公开(公告)号：US5391326A

公开(公告)日：1995-02-21

申请号：US96399

申请日：1993-07-26

申请人： Kim R. Smith ,  James E. Borland ,  Terry Crutcher ,  Joe D. Sauer

发明人： Kim R. Smith ,  James E. Borland ,  Terry Crutcher ,  Joe D. Sauer

IPC分类号： C11D1/14 ,  C11D1/22 ,  C11D1/72 ,  C11D1/75 ,  C11D1/83 ,  C11D3/00 ,  C11D3/08 ,  C11D3/12 ,  C11D10/04 ,  C11D1/831

CPC分类号： C11D1/83 ,  C11D10/04 ,  C11D3/0036 ,  C11D3/08 ,  C11D3/128 ,  C11D1/14 ,  C11D1/22 ,  C11D1/72 ,  C11D1/75

摘要： A phosphate-free granular laundry detergent having a cleaning performance comparable to that of a premium phosphate-containing laundry detergent has a surfactant content of 1-30% and a detergent builder content of at least 50% by weight and contains:(A) as its sole surfactant, a mixture of 20-98% by weight of an ethoxylated fatty alcohol corresponding to the formula Z(OCH.sub.2 CH.sub.2).sub.n OH in which Z is an alkyl group containing 8-30 carbons and n is an integer of 1-50, 1-75% by weight of an alkali metal or ammonium salt of an alkylbenzene sulfonate in which the alkyl group contains 10-18 carbons, and 1-20% by weight of an amine oxide corresponding to the formula RR'R"NO in which R is a primary alkyl group containing 8-24 carbons, R' is methyl, ethyl, or 2-hydroxyethyl; and R" is independently selected from methyl, ethyl, 2-hydroxyethyl, and primary alkyl groups containing 8-24 carbons and(B) as its sole detergent builder, a mixture of a sodium aluminum silicate, an anti-redeposition agent, sodium silicate, and at least one different water-soluble inorganic salt in proportions such that the laundry detergent contains 1-50% by weight of the sodium aluminum silicate, 0.1-5% by weight of the anti-redeposition agent, 1-20% by weight of the sodium silicate, and 10-80% by weight of the different inorganic salt.

摘要翻译： 具有与优质含磷酸盐洗衣洗涤剂相当的清洗性能的无磷酸盐颗粒洗衣洗涤剂具有1-30％的表面活性剂含量和至少50重量％的洗涤剂助洗剂含量，并包含：（A）为 其单独的表面活性剂，20-98重量％的对应于式Z（OCH 2 CH 2）n OH的乙氧基化脂肪醇的混合物，其中Z是含有8-30个碳的烷基，n是1-50的整数1 -75重量％的烷基苯磺酸盐的碱金属盐或铵盐，其中烷基含有10-18个碳原子，和1-20重量％的对应于式RR'R''NO的氧化胺，其中 R是含8-24个碳原子的烷基，R'是甲基，乙基或2-羟基乙基; R“独立地选自甲基，乙基，2-羟基乙基和含有8-24个碳原子的伯烷基，和（B）作为其唯一的洗涤剂助剂，硅酸钠铝，抗再沉积剂，钠 硅酸盐和至少一种不同的水溶性无机盐，其比例使得洗衣洗涤剂含有1-50重量％的硅酸铝钠，0.1-5重量％的抗再沉积剂，1-20重量％ 硅酸钠的重量和10-80％重量的不同的无机盐。

公开(公告)号：US5359139A

公开(公告)日：1994-10-25

申请号：US670568

申请日：1991-03-18

申请人： Kim R. Smith ,  James E. Borland ,  Joe D. Sauer

发明人： Kim R. Smith ,  James E. Borland ,  Joe D. Sauer

IPC分类号： C07C209/90

CPC分类号： C07C209/90

摘要： A tert-amine which contains an acid-activated color body precursor is treated to prevent it or a derivative thereof, e.g., an amine oxide, betaine, or quaternary ammonium compound, from turning pink when exposed to acidic conditions by contacting it with ascorbic acid.

