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    Phosphate-phosphites acid halides
    4.
    发明授权
    Phosphate-phosphites acid halides 失效
    磷酸亚磷酸酯

    公开(公告)号：US4885381A

    公开(公告)日：1989-12-05

    申请号：US179793

    申请日：1988-04-11

    申请人： Chester E. Pawloski

    发明人： Chester E. Pawloski

    IPC分类号： C07F9/141 ,  C07F9/146 ,  C08K5/524

    CPC分类号： C08K5/524 ,  C07F9/1411 ,  C07F9/146

    摘要： Included are halogenated phosphate-phosphites and their acid halides and acids. The halogenated phosphate-phosphites can be prepared by a process comprising serially contacing(A) a phosphorus trihalide with a triol;(B) a halogenating agent; and(C) an oxirane or an alcohol;under conditions sufficient to prepare the halogenated phosphate-phosphite. Steps (A) and (B) can prepare their acid halides. Use of water in step (C) can prepare their acids. For example, 3-((bis(2-chloroethoxy)phosphino)oxy)(2-bromoethyl-2-methylpropyl, 2-bromoethyl, 2-chloroethyl)phosphorate can be prepared from 2-methyl-2-(hydroxymethyl)-1,3-propanediol; phosphorus trichloride; bromine; and ethylene oxide.Also included is use of the compounds as a hyraulic fluid or flame retardant. For example, polyurethanes can be rendered less flammable with the halogenated phosphate-phosphite flame retardant.

    摘要翻译： 包括卤代磷酸酯 - 亚磷酸酯及其酰基卤和酸。 卤代磷酸酯 - 亚磷酸酯可以通过包括（A）三卤化磷与三醇的串联方法来制备; （B）卤化剂; 和（C）环氧乙烷或醇; 在足以制备卤代磷酸酯 - 亚磷酸酯的条件下。 步骤（A）和（B）可以制备它们的酰卤。 在步骤（C）中使用水可以制备它们的酸。 例如，可以从2-甲基-2-（羟基甲基）-1（2-甲基-2-氧代乙基）氧基）（2-溴乙基） ，3-丙二醇; 三氯化磷; 溴; 和环氧乙烷。 还包括使用化合物作为液压油或阻燃剂。 例如，使用卤代磷酸酯 - 亚磷酸酯阻燃剂，可以使聚氨酯变得不易燃。

    Neucarbyl-substituted phosphorates
    5.
    发明授权
    Neucarbyl-substituted phosphorates 失效
    烯基取代的磷酸盐

    公开(公告)号：US4739091A

    公开(公告)日：1988-04-19

    申请号：US843452

    申请日：1986-03-24

    申请人： Chester E. Pawloski

    发明人： Chester E. Pawloski

    IPC分类号： C07F9/09 ,  C08K5/521

    CPC分类号： C07F9/091 ,  C08K5/521

    摘要： Included is a process for the preparation of a ((neocarbyl)contrasting-halo-substituted)phosphorate comprising serially contacting (1) a phosphorus trihalide with a neocarbyl alcohol; (2) an oxirane; (3) a halogenating agent; and (4) an oxirane, under conditions sufficient to prepare the ((neocarbyl)contrasting-halo-substituted)phosphorate.The phosphate can be very pure.Also included is a method for improving a production characteristic of flame-retardant polyurethanes. The characteristic may be selected from the group consisting of (1) processability; (2) scorch; (3) odor; (4) flame-retardant efficiency; and (5) combinations thereof. The method comprises incorporation into a polyurethane an amount effective to reduce combustibility of the foregoing phosphorate flame retardant under conditions sufficient to improve said characteristic. Also included is the flame-retardant polyurethane composition of said method. Preferably, the polyurethane is a foam, especially a flexible foam and most especially flexible slabstock foam.

    摘要翻译： 包括制备（（新碳基）对比卤素取代的）磷酸盐的方法，包括使（1）三卤化磷与新碳酸氢盐连续接触; （2）环氧乙烷; （3）卤化剂; 和（4）环氧乙烷，在足以制备（（新碳基）对比卤代取代的）磷酸盐的条件下。磷酸盐可以是非常纯的。 还包括改善阻燃聚氨酯的生产特性的方法。 特征可以选自（1）加工性; （2）焦烧; （3）气味; （4）阻燃效率; 和（5）其组合。 该方法包括在足以改善所述特性的条件下将有效降低前述磷酸酯阻燃剂的可燃性的量掺入聚氨酯中。 还包括所述方法的阻燃聚氨酯组合物。 优选地，聚氨酯是泡沫，特别是柔性泡沫，最特别是柔性块状泡沫。

    Novel primary hydroxyl-containing phosphono-s-triazines as reactants in the production of polyurethanes
    6.
    发明授权
    Novel primary hydroxyl-containing phosphono-s-triazines as reactants in the production of polyurethanes 失效
    新型含羟基的膦酰基 - 三嗪作为聚氨酯生产中的反应物

