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1.发明授权Antifouling coating composition, antifouling coating film formed from the composition, coated object having the coating film on surface, and method of antifouling by forming the coating film 有权防污涂料组合物，由组合物形成的防污涂膜，表面具有涂膜的涂布物，以及通过形成涂膜的防污方法公开(公告)号：US07977407B1
公开(公告)日：2011-07-12
申请号：US13061750
申请日：2009-12-17
CPC分类号： C09D5/165 , C08L93/04 , C09D5/1618 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that can effectively exhibit an antifouling effect in seawater for a long period of time and furthermore exhibits a small temperature dependency of the coating film dissolving amount. The present invention provides an antifouling coating composition comprising: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl methacrylate monomer represented by a general formula (1) in which R1, R2, and R3 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) a methoxyalkyl methacrylate monomer represented by a general formula (2) in which R4 represents an alkylene group having 2 to 4 carbons, wherein a content ratio of the monomer (a) in the mixture is 45 to 65 weight %, and a total content of the monomer (a) and the monomer (b) in the mixture is 80 weight % or more, and a copper salt that is at least one member selected from the group consisting of rosin copper salts and copper salts of rosin derivatives.
摘要翻译： 本发明的目的是提供一种环境友好的防污涂膜的组合物，其能够长时间有效地在海水中显示防污效果，并且还显示出涂膜溶解量的温度依赖性。 本发明提供了一种防污涂料组合物，其包含：（A）通过（a）由通式（1）表示的甲基丙烯酸三有机甲硅烷酯单体（其中R 1，R 2和R 3相同）的混合物获得的含三有机甲硅烷基酯的共聚物，或 各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）由通式（2）表示的甲基丙烯酸甲氧基烷基酯单体，其中，R 4表示具有 2至4个碳，其中混合物中单体（a）的含量比为45-65重量％，并且混合物中单体（a）和单体（b）的总含量为80重量％以上 以及选自由松香铜盐和松香衍生物的铜盐组成的组中的至少一种的铜盐。
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2.发明申请公开(公告)号：US20110166253A1
公开(公告)日：2011-07-07
申请号：US13061750
申请日：2009-12-17
IPC分类号： C09D5/16
CPC分类号： C09D5/165 , C08L93/04 , C09D5/1618 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that can effectively exhibit an antifouling effect in seawater for a long period of time and furthermore exhibits a small temperature dependency of the coating film dissolving amount. The present invention provides an antifouling coating composition comprising: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl methacrylate monomer represented by a general formula (1) in which R1, R2, and R3 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) a methoxyalkyl methacrylate monomer represented by a general formula (2) in which R4 represents an alkylene group having 2 to 4 carbons, wherein a content ratio of the monomer (a) in the mixture is 45 to 65 weight %, and a total content of the monomer (a) and the monomer (b) in the mixture is 80 weight % or more, and a copper salt that is at least one member selected from the group consisting of rosin copper salts and copper salts of rosin derivatives.
摘要翻译： 本发明的目的是提供一种环境友好的防污涂膜的组合物，其能够长时间有效地在海水中显示防污效果，并且还显示出涂膜溶解量的温度依赖性。 本发明提供了一种防污涂料组合物，其包含：（A）通过（a）由通式（1）表示的甲基丙烯酸三有机甲硅烷酯单体（其中R 1，R 2和R 3相同）的混合物获得的含三有机甲硅烷基酯的共聚物，或 各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）由通式（2）表示的甲基丙烯酸甲氧基烷基酯单体，其中，R 4表示具有 2至4个碳，其中混合物中单体（a）的含量比为45-65重量％，并且混合物中单体（a）和单体（b）的总含量为80重量％以上 以及选自由松香铜盐和松香衍生物的铜盐组成的组中的至少一种的铜盐。
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3.发明授权Antifouling coating composition, antifouling coating film formed using the composition, coated article having the coating film on the surface, and antifouling treatment method to form the coating film 有权防污涂料组合物，使用该组合物形成的防污涂膜，在表面具有涂膜的涂布制品和形成涂膜的防污处理方法公开(公告)号：US07989521B1
公开(公告)日：2011-08-02
申请号：US13061708
申请日：2009-12-17
CPC分类号： C09D5/1612 , C08L93/04 , C09D5/1662 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that is unlikely to cause a hairline crack and like coating film defects even when immersed in seawater for a long time, and that prevents or inhibits attachment of slime. An antifouling coating composition of the invention comprises: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl (meth)acrylate monomer represented by a general formula (1): R1 is a hydrogen atom or a methyl, and R2, R3, and R4 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) an ethylenically unsaturated monomer copolymerizable with the triorganosilyl (meth)acrylate monomer, (B) a modified rosin salt which is a salt of a modified rosin and zinc and/or copper, the modified rosin containing, in an amount of 80 weight % or more, two or more members selected from the group consisting of dihydroabietic acid, tetrahydroabietic acid, dehydroabietic acid, pimaric acid, isopimaric acid, and dihydropimaric acid.
