4-Butyl-3,4,5-trimethylcyclohexa-25-dienone
    6.
    发明授权
    4-Butyl-3,4,5-trimethylcyclohexa-25-dienone 失效
    4-丁基-3,4,5-三甲基环己基-25-二烯酮

    公开(公告)号:US4154763A

    公开(公告)日:1979-05-15

    申请号:US860121

    申请日:1977-12-13

    摘要: Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma; tobacco flavor and aroma; perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, produced by one of the following processes:(i) Reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product; or(ii) Reacting a 4-alkyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one with dilute aqueous mineral acid and distilling the resulting reaction product.Addition of one or more of the cyclohexadiene derivatives having the formula: ##STR2## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavoring compositions, chewing gums, toothpastes and medicinal products, sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco-like and "Oriental" aroma characteristics with sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco, "Oriental" flavor characteristics;(b) In perfumes, colognes and perfumed articles, warm sweet, slightly minty, woody, natural green, herbaceous, Jasmine-like, fruity aromas; and(c) In tobaccos and tobacco flavors, "dry black tobacco-like" notes, spicey notes, celery-like notes, black pepper-like notes, sweet notes and Virginia tobacco-like notes prior to and on smoking, in both the main stream and the side stream.

    摘要翻译: 描述了用于食品,口香糖,牙膏和药用产品香味和香气的方法和组合物; 烟草香气和香气; 香水和香水制品香气增强,增强和赋予组合物; 作为一种或多种具有以下通式的环己二烯衍生物的食品,口香糖,牙膏,药用产品,烟草,香料和香料制品香气赋予材料:其中R是C 1 -C 5烷基之一,当R 2为R 1时,R 1为甲基 是氢,当R 2为甲基时,R 1为氢,由以下方法之一制备:

    Detergent containing cyclohexadiene derivatives
    8.
    发明授权
    Detergent containing cyclohexadiene derivatives 失效
    含有环己二烯衍生物的洗涤剂

    公开(公告)号:US4154696A

    公开(公告)日:1979-05-15

    申请号:US917772

    申请日:1978-06-21

    摘要: Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma; tobacco flavor and aroma; perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, produced by one of the following processes:(i) Reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product; or(ii) Reacting a 4-alkyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one with dilute aqueous mineral acid and distilling the resulting reaction product.Addition of one or more of the cyclohexadiene derivatives having the formula: ##STR2## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavoring compositions, chewing gums, toothpastes and medicinal products, sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco-like and "Oriental" aroma characteristics with sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco, "Oriental" flavor characteristics;(b) In perfumes, colognes and perfumed articles, warm sweet, slightly minty, woody, natural green, herbaceous, Jasmine-like, fruity aromas; and(c) In tobaccos and tobacco flavors, "dry black tobacco-like" notes, spicey notes, celery-like notes, black pepper-like notes, sweet notes and Virginia tobacco-like notes prior to and on smoking, in both the main stream and the side stream.

    摘要翻译: 描述了用于食品,口香糖,牙膏和药用产品香味和香气的方法和组合物; 烟草香气和香气; 香水和香水制品香气增强,增强和赋予组合物; 作为一种或多种具有以下通式的环己二烯衍生物的食品,口香糖,牙膏,药用产品,烟草,香料和香料制品香气赋予材料:其中R是C 1 -C 5烷基之一,当R 2为R 1时,R 1为甲基 是氢,当R 2为甲基时,R 1为氢,由以下方法之一制备: