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公开(公告)号：US20120024709A1
公开(公告)日：2012-02-02
申请号：US12845058
申请日：2010-07-28
申请人： Kie-Moon Sung , Man-Jae Weon , Kyung-Ho Lee , Young-Min Park
发明人： Kie-Moon Sung , Man-Jae Weon , Kyung-Ho Lee , Young-Min Park
IPC分类号： C25D1/10
摘要： Disclosed are a porous electroformed shell for forming a grain pattern and a manufacturing method thereof. The method includes the step of causing an epoxy mandrel to be conductive by formation of a conductive thin film thereon; transferring a non-conductive masking pattern on the conductive thin film by using a masking film; generating and growing a fine pore at the position of the non-conductive masking pattern through electroforming; and demolding an electrodeposited layer having the fine pore from the epoxy mandrel, Through the disclosed method, precise control, both as a whole or in part, on a diameter, a formation position, and a density of a fine pore can be simply, economically, and efficiently can be carried out according to various curved shapes of the electroformed shell. Accordingly, in forming the surface of a high-quality surface skin material or a plastic molded product with a predetermined pattern, when the fine pore is used as a decompression suction hole or an air vent, a predetermined pattern can be efficiently and economically obtained in such a manner that it has a regular position, a regular directionality, sharp radii, and minimized deformation.
摘要翻译： 公开了一种用于形成颗粒图案的多孔电铸壳及其制造方法。 该方法包括通过在其上形成导电薄膜使环氧心轴导电的步骤; 通过使用掩模膜在导电薄膜上转印非导电掩模图案; 通过电铸在非导电掩模图案的位置产生和生长细孔; 通过所公开的方法，可以简单地，经济上精确地控制直径，形成位置和细孔密度，整体上或部分地精确地控制了细孔的电沉积层。 并且可以根据电铸外壳的各种弯曲形状有效地进行。 因此，在形成具有规定图案的高品质表皮材料或塑料成型体的表面时，当细孔用作减压吸孔或排气孔时，可以有效地和经济地获得预定图案 这种方式使其具有规则位置，规则方向性，锐利的半径和最小的变形。
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公开(公告)号：US09074293B2
公开(公告)日：2015-07-07
申请号：US12845058
申请日：2010-07-28
申请人： Kie-Moon Sung , Man-Jae Weon , Kyung-Ho Lee , Young-Min Park
发明人： Kie-Moon Sung , Man-Jae Weon , Kyung-Ho Lee , Young-Min Park
摘要： Disclosed are a porous electroformed shell for forming a grain pattern and a manufacturing method thereof. The method includes the step of causing an epoxy mandrel to be conductive by formation of a conductive thin film thereon; transferring a non-conductive masking pattern on the conductive thin film by using a masking film; generating and growing a fine pore at the position of the non-conductive masking pattern through electroforming; and demolding an electrodeposited layer having the fine pore from the epoxy mandrel, Through the disclosed method, precise control, both as a whole or in part, on a diameter, a formation position, and a density of a fine pore can be simply, economically, and efficiently can be carried out according to various curved shapes of the electroformed shell. Accordingly, in forming the surface of a high-quality surface skin material or a plastic molded product with a predetermined pattern, when the fine pore is used as a decompression suction hole or an air vent, a predetermined pattern can be efficiently and economically obtained in such a manner that it has a regular position, a regular directionality, sharp radii, and minimized deformation.
摘要翻译： 公开了一种用于形成颗粒图案的多孔电铸壳及其制造方法。 该方法包括通过在其上形成导电薄膜使环氧心轴导电的步骤; 通过使用掩模膜在导电薄膜上转印非导电掩模图案; 通过电铸在非导电掩模图案的位置产生和生长细孔; 通过所公开的方法，可以简单地，经济上精确地控制直径，形成位置和细孔密度，整体上或部分地精确地控制了细孔的电沉积层。 并且可以根据电铸外壳的各种弯曲形状有效地进行。 因此，在形成具有规定图案的高品质表皮材料或塑料成型体的表面时，当细孔用作减压吸孔或排气孔时，可以有效地和经济地获得预定图案 这种方式使其具有规则位置，规则方向性，锐利的半径和最小的变形。
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公开(公告)号：US20140206860A1
公开(公告)日：2014-07-24
申请号：US14060540
申请日：2013-10-22
IPC分类号： C08B37/16
CPC分类号： C08B37/0012 , B05D1/00 , C01B13/00 , C08B37/0015 , Y10S977/778 , Y10S977/882 , Y10T428/25 , Y10T428/2991
摘要： Fabrication and arrangement of nanoparticles into one-dimensional linear chains is achieved by successive chemical reactions, each reaction adding one or more nanoparticles by building onto exposed, unprotected linker functionalities. Optionally, protecting groups may be used to control and organize growth. Nanoparticle spheres are functionalized in a controlled manner in order to enable covalent linkages. Functionalization of nanoparticles is accomplished by either ligand exchange or chemical modification of the terminal functional groups of the capping ligand. Nanoparticle chains are obtained by a variety of connectivity modes such as direct coupling, use of linker molecules, and use of linear polymeric templates. In particular, a versatile building block system is obtained through controlled monofunctionalization of nanoparticles.
