄影元件

    公开(公告)号：US07354701B2

    公开(公告)日：2008-04-08

    申请号：US10574394

    申请日：2004-10-01

    申请人： Bernard A. Clark ,  Philip A. Allway ,  Tania Zuberi ,  Stephen P. Singer ,  Charles E. Heckler ,  Louis E. Friedrich

    发明人： Bernard A. Clark ,  Philip A. Allway ,  Tania Zuberi ,  Stephen P. Singer ,  Charles E. Heckler ,  Louis E. Friedrich

    IPC分类号： G03C1/46 ,  G03C1/06 ,  G03C1/005 ,  G03C1/494

    CPC分类号： G03C7/3924 ,  G03C7/3029 ,  G03C7/3212 ,  G03C7/39252 ,  G03C7/39276 ,  G03C2007/3034 ,  G03C2200/29

    摘要： The invention provides a color photographic element comprising at least one light-sensitive silver halide emulsion layer or a non silver-containing light-insensitive layer, in which at least one of these layers contains a colorless heterocyclic compound having either one or two hetero atoms in the ring or ring system, being other than an imidazole compound, that undergoes less than 10% chemical or redox reaction directly with oxidized developer and which has a partition coefficient to enable the photographic speed of the element to be increased by at least 0.03 stop without increasing granularity, compared to the same element without the compound. The heterocyclic compounds increase speed without a concomitant increase in size of the light-sensitive silver halide grains.

    摘要翻译： 本发明提供了一种彩色照相元件，其包含至少一种感光卤化银乳剂层或非含银不光敏层，其中这些层中的至少一层含有具有一个或两个杂原子的无色杂环化合物 与咪唑化合物不同的环或环体系，其与氧化显影剂直接进行少于10％的化学或氧化还原反应，并且具有分配系数以使元件的照相速度能够增加至少0.03个停止，而没有 与没有化合物的相同元素相比，粒度增加。 杂环化合物增加速度，而不增加感光卤化银颗粒的尺寸。