摘要翻译： 本发明的目的是提供一种用于形成环境友好的防污涂膜的组合物，其即使长时间浸入海水中也不易引起发丝裂纹和类似的涂膜缺陷，并且防止或抑制粘附 。 本发明的防污涂料组合物包含：（A）通过（a）由通式（1）表示的（甲基）丙烯酸三有机甲硅烷酯单体的混合物获得的含三有机甲硅烷基酯的共聚物：R1是氢原子或甲基 R 2，R 3和R 4相同或不同，各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）可与三有机甲硅烷基（ 甲基）丙烯酸酯单体，（B）改性松香盐，其为改性松香和锌和/或铜的盐，所述改性松香含有80重量％以上的两种或更多种选自 由二氢松香酸，四氢松香酸，脱氢松香酸，海松酸，异海松酸和二氢海松酸组成。
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4.发明申请公开(公告)号：US20110172325A1
公开(公告)日：2011-07-14
申请号：US13061708
申请日：2009-12-17
IPC分类号： C09D5/16
CPC分类号： C09D5/1612 , C08L93/04 , C09D5/1662 , C09D143/04 , C09D193/04 , Y10T428/31663 , C08L2666/26
摘要： An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that is unlikely to cause a hairline crack and like coating film defects even when immersed in seawater for a long time, and that prevents or inhibits attachment of slime. An antifouling coating composition of the invention comprises: (A) a triorganosilyl ester-containing copolymer obtained by a mixture of (a) a triorganosilyl (meth)acrylate monomer represented by a general formula (1): R1 is a hydrogen atom or a methyl, and R2, R3, and R4 are equal or different each other, and each represent an alkyl group having 3 to 6 carbons and branched on α-position or a phenyl group, and (b) an ethylenically unsaturated monomer copolymerizable with the triorganosilyl (meth)acrylate monomer, (B) a modified rosin salt which is a salt of a modified rosin and zinc and/or copper, the modified rosin containing, in an amount of 80 weight % or more, two or more members selected from the group consisting of dihydroabietic acid, tetrahydroabietic acid, dehydroabietic acid, pimaric acid, isopimaric acid, and dihydropimaric acid.