摘要翻译： 通过连续的化学反应来实现纳米颗粒到一维线性链中的制备和排列，每个反应通过构建到暴露的未受保护的接头功能上而添加一种或多种纳米颗粒。 任选地，保护基团可用于控制和组织生长。 纳米颗粒球以受控的方式进行功能化，以实现共价键。 纳米颗粒的官能化通过配体交换或封端配体的末端官能团的化学修饰来实现。 通过各种连接模式（例如直接偶联，使用连接分子）和使用线性聚合物模板获得纳米颗粒链。 特别地，通过纳米颗粒的受控单官能化获得通用的结构单元体系。
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4.发明授权公开(公告)号：US08357424B2
公开(公告)日：2013-01-22
申请号：US12352129
申请日：2009-01-12
CPC分类号： C08B37/0012 , B05D1/00 , C01B13/00 , C08B37/0015 , Y10S977/778 , Y10S977/882 , Y10T428/25 , Y10T428/2991
摘要： Fabrication and arrangement of nanoparticles into one-dimensional linear chains is achieved by successive chemical reactions, each reaction adding one or more nanoparticles by building onto exposed, unprotected linker functionalities. Optionally, protecting groups may be used to control and organize growth. Nanoparticle spheres are functionalized in a controlled manner in order to enable covalent linkages. Functionalization of nanoparticles is accomplished by either ligand exchange or chemical modification of the terminal functional groups of the capping ligand. Nanoparticle chains are obtained by a variety of connectivity modes such as direct coupling, use of linker molecules, and use of linear polymeric templates. In particular, a versatile building block system is obtained through controlled monofunctionalization of nanoparticles.
摘要翻译： 通过连续的化学反应来实现纳米颗粒到一维线性链中的制备和排列，每个反应通过构建到暴露的未受保护的接头功能上而添加一种或多种纳米颗粒。 任选地，保护基团可用于控制和组织生长。 纳米颗粒球以受控的方式进行功能化，以实现共价键。 纳米颗粒的官能化通过配体交换或封端配体的末端官能团的化学修饰来实现。 通过各种连接模式（例如直接偶联，使用连接分子）和使用线性聚合物模板获得纳米颗粒链。 特别地，通过纳米颗粒的受控单官能化获得通用的结构单元体系。
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5.发明授权Nanoparticle chains by direct bonding of functional groups and preparation thereof 有权通过官能团的直接键合制备纳米粒子链公开(公告)号：US08563081B2
公开(公告)日：2013-10-22
申请号：US13747373
申请日：2013-01-22
CPC分类号： C08B37/0012 , B05D1/00 , C01B13/00 , C08B37/0015 , Y10S977/778 , Y10S977/882 , Y10T428/25 , Y10T428/2991
摘要： Fabrication and arrangement of nanoparticles into one-dimensional linear chains is achieved by successive chemical reactions, each reaction adding one or more nanoparticles by building onto exposed, unprotected linker functionalities. Optionally, protecting groups may be used to control and organize growth. Nanoparticle spheres are functionalized in a controlled manner in order to enable covalent linkages. Functionalization of nanoparticles is accomplished by either ligand exchange or chemical modification of the terminal functional groups of the capping ligand. Nanoparticle chains are obtained by a variety of connectivity modes such as direct coupling, use of linker molecules, and use of linear polymeric templates. In particular, a versatile building block system is obtained through controlled monofunctionalization of nanoparticles.