摘要翻译： 处理含有酸活化的颜色体前体的叔胺以防止其或其衍生物，例如氧化胺，甜菜碱或季铵化合物，当其暴露于酸性条件时，将其与抗坏血酸接触 。

公开(公告)号：US5292954A

公开(公告)日：1994-03-08

申请号：US627982

申请日：1990-12-17

申请人： James E. Borland ,  Joe D. Sauer ,  Kim R. Smith

发明人： James E. Borland ,  Joe D. Sauer ,  Kim R. Smith

IPC分类号： C07C291/04 ,  C11D1/75 ,  C07C291/02

CPC分类号： C11D1/75 ,  C07C291/04

摘要： A pourable amine oxide composition which is suitable for use in detergent compositions is obtained by reacting a tert-amine with aqueous hydrogen peroxide in a nonionic surfactant as the sole organic solvent, at least a portion of the nonionic surfactant being an alkylphenol ethoxylate or other compound corresponding to the formula Z[OC(Z')HCH.sub.2 ].sub.m OH in which Z is an alkylphenyl group wherein the alkyl group contains 4-30 carbons, Z' is hydrogen or an alkyl or hydroxyalkyl group containing 1-3 carbons, and m is an integer of 1-100. When the composition has a low water content, it is suitable for use in water-sensitive formulations, such as bar soaps and detergent concentrates.

摘要翻译： 适用于洗涤剂组合物的可倾倒的氧化胺组合物是通过叔胺与过氧化氢水溶液作为唯一的有机溶剂在非离子表面活性剂中反应得到的，至少一部分非离子表面活性剂是烷基酚乙氧基化物或其它化合物 对应于其中Z为烷基苯基的式Z（OC（Z'）HCH 2）mOH，其中烷基含有4-30个碳，Z'为氢或含有1-3个碳的烷基或羟烷基，m为 整数1-100。 当组合物具有低含水量时，它适用于水敏性制剂，例如酒吧皂和洗涤剂浓缩物。

公开(公告)号：US5207951A

公开(公告)日：1993-05-04

申请号：US750191

申请日：1991-08-27

申请人： Joe D. Sauer ,  Kim R. Smith ,  James E. Borland ,  Terry Crutcher

发明人： Joe D. Sauer ,  Kim R. Smith ,  James E. Borland ,  Terry Crutcher

IPC分类号： C11D1/75 ,  C11D3/37

CPC分类号： C11D3/3707 ,  C11D1/75

摘要： Surfactant compositions which provide acceptable foamability at a lower cost than amine oxides consist of (A) an amine oxide corresponding to the formula RR'R"NO in which R is a primary alkyl group containing 6-24 carbons and R' and R" are independently selected from methyl, ethyl, and 2-hydroxyethyl and (B) a normally liquid polyalkylene glycol.

摘要翻译： 以比氧化胺更低的成本提供可接受的起泡性的表面活性剂组合物由（A）对应于式RR'R''NO的氧化胺组成，其中R是含有6-24个碳原子的烷基，R'和R' '独立地选自甲基，乙基和2-羟乙基，和（B）常规的聚亚烷基二醇。

公开(公告)号：US5167873A

公开(公告)日：1992-12-01

申请号：US788817

申请日：1991-11-07

申请人： Terry Crutcher ,  Jeffrey W. Perine ,  Joe D. Sauer ,  Kim R. Smith ,  James E. Borland

发明人： Terry Crutcher ,  Jeffrey W. Perine ,  Joe D. Sauer ,  Kim R. Smith ,  James E. Borland

IPC分类号： C11D1/18 ,  C11D1/52 ,  C11D1/94

CPC分类号： A61K8/42 ,  A61K8/44 ,  A61Q19/10 ,  A61Q5/02 ,  C11D1/94 ,  A61K2800/596 ,  C11D1/523 ,  Y10S516/06 ,  Y10S516/07

摘要： Surfactant mixtures which have foamability performance and/or cost advantages over the individual components consist of 50-95% by weight of an alkyldimethylbetaine in which the alkyl group contains 8-18 carbons and 50-5% by weight of a fatty acid alkanolamide. Preferred mixtures are those in which the betaine is tetradecyldimethylbetaine and the alkanolamide is cocodiethanolsuperamide.