摘要翻译： 本发明的目的是提供一种用于形成环境友好的防污涂膜的组合物，其即使长时间浸入海水中也不易引起发丝裂纹和类似的涂膜缺陷，并且防止或抑制粘附 。 本发明的防污涂料组合物包含：（A）通过（a）由通式（1）表示的（甲基）丙烯酸三有机甲硅烷酯单体的混合物获得的含三有机甲硅烷基酯的共聚物：R1是氢原子或甲基 R 2，R 3和R 4相同或不同，各自表示碳原子数为3〜6的烷基，在α-位或苯基上分支，（b）可与三有机甲硅烷基（ 甲基）丙烯酸酯单体，（B）改性松香盐，其为改性松香和锌和/或铜的盐，所述改性松香含有80重量％以上的两种或更多种选自 由二氢松香酸，四氢松香酸，脱氢松香酸，海松酸，异海松酸和二氢海松酸组成。
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公开(公告)号：US20070220744A1
公开(公告)日：2007-09-27
申请号：US11587439
申请日：2005-07-21
申请人： Kenji Kitaoka , Takayoshi Fujimoto
发明人： Kenji Kitaoka , Takayoshi Fujimoto
CPC分类号： H05K3/4007 , H05K1/0284 , H05K3/107 , H05K3/1258 , H05K3/182 , H05K3/246 , H05K3/3436 , H05K3/4614 , H05K2201/0347 , H05K2201/0367 , H05K2201/0373 , H05K2201/09036 , H05K2201/09045 , H05K2201/09472 , H05K2203/0709 , H05K2203/1173 , H05K2203/1189 , H05K2203/1476 , Y10T29/49155 , Y10T29/49165
摘要： A wiring circuit board and a method of producing the same are provided in which a desired pattern of wiring is provided at higher density while permitting no overflow from the grooves of an electroless plating catalyst containing solution and an electric conductor forming liquid such as silver ink. The pattern of electric conductor is deposited by applying the electric conductor forming liquid into the grooves provided in a substrate and distributing the same along the grooves with the action of capillarity. The method starts with patterning the grooves in the surface of the substrate (S1), applying the electric conductor forming liquid into the grooves (S2), and coating the surface of the substrate with a layer of repellent liquid which is lower in the affinity with the electric conductor forming liquid (S3). This is followed by cleaning at least the grooves (S4) and then filling the grooves with the electric conductor forming liquid once again (S5). The electric conductor forming liquid applied into the grooves is then distributed throughout the grooves by the action of capillarity. When silver ink is used, the pattern of electric conductor is produced by repeating an action of applying and drying a number of times. Alternatively, the patter of electric conductor can be produced by an electroless plating technique or a combination of an electroless plating technique and an electro-plating technique for separating an electrical conductive material form the electric conductor forming liquid.
摘要翻译： 提供一种布线电路板及其制造方法，其中以更高的密度提供所需的布线图案，同时不允许来自含化学镀电镀催化剂溶液的槽和诸如银墨的电导体形成液体的槽溢出。 通过将导电剂形成液体施加到设置在基板中的凹槽中并通过毛细管作用沿着凹槽分布而将电导体的图案沉积。 该方法开始于图案化基板表面（S 1）中的凹槽，将导电体形成液体施加到凹槽（S 2）中，并且在基板的表面中涂覆一层较低的驱避液体 与导电体形成液体的亲合力（S 3）。 然后，至少清洗槽（S 4），然后再次用导电体形成液填充槽（S 5）。 然后通过毛细作用的作用将施加到槽中的导电体形成液体分布在整个槽中。 当使用银墨时，通过重复施加和干燥多次的作用产生电导体的图案。 或者，电导体的图案可以通过化学镀技术或化学镀技术和电镀技术的组合来制造，用于从形成电导体的液体中分离导电材料。
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公开(公告)号：US08993877B2
公开(公告)日：2015-03-31
申请号：US13378908
申请日：2010-06-16
IPC分类号： H01L31/00 , H01L31/048
CPC分类号： H01L31/048 , H01L31/0481 , Y02E10/50
摘要： A solar battery module has a structure in which a solar battery cell formed by a transparent electrode, a power generating element, and a back electrode is formed on a substrate, and it is sealed with a resin material such as EVA. However, there has been a problem that water enters from a gap between the substrate and a resin sealing material, thereby resulting in the corrosion of the resin or the solar battery cell. A barrier layer made of inorganic substances having portions in contact with the substrate and the second electrode is provided. Here, the barrier layer is formed by laminating at least SiO2 and an inorganic layer having a lower density than SiO2, and the film having a lower density than SiO2 is directly formed on the substrate and the second electrode.