    公开(公告)号：US4607063A

    公开(公告)日：1986-08-19

    申请号：US764032

    申请日：1985-08-09

    申请人： Chester E. Pawloski ,  Sally P. Ginter

    发明人： Chester E. Pawloski ,  Sally P. Ginter

    IPC分类号： C07F9/6521 ,  C08G18/38 ,  C08G18/14

    CPC分类号： C08G18/3889 ,  C07F9/65216

    摘要： The invention is phosphono-s-triazines corresponding to the formula ##STR1## wherein: X is separately in each occurrence chlorine, bromine, haloalkyl or alkyl;Y is separately in each occurrence hydrogen, chlorine or bromine;R is separately in each occurrence hydrogen, hydrocarbyl, CH.sub.2 Y, CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3 wherein R.sup.1 is alkyl;a is an integer from 0 to 2 inclusive; andb is an integer from 1 to 3 inclusive, with the proviso that the sum of a and b equal 3, and with the further proviso that at least one R is CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3.

    摘要翻译： 本发明是对应于下式的膦酰基-s-三嗪：其中：X在每次出现时分别为氯，溴，卤代烷基或烷基; Y在每次出现时分别是氢，氯或溴; R各自独立地为氢，烃基，CH 2 Y，CH 2 OH或CH 2 OC（R 1）3，其中R 1为烷基; a是0到2的整数; b为1〜3的整数，条件是a和b之和等于3，另外条件是至少一个R为CH 2 OH或CH 2 OC（R 1）3。

    Heterocyclic substituted triazolyl phosphorous compounds
    7.
    发明授权
    Heterocyclic substituted triazolyl phosphorous compounds 失效
    杂环取代的三唑基磷化合物

    公开(公告)号：US4451653A

    公开(公告)日：1984-05-29

    申请号：US440934

    申请日：1982-11-12

    申请人： Chester E. Pawloski

    发明人： Chester E. Pawloski

    IPC分类号： A01N57/08 ,  C07D213/77 ,  C07D249/12 ,  C07F9/6518 ,  C07F9/6558 ,  C07D237/30 ,  C07D241/10

    CPC分类号： C07D213/77 ,  A01N57/08 ,  C07F9/65185 ,  C07F9/65583

    摘要： Compounds are prepared which correspond to the formulae ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.1 represents hydrogen, chloro, fluoro, bromo, alkyl of 1 to 4 carbon atoms, cycloalkyl of 3-6 carbon atoms, phenyl, phenylthio, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, thiocyanato, trifluoromethyl, trichloromethyl, amino, mono- and dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms; R.sup.2 represents methyl, ethyl, propyl or isobutyl and R.sup.3 represents methoxy, ethoxy, propoxy, ethyl, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms or phenyl.

    摘要翻译： 制备符合下式的化合物：其中R表示与下式之一相对应的含氮杂环基，每个X独立地表示氯，氟，溴，硝基 ，1至4个碳原子的烷基，氨基，单 - 或二烷基氨基，其中每个烷基独立地含有1至4个碳原子，1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至4个碳原子的烷基亚磺酰基 1至4个碳原子的烷基磺酰基，氰基，三氟甲基，三氯甲基，苯氧基或取代的苯氧基，其中每个Z独立地表示氯，氟，溴，硝基，氰基，1-4个碳原子的烷氧基或烷硫基 具有1至4个碳原子，条件是当n为2或3时，所有X基彼此在空间上相容，并且所有Z基彼此在空间上相容; Y表示氧或硫; 每个n可以独立地表示0至3的整数，包括0和3; R 1表示氢，氯，氟，溴，1至4个碳原子的烷基，3-6个碳原子的环烷基，苯基，苯硫基，1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至 4个碳原子，1至4个碳原子的烷基磺酰基，硫氰酸酯，三氟甲基，三氯甲基，氨基，单 - 和二烷基氨基，其中每个烷基独立地含有1至4个碳原子; R 2表示甲基，乙基，丙基或异丁基，R 3表示甲氧基，乙氧基，丙氧基，乙基，单 - 或二烷基氨基，其中各烷基独立地含有1至4个碳原子，1至4个碳原子的烷硫基或苯基。

    Substituted pyridine carbonyl amino ethyl esters of 2-methyl-2-propenoic acid
    8.
    发明授权
    Substituted pyridine carbonyl amino ethyl esters of 2-methyl-2-propenoic acid 失效
    取代的2-甲基-2-丙烯酸的吡啶羰基氨基乙酯

    公开(公告)号：US4418198A

    公开(公告)日：1983-11-29

    申请号：US321356

    申请日：1981-11-16

    申请人： Chester E. Pawloski

    发明人： Chester E. Pawloski

    IPC分类号： A01N47/12 ,  A01N47/18 ,  A01N47/36 ,  C07D213/64 ,  C07D213/65 ,  C07D213/68 ,  C07D213/70

    CPC分类号： C07D213/64 ,  A01N47/12 ,  A01N47/18 ,  A01N47/36 ,  C07D213/65 ,  C07D213/68 ,  C07D213/70

    摘要： The invention is directed to the novel 2-(((substituted pyridinyl)carbonyl)amino)ethyl esters of 2-methyl-2-propenoic acid and their method of preparation. The compounds are prepared by reacting an appropriately substituted pyridinol, pyridinethiol, aminopyridine, or hydroxyalkyloxypyridine with isocyanatoethyl methacrylate in an appropriate solvent in the presence of an activating agent. These compounds may be utilized as herbicides, fungicides, or both.

