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1.发明申请公开(公告)号：US20150064105A1
公开(公告)日：2015-03-05
申请号：US14477414
申请日：2014-09-04
发明人： Kazuhiro Takanabe , Tayirjan Isimjan , Weili Yu , Silvano Del Gobbo , Wei Xu
CPC分类号： B01J31/226 , B01J23/06 , B01J23/755 , B01J27/043 , B01J31/2273 , B01J31/2278 , B01J35/004 , B01J37/038 , B01J37/04 , B01J2531/847 , C01B3/065 , Y02E60/36 , Y02E60/364
摘要： The present invention is directed, at least in part, to a process for improving the efficiency of a photocatalyst (a semiconductor photocatalyst) by tethering (depositing) a metal (e.g., metal ions of a late transition metal, such as nickel) to the semiconductor (photocatalyst) surface through the use of an organic ligand. More specifically, 1,2-ethanedithiol (EDT) functions as an excellent molecular linker (organic ligand) to attach a transition metal complex (e.g., nickel (Ni2+ ions)) to the semiconductor surface, which can be in the form of a cadmium sulfide surface. The photocatalyst has particular utility in generating hydrogen from H2S.
摘要翻译： 本发明至少部分地涉及通过将金属（例如后过渡金属如镍的金属离子）束缚（沉积）（例如镍）来提高光催化剂（半导体光催化剂）的效率的方法， 半导体（光催化剂）表面通过使用有机配体。 更具体地，1,2-乙二硫醇（EDT）作为将过渡金属络合物（例如镍（Ni 2+离子））附着到半导体表面上的优异的分子接头（有机配体）起作用，其可以是镉的形式 硫化物表面。 该光催化剂特别适用于从H2S产生氢气。
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2.发明授权Tethered transition metals promoted photocatalytic system for efficient hydrogen evolutions 有权连接的过渡金属促进了光催化体系的高效氢化演化公开(公告)号：US09579639B2
公开(公告)日：2017-02-28
申请号：US14477414
申请日：2014-09-04
发明人： Kazuhiro Takanabe , Tayirjan Isimjan , Weili Yu , Silvano Del Gobbo , Wei Xu
IPC分类号： B01J31/22 , C01B3/06 , B01J37/03 , B01J37/04 , B01J23/06 , B01J23/755 , B01J27/043 , B01J35/00
CPC分类号： B01J31/226 , B01J23/06 , B01J23/755 , B01J27/043 , B01J31/2273 , B01J31/2278 , B01J35/004 , B01J37/038 , B01J37/04 , B01J2531/847 , C01B3/065 , Y02E60/36 , Y02E60/364
摘要： The present invention is directed, at least in part, to a process for improving the efficiency of a photocatalyst (a semiconductor photocatalyst) by tethering (depositing) a metal (e.g., metal ions of a late transition metal, such as nickel) to the semiconductor (photocatalyst) surface through the use of an organic ligand. More specifically, 1,2-ethanedithiol (EDT) functions as an excellent molecular linker (organic ligand) to attach a transition metal complex (e.g., nickel (Ni2+ ions)) to the semiconductor surface, which can be in the form of a cadmium sulfide surface. The photocatalyst has particular utility in generating hydrogen from H2S.
摘要翻译： 本发明至少部分地涉及通过将金属（例如后过渡金属如镍的金属离子）束缚（沉积）（例如镍）来提高光催化剂（半导体光催化剂）的效率的方法， 半导体（光催化剂）表面通过使用有机配体。 更具体地，1,2-乙二硫醇（EDT）作为将过渡金属络合物（例如镍（Ni 2+离子））附着到半导体表面上的优异的分子接头（有机配体）起作用，其可以是镉的形式 硫化物表面。 该光催化剂特别适用于从H2S产生氢气。
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公开(公告)号：US10749120B2
公开(公告)日：2020-08-18
申请号：US16330852
申请日：2017-09-05
发明人： Weili Yu , Aram Amassian , Liyang Yu
摘要： Embodiments of the present disclosure describe a method of fabricating a semiconducting material, comprising fixing a first substrate to a second substrate via a bonding material sufficient to form a two-substrate support with a cavity region, applying an organo-lead halide perovskite precursor solution to the cavity region of the two-substrate support, and annealing sufficient to form in the cavity region a semiconducting material including an organo-lead halide perovskite thin single crystal. Embodiments of the present disclosure further describe a transistor comprising a source terminal, a drain terminal, a channel layer extending between the source terminal and the drain terminal and including an organo-lead halide perovskite thin single crystal, a gate terminal, and an insulating layer separating the gate terminal from the source terminal, drain terminal, and channel layer sufficient to form a transistor.
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