摘要翻译： 太阳能电池模块具有在基板上形成由透明电极，发电元件和背面电极形成的太阳能电池单元的结构，并且用树脂材料如EVA密封。 然而，存在水从基板和树脂密封材料之间的间隙进入的问题，从而导致树脂或太阳能电池的腐蚀。 提供由具有与基板和第二电极接触的部分的无机物质制成的阻挡层。 这里，通过层压至少SiO 2和密度低于SiO 2的无机层来形成阻挡层，并且在基板和第二电极上直接形成具有比SiO 2低的密度的膜。
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公开(公告)号：US20120085407A1
公开(公告)日：2012-04-12
申请号：US13378908
申请日：2010-06-16
IPC分类号： H01L31/0224
CPC分类号： H01L31/048 , H01L31/0481 , Y02E10/50
摘要： A solar battery module has a structure in which a solar battery cell formed by a transparent electrode, a power generating element, and a back electrode is formed on a substrate, and it is sealed with a resin material such as EVA. However, there has been a problem that water enters from a gap between the substrate and a resin sealing material, thereby resulting in the corrosion of the resin or the solar battery cell. A barrier layer made of inorganic substances having portions in contact with the substrate and the second electrode is provided. Here, the barrier layer is formed by laminating at least SiO2 and an inorganic layer having a lower density than SiO2, and the film having a lower density than SiO2 is directly formed on the substrate and the second electrode.
摘要翻译： 太阳能电池模块具有在基板上形成由透明电极，发电元件和背面电极形成的太阳能电池单元的结构，并且用树脂材料如EVA密封。 然而，存在水从基板和树脂密封材料之间的间隙进入的问题，从而导致树脂或太阳能电池的腐蚀。 提供由具有与基板和第二电极接触的部分的无机物质制成的阻挡层。 这里，通过层压至少SiO 2和密度低于SiO 2的无机层来形成阻挡层，并且在基板和第二电极上直接形成具有比SiO 2低的密度的膜。
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8.发明申请ANTIFOULING COATING COMPOSITION, ANTIFOULING COATING FILM FORMED BY USE OF THE COMPOSITION, COATED OBJECT HAVING THE COATING FILM THEREON, AND METHOD OF ANTIFOULING TREATMENT BY FORMING THE COATING FILM 审中-公开防涂层组合物，使用组合物形成的防粘涂膜，其涂布膜的涂覆对象，以及通过形成涂膜进行抗蚀处理的方法公开(公告)号：US20120010342A1
公开(公告)日：2012-01-12
申请号：US13257532
申请日：2010-06-01
IPC分类号： C09D5/16 , C09D129/12
CPC分类号： C09D5/1668 , C09D133/14
摘要： The present invention provides an antifouling coating material which can be used to form an antifouling coating film excellent in long-term antifouling performance and physical properties, and which is excellent in long-term storage stability. The present invention provides an antifouling coating composition containing a copolymer [A] obtained by copolymerizing a monomer represented by a general formula (1) (wherein, X represents acryloyloxy, methacryloyloxy, crotonoyloxy, or isocrotonoyloxy, R1 represents a hydrogen atom or methyl, and R2 represents an alkyl group having a carbon number of 1 to 6), and a polymerizable monomer represented by a general formula (2) (wherein, R3 represents a hydrogen atom or methyl, R4 represents an alkyl group having a carbon number of 1 to 10, or an alkyl group having a carbon number of 2 to 5 to which an alkoxy group having a carbon number of 1 to 4 is bonded.).
摘要翻译： 本发明提供一种防污涂料，其可用于形成长期防污性能和物理性能优异的防污涂膜，并且其长期保存稳定性优异。 本发明提供一种防污涂料组合物，其含有通过使通式（1）表示的单体（其中X表示丙烯酰氧基，甲基丙烯酰氧基，巴豆酰氧基或异柠烷酰氧基，R1表示氢原子或甲基）和 R2表示碳数为1〜6的烷基）和由通式（2）表示的可聚合单体（其中，R3表示氢原子或甲基，R4表示碳原子数为1〜 10或碳原子数为1〜4的烷氧基的碳数为2〜5的烷基）。
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