    摘要翻译： 本发明涉及2-甲基-2-丙烯酸的新型2 - （（（取代吡啶基）羰基）氨基）乙酯及其制备方法。 通过使适当取代的吡啶酚，吡啶硫醇，氨基吡啶或羟基烷氧基吡啶与甲基丙烯酸异氰酸根合乙酯在合适的溶剂中，在活化剂的存在下反应制备化合物。 这些化合物可以用作除草剂，杀真菌剂或两者。

    (Halo)(hydroxy)-substituted phosphites and phosphorates as flame retardants in polyurethane foams
    9.
    发明授权
    (Halo)(hydroxy)-substituted phosphites and phosphorates as flame retardants in polyurethane foams 失效
    （卤代）（羟基） - 取代亚磷酸酯和磷酸酯作为聚氨酯泡沫塑料中的阻燃剂

    公开(公告)号：US4365026A

    公开(公告)日：1982-12-21

    申请号：US250449

    申请日：1981-04-02

    申请人： Chester E. Pawloski ,  Sally P. Ginter

    发明人： Chester E. Pawloski ,  Sally P. Ginter

    IPC分类号： C08G18/38 ,  C08G18/14 ,  C07F9/02 ,  C08G18/32

    CPC分类号： C08G18/3878

    摘要： Novel (halo)(hydroxy)-substituted phosphorus-containing acid derivatives are disclosed. Preferred compounds are 2-halo-3-hydroxypropyl ester derivatives of phosphorus and phosphoric acid formed by reaction of at least some amount of tertiary butyl glycidyl ether with a halogenated derivative of a phosphorus-containing acid followed by acid dealkylation of the product. The polyol products are useful in the production of polyurethane articles such as foams having increased resistance to the effects of fire.

    摘要翻译： 公开了新的（卤代）（羟基）取代的含磷酸衍生物。 优选的化合物是由至少一定量的叔丁基缩水甘油醚与含磷酸的卤代衍生物反应形成的磷和磷酸的2-卤-3-羟基丙酯衍生物，随后产物的酸脱烷基化。 多元醇产品可用于生产具有增加的耐火效果的泡沫的聚氨酯制品。

    Aryl arenesulfonates and a method of lubrication using the aryl arenesulfonates
    10.
    发明授权
    Aryl arenesulfonates and a method of lubrication using the aryl arenesulfonates 失效
    芳基磺酰基芳基磺酸盐和使用芳基芳烃磺酸盐的润滑方法

    公开(公告)号：US5340489A

    公开(公告)日：1994-08-23

    申请号：US996548

    申请日：1992-12-24

    申请人： Bassam S. Nader ,  Chester E. Pawloski

    发明人： Bassam S. Nader ,  Chester E. Pawloski

    IPC分类号： C10M105/72 ,  C10M135/10

    CPC分类号： C10M105/72 ,  C10M2219/044 ,  C10N2230/08 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/12 ,  C10N2240/121

    摘要： A method for lubricating inorganic surfaces which comprises applying an aryl arenesulfonate between two inorganic surfaces in an amount sufficient to decrease the friction between the two surfaces, wherein the aryl arenesulfonate is of the formula ASO.sub.3 A, ASO.sub.3 BSO.sub.3 A, or (ASO.sub.3).sub.3 B wherein A is independently in each occurrence phenyl or substituted phenyl, wherein when A is substituted phenyl the phenyl can be substituted by halo, a ketone substituted by an aromatic group or alkyl group, alkyl, polyhaloalkyl, alkoxy, polyhaloalkoxy, aryl, aralkyl, haloaryl, aryloxy, polyhaloaryloxy, polyhaloalkylaryl, or polyhaloalkylaryloxy, and wherein B is benzene or two benzene rings connected by a divalent bridging group selected from the group consisting of C(CH.sub.3).sub.2, O, OCH.sub.2, OCH.sub.2 CH.sub.2, OCH.sub.2 CH.sub.2 O, C(CF.sub.3).sub.2, S, SO.sub.2, CO, and 9,9'-fluorene.

    摘要翻译： 一种用于润滑无机表面的方法，其包括在两个无机表面之间施加足够的量的芳族芳烃磺酸芳基酯以减少两个表面之间的摩擦，其中芳基芳烃磺酸盐具有式ASO3A，ASO3BSO3A或（ASO3）3B，其中A独立地 在每次出现苯基或取代的苯基时，其中当A为取代苯基时，苯基可被卤素取代，被芳基或烷基取代的酮，烷基，多卤代烷基，烷氧基，多卤代烷氧基，芳基，芳烷基，卤代芳基，芳氧基，多卤代芳基 ，多卤代烷基芳基或多卤代烷氧基，并且其中B是苯或通过选自C（CH 3）2，O，OCH 2，OCH 2 CH 2，OCH 2 CH 2 O，C（CF 3）2，S，SO 2的二价桥连基团连接的两个苯环） ，CO和9,9'-芴。