摘要翻译： 通过连续的化学反应来实现纳米颗粒到一维线性链中的制备和排列，每个反应通过构建到暴露的未受保护的接头功能上而添加一种或多种纳米颗粒。 任选地，保护基团可用于控制和组织生长。 纳米颗粒球以受控的方式进行功能化，以实现共价键。 纳米颗粒的官能化通过配体交换或封端配体的末端官能团的化学修饰来实现。 通过各种连接模式（例如直接偶联，使用连接分子）和使用线性聚合物模板获得纳米颗粒链。 特别地，通过纳米颗粒的受控单官能化获得通用的结构单元体系。
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公开(公告)号：US20090124780A1
公开(公告)日：2009-05-14
申请号：US12352129
申请日：2009-01-12
CPC分类号： C08B37/0012 , B05D1/00 , C01B13/00 , C08B37/0015 , Y10S977/778 , Y10S977/882 , Y10T428/25 , Y10T428/2991
摘要： Fabrication and arrangement of nanoparticles into one-dimensional linear chains is achieved by successive chemical reactions, each reaction adding one or more nanoparticles by building onto exposed, unprotected linker functionalities. Optionally, protecting groups may be used to control and organize growth. Nanoparticle spheres are functionalized in a controlled manner in order to enable covalent linkages. Functionalization of nanoparticles is accomplished by either ligand exchange or chemical modification of the terminal functional groups of the capping ligand. Nanoparticle chains are obtained by a variety of connectivity modes such as direct coupling, use of linker molecules, and use of linear polymeric templates. In particular, a versatile building block system is obtained through controlled monofunctionalization of nanoparticles.
摘要翻译： 通过连续的化学反应来实现纳米颗粒到一维线性链中的制备和排列，每个反应通过构建到暴露的未受保护的接头功能上而添加一种或多种纳米颗粒。 任选地，保护基团可用于控制和组织生长。 纳米颗粒球以受控的方式进行功能化，以实现共价键。 纳米颗粒的官能化通过配体交换或封端配体的末端官能团的化学修饰来实现。 通过各种连接模式（例如直接偶联，使用连接分子）和使用线性聚合物模板获得纳米颗粒链。 特别地，通过纳米颗粒的受控单官能化获得通用的结构单元体系。
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公开(公告)号：US20130197214A1
公开(公告)日：2013-08-01
申请号：US13747373
申请日：2013-01-22
IPC分类号： C08B37/16
CPC分类号： C08B37/0012 , B05D1/00 , C01B13/00 , C08B37/0015 , Y10S977/778 , Y10S977/882 , Y10T428/25 , Y10T428/2991
摘要： Fabrication and arrangement of nanoparticles into one-dimensional linear chains is achieved by successive chemical reactions, each reaction adding one or more nanoparticles by building onto exposed, unprotected linker functionalities. Optionally, protecting groups may be used to control and organize growth. Nanoparticle spheres are functionalized in a controlled manner in order to enable covalent linkages. Functionalization of nanoparticles is accomplished by either ligand exchange or chemical modification of the terminal functional groups of the capping ligand. Nanoparticle chains are obtained by a variety of connectivity modes such as direct coupling, use of linker molecules, and use of linear polymeric templates. In particular, a versatile building block system is obtained through controlled monofunctionalization of nanoparticles.
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公开(公告)号：US07476442B2
公开(公告)日：2009-01-13
申请号：US10621790
申请日：2003-07-17
IPC分类号： B32B5/16
CPC分类号： C08B37/0012 , B05D1/00 , C01B13/00 , C08B37/0015 , Y10S977/778 , Y10S977/882 , Y10T428/25 , Y10T428/2991
摘要： Fabrication and arrangement of nanoparticles into one-dimensional linear chains is achieved by successive chemical reactions, each reaction adding one or more nanoparticles by building onto exposed, unprotected linker functionalities. Optionally, protecting groups may be used to control and organize growth. Nanoparticle spheres are functionalized in a controlled manner in order to enable covalent linkages. Functionalization of nanoparticles is accomplished by either ligand exchange or chemical modification of the terminal functional groups of the capping ligand. Nanoparticle chains are obtained by a variety of connectivity modes such as direct coupling, use of linker molecules, and use of linear polymeric templates. In particular, a versatile building block system is obtained through controlled monofunctionalization of nanoparticles.
摘要翻译： 通过连续的化学反应来实现纳米颗粒到一维线性链中的制备和排列，每个反应通过构建到暴露的未受保护的接头功能上而添加一种或多种纳米颗粒。 任选地，保护基团可用于控制和组织生长。 纳米颗粒球以受控的方式进行功能化，以实现共价键。 纳米颗粒的官能化通过配体交换或封端配体的末端官能团的化学修饰来实现。 通过各种连接模式（例如直接偶联，使用连接分子）和使用线性聚合物模板获得纳米颗粒链。 特别地，通过纳米颗粒的受控单官能化获得通用的结构单元体系。
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