摘要翻译： 具有比单独组分具有发泡性能和/或成本优势的表面活性剂混合物包含50-95重量％的烷基二甲基甜菜碱，其中烷基含有8-18个碳原子和50-5重量％的脂肪酸​​烷醇酰胺。 优选的混合物是其中甜菜碱是十四烷基二甲基甜菜碱，而链烷醇酰胺是椰油二乙醇胺上酰胺。

公开(公告)号：US5080810A

公开(公告)日：1992-01-14

申请号：US652615

申请日：1991-02-08

申请人： Kim R. Smith ,  Terry Crutcher ,  Joe D. Sauer ,  Jeffrey W. Perine ,  James E. Borland

发明人： Kim R. Smith ,  Terry Crutcher ,  Joe D. Sauer ,  Jeffrey W. Perine ,  James E. Borland

IPC分类号： C11D1/62 ,  C11D1/75 ,  C11D1/835 ,  C11D17/04 ,  D06M13/388 ,  D06M13/463 ,  D21H17/07

CPC分类号： C11D17/047 ,  C11D1/835 ,  C11D17/046 ,  D06M13/388 ,  D06M13/463 ,  D21H17/07 ,  C11D1/62 ,  C11D1/75

摘要： The softness of laundered fabrics, such as cotton fabrics, is improved by drying them in the presence of a laundry dryer sheet containing as the fabric softener a mixture or 50-80% by weight of N-dihydrogenatedtallow-N,N-dimethylammonium chloride and 50-20% by weight of N-octadecyl-N,N-dimethylamine oxide.

摘要翻译： 洗涤织物如棉织物的柔软度通过在包含作为织物柔软剂的衣物干燥剂片材的存在下干燥而得到改善，混合物或50-80重量％的N-二氢化粗N，N-二甲基氯化铵和 50〜20重量％的N-十八烷基-N，N-二甲基氧化胺。

公开(公告)号：US5068430A

公开(公告)日：1991-11-26

申请号：US558094

申请日：1990-07-26

申请人： James E. Borland ,  Y.-D. Mark Chen ,  Joe D. Sauer ,  Kim R. Smith ,  Rebecca F. Smith

发明人： James E. Borland ,  Y.-D. Mark Chen ,  Joe D. Sauer ,  Kim R. Smith ,  Rebecca F. Smith

IPC分类号： C07C291/04

CPC分类号： C07C291/04

摘要： Amine oxides, such as amine oxide dihydrates, which have become discolored by being prepared from tert-amines and hydrogen peroxide in a liquid medium constituting not more than 50% of the weight of the reaction mixture and in the presence of carbon dioxide are bleached by exposing them to visible light, preferably incandescent light having a luminosity of at least about 1750 lumens.

摘要翻译： 通过在构成不超过反应混合物的50重量％的液体介质中和在二氧化碳存在下由叔胺和过氧化氢制备而变色的胺氧化物如氧化胺二氧化物被漂白 将其暴露于可见光，优选具有至少约1750流明的亮度的白炽灯。

公开(公告)号：US5055614A

公开(公告)日：1991-10-08

申请号：US597067

申请日：1990-10-15

申请人： Joe D. Sauer ,  Kim R. Smith ,  James E. Borland

发明人： Joe D. Sauer ,  Kim R. Smith ,  James E. Borland

IPC分类号： C07C291/04 ,  C11D1/75

CPC分类号： C11D1/75 ,  C07C291/04

摘要： A pourable amine oxide composition which is suitable for use in detergent compositions is obtained by reacting a tert-amine with aqueous hydrogen peroxide in a nonionic surfactant as the sole organic solvent, at least a portion of the nonionic surfactant being a fatty alkanolamide corresponding to the formula ZC(O)NZ'Z" in which Z is an alkyl group containing 4-30 carbons, Z' is hydrogen or an alkyl or hydroxyalkyl group containing 1-3 carbons, and Z" is a hydroxyalkyl group containing 1-3 carbons. When the composition has a low water content, it is suitable for use in water-sensitive formulations, such as bar soaps and detergent concentrates.

