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1.发明授权Antifouling coating composition, antifouling coating film formed from the composition, coated object having the coating film on surface, and method of antifouling by forming the coating film 有权防污涂料组合物，由组合物形成的防污涂膜，表面具有涂膜的涂布物，以及通过形成涂膜的防污方法公开(公告)号：US07977407B1
公开(公告)日：2011-07-12
申请号：US13061750
申请日：2009-12-17
CPC分类号： C09D5/165 , C08L93/04 , C09D5/1618 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that can effectively exhibit an antifouling effect in seawater for a long period of time and furthermore exhibits a small temperature dependency of the coating film dissolving amount. The present invention provides an antifouling coating composition comprising: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl methacrylate monomer represented by a general formula (1) in which R1, R2, and R3 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) a methoxyalkyl methacrylate monomer represented by a general formula (2) in which R4 represents an alkylene group having 2 to 4 carbons, wherein a content ratio of the monomer (a) in the mixture is 45 to 65 weight %, and a total content of the monomer (a) and the monomer (b) in the mixture is 80 weight % or more, and a copper salt that is at least one member selected from the group consisting of rosin copper salts and copper salts of rosin derivatives.
摘要翻译： 本发明的目的是提供一种环境友好的防污涂膜的组合物，其能够长时间有效地在海水中显示防污效果，并且还显示出涂膜溶解量的温度依赖性。 本发明提供了一种防污涂料组合物，其包含：（A）通过（a）由通式（1）表示的甲基丙烯酸三有机甲硅烷酯单体（其中R 1，R 2和R 3相同）的混合物获得的含三有机甲硅烷基酯的共聚物，或 各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）由通式（2）表示的甲基丙烯酸甲氧基烷基酯单体，其中，R 4表示具有 2至4个碳，其中混合物中单体（a）的含量比为45-65重量％，并且混合物中单体（a）和单体（b）的总含量为80重量％以上 以及选自由松香铜盐和松香衍生物的铜盐组成的组中的至少一种的铜盐。
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2.发明申请公开(公告)号：US20110166253A1
公开(公告)日：2011-07-07
申请号：US13061750
申请日：2009-12-17
IPC分类号： C09D5/16
CPC分类号： C09D5/165 , C08L93/04 , C09D5/1618 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that can effectively exhibit an antifouling effect in seawater for a long period of time and furthermore exhibits a small temperature dependency of the coating film dissolving amount. The present invention provides an antifouling coating composition comprising: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl methacrylate monomer represented by a general formula (1) in which R1, R2, and R3 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) a methoxyalkyl methacrylate monomer represented by a general formula (2) in which R4 represents an alkylene group having 2 to 4 carbons, wherein a content ratio of the monomer (a) in the mixture is 45 to 65 weight %, and a total content of the monomer (a) and the monomer (b) in the mixture is 80 weight % or more, and a copper salt that is at least one member selected from the group consisting of rosin copper salts and copper salts of rosin derivatives.
摘要翻译： 本发明的目的是提供一种环境友好的防污涂膜的组合物，其能够长时间有效地在海水中显示防污效果，并且还显示出涂膜溶解量的温度依赖性。 本发明提供了一种防污涂料组合物，其包含：（A）通过（a）由通式（1）表示的甲基丙烯酸三有机甲硅烷酯单体（其中R 1，R 2和R 3相同）的混合物获得的含三有机甲硅烷基酯的共聚物，或 各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）由通式（2）表示的甲基丙烯酸甲氧基烷基酯单体，其中，R 4表示具有 2至4个碳，其中混合物中单体（a）的含量比为45-65重量％，并且混合物中单体（a）和单体（b）的总含量为80重量％以上 以及选自由松香铜盐和松香衍生物的铜盐组成的组中的至少一种的铜盐。
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3.发明申请公开(公告)号：US20110172325A1
公开(公告)日：2011-07-14
申请号：US13061708
申请日：2009-12-17
IPC分类号： C09D5/16
CPC分类号： C09D5/1612 , C08L93/04 , C09D5/1662 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that is unlikely to cause a hairline crack and like coating film defects even when immersed in seawater for a long time, and that prevents or inhibits attachment of slime. An antifouling coating composition of the invention comprises: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl (meth)acrylate monomer represented by a general formula (1): R1 is a hydrogen atom or a methyl, and R2, R3, and R4 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) an ethylenically unsaturated monomer copolymerizable with the triorganosilyl (meth)acrylate monomer, (B) a modified rosin salt which is a salt of a modified rosin and zinc and/or copper, the modified rosin containing, in an amount of 80 weight % or more, two or more members selected from the group consisting of dihydroabietic acid, tetrahydroabietic acid, dehydroabietic acid, pimaric acid, isopimaric acid, and dihydropimaric acid.
摘要翻译： 本发明的目的是提供一种用于形成环境友好的防污涂膜的组合物，其即使长时间浸入海水中也不易引起发丝裂纹和类似的涂膜缺陷，并且防止或抑制粘附 。 本发明的防污涂料组合物包含：（A）通过（a）由通式（1）表示的（甲基）丙烯酸三有机甲硅烷酯单体的混合物获得的含三有机甲硅烷基酯的共聚物：R1是氢原子或甲基 R 2，R 3和R 4相同或不同，各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）可与三有机甲硅烷基（ 甲基）丙烯酸酯单体，（B）改性松香盐，其为改性松香和锌和/或铜的盐，所述改性松香含有80重量％以上的两种或更多种选自 由二氢松香酸，四氢松香酸，脱氢松香酸，海松酸，异海松酸和二氢海松酸组成。
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4.发明授权Antifouling coating composition, antifouling coating film formed using the composition, coated article having the coating film on the surface, and antifouling treatment method to form the coating film 有权防污涂料组合物，使用该组合物形成的防污涂膜，在表面具有涂膜的涂布制品和形成涂膜的防污处理方法公开(公告)号：US07989521B1
公开(公告)日：2011-08-02
申请号：US13061708
申请日：2009-12-17
CPC分类号： C09D5/1612 , C08L93/04 , C09D5/1662 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that is unlikely to cause a hairline crack and like coating film defects even when immersed in seawater for a long time, and that prevents or inhibits attachment of slime. An antifouling coating composition of the invention comprises: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl (meth)acrylate monomer represented by a general formula (1): R1 is a hydrogen atom or a methyl, and R2, R3, and R4 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) an ethylenically unsaturated monomer copolymerizable with the triorganosilyl (meth)acrylate monomer, (B) a modified rosin salt which is a salt of a modified rosin and zinc and/or copper, the modified rosin containing, in an amount of 80 weight % or more, two or more members selected from the group consisting of dihydroabietic acid, tetrahydroabietic acid, dehydroabietic acid, pimaric acid, isopimaric acid, and dihydropimaric acid.
摘要翻译： 本发明的目的是提供一种用于形成环境友好的防污涂膜的组合物，其即使长时间浸入海水中也不易引起发丝裂纹和类似的涂膜缺陷，并且防止或抑制粘附 。 本发明的防污涂料组合物包含：（A）通过（a）由通式（1）表示的（甲基）丙烯酸三有机甲硅烷酯单体的混合物获得的含三有机甲硅烷基酯的共聚物：R1是氢原子或甲基 R 2，R 3和R 4相同或不同，各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）可与三有机甲硅烷基（ 甲基）丙烯酸酯单体，（B）改性松香盐，其为改性松香和锌和/或铜的盐，所述改性松香含有80重量％以上的两种或更多种选自 由二氢松香酸，四氢松香酸，脱氢松香酸，海松酸，异海松酸和二氢海松酸组成。
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