摘要翻译： 适用于洗涤剂组合物的可倾倒的氧化胺组合物通过叔胺与过氧化氢水溶液作为唯一的有机溶剂在非离子表面活性剂中反应而获得，至少一部分非离子表面活性剂是对应于 式ZC（O）NZ'Z“，其中Z是含有4-30个碳的烷基，Z'是氢或含有1-3个碳的烷基或羟烷基，Z”是含1- 3个碳。 当组合物具有低含水量时，它适用于水敏性制剂，例如酒吧皂和洗涤剂浓缩物。

公开(公告)号：US4883917A

公开(公告)日：1989-11-28

申请号：US782353

申请日：1985-10-01

申请人： Kim R. Smith ,  Joe D. Sauer ,  James E. Borland

发明人： Kim R. Smith ,  Joe D. Sauer ,  James E. Borland

IPC分类号： C07C217/08

CPC分类号： C07C217/08

摘要： Disclosed herein are quaternary ammonium compounds of the formula R.sup.1 R.sup.2 R.sup.3 N.sup.+ --(CH.sub.2).sub.m Y X.sub.n.sup.- wherein n is 1 or 2 depending on the valence of the cation; m is an integer from 1 to 6; Y is a group selected from Z, --N.sup.+ R.sup.1 R.sup.2 R.sup.3, --OH, --SOCl, --CH.tbd.CH.sub.2, --O--R.sup.4, --OSiR.sup.5 R.sup.6 R.sup.7, --OC(O)R.sup.8, --CN, --SO.sub.4 Q, --C.dbd.CH, epoxide, --SR.sup.10, --S(O.sub.2)R.sup.11, --S(O)R.sup.12, ##STR1## SO.sub.3 Q, --Si(OR.sup.13)(OR.sup.14)-- (OR.sup.15), --OC(O)--(CH.sub.2).sub.p --C(O)--O--(CH.sub.2).sub.m --NR.sup.1 R.sup.2 R.sup.3, and --NR.sup.16 R.sup.17 wherein m and p are integers, the R groups are hydrocarbyl, Q is H or alkali metal. They are useful as fungicides, herbicides, antiseptics and peroxygen bleach activators.

摘要翻译： 本文公开的是式R 1 R 2 R 3 N + - （CH 2）m Y X n - 的季铵化合物，其中n为1或2，这取决于阳离子的化合价; m是1至6的整数; Y是选自Z，-N + R1R2R3，-OH，-SOCl，-CH3OND CH2，-O-R4，-OSiR5R6R7，-OC（O）R8，-CN，-SO4Q，-C = CH， 环氧化物，-SR 10，-S（O 2）R 11，-S（O）R 12，SO 3 Q，-Si（OR 13）（OR 14） - （OR 15） -O-（CH2）m-NR1R2R3和-NR16R17，其中m和p是整数，R基团是烃基，Q是H或碱金属。 它们可用作杀真菌剂，除草剂，防腐剂和过氧漂白活化剂。

公开(公告)号：US5167874A

公开(公告)日：1992-12-01

申请号：US788815

申请日：1991-11-07

申请人： James E. Borland ,  Terry Crutcher ,  Joe D. Sauer ,  Kim R. Smith

发明人： James E. Borland ,  Terry Crutcher ,  Joe D. Sauer ,  Kim R. Smith

IPC分类号： A61K8/40 ,  A61K8/46 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/18 ,  C11D1/83

CPC分类号： C11D1/83 ,  A61K8/40 ,  A61K8/466 ,  A61Q19/10 ,  A61Q5/02 ,  C11D3/0094 ,  A61K2800/596 ,  Y10S516/05 ,  Y10S516/07

摘要： Surfactant mixtures which provide denser foams than the individual components consist of 50-90% by weight of an amine oxide corresponding to the formula RR'R"NO in which R is a primary alkyl group containing 6-24 carbons and R' and R" are independently selected from methyl, ethyl, and 2-hydroxyethyl and 50-10% by weight of an alkylbenzenesulfonate surfactant. Preferred mixtures are those in which the amine oxide is N-tetradecyldimethylamine oxide and the alkylbenzenesulfonate surfactant is sodium dodecylbenzenesulfonate.

摘要翻译： 提供比各个组分更致密的泡沫的表面活性剂混合物由50-90重量％的对应于式RR'R''N的氧化胺组成，其中R是含有6-24个碳的伯烷基，R'和R 独立地选自甲基，乙基和2-羟乙基，和50-10重量％的烷基苯磺酸盐表面活性剂。 优选的混合物是其中氧化胺是N-十四烷基二甲基胺氧化物并且烷基苯磺酸盐表面活性剂是十二烷基苯磺酸钠的混合物。