公开(公告)号：US07732549B2

公开(公告)日：2010-06-08

申请号：US10595974

申请日：2004-11-25

申请人： Koichiro Aoyagi ,  Takeshi Niitani

发明人： Koichiro Aoyagi ,  Takeshi Niitani

IPC分类号： C08F4/06 ,  C08F12/16 ,  C08F20/22

CPC分类号： C08F12/16 ,  C08F4/06 ,  C08G83/005

摘要： The aim of the present invention is to provide a multi-branched polymer, in which branch terminals can be easily modified and which have a high degree of branching and narrow dispersion. By polymerizing a compound having 2 or more polymerization-initiation sites and polymerizable unsaturated bonds with a living radical polymerization method using a metal catalyst, it is possible to produce a multi-branched polymer with narrow dispersion and a high degree of branching and having repeating units represented by the formula (I): wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, R1 may be bonded to R3 to form a ring; X represents a connecting group having a valence of 3 or higher; Y may be the same or different and each represents a functional group which may have a halogen atom at a terminal thereof; and a is an integer of 2 or larger.

摘要翻译： 本发明的目的是提供一种多支化聚合物，其中分支端子可以容易地改性并且具有高度的支化度和窄的分散性。 通过使用金属催化剂通过活性自由基聚合法聚合具有2个以上聚合引发部位和聚合性不饱和键的化合物，可以制造具有窄分散性和高支化度的重复单元的多支链聚合物 由式（I）表示：其中R 1至R 3各自独立地表示氢或烃基，R 1可以与R 3结合形成环; X表示3价以上的连接基， Y可以相同或不同，表示可以在其末端具有卤素原子的官能团; a为2以上的整数。

公开(公告)号：US07678860B2

公开(公告)日：2010-03-16

申请号：US10571998

申请日：2004-01-23

申请人： Hiroo Muramoto ,  Takeshi Niitani ,  Koichiro Aoyagi

发明人： Hiroo Muramoto ,  Takeshi Niitani ,  Koichiro Aoyagi

IPC分类号： C08F118/02 ,  H01G9/02

CPC分类号： C08J5/2231 ,  C08F290/062 ,  C08J2325/08 ,  H01B1/122 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082

摘要： The present invention provides a polymer solid electrolyte excellent in thermal properties, physical properties and ion conductivity and being close to practical level; especially, a totally solid electrolyte and a composition for producing the same. A composition for polymer solid electrolyte includes a copolymer having repeating units represented by Formula (I): (wherein each of R1 to R3 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R4a and R4b independently represents a hydrogen atom or a methyl group; R5 represents a hydrogen atom, a hydrocarbon group, an acyl group or a silyl group; and m is an integer of 1 to 100), and repeating units represented by Formula (II): (wherein each of R6 and R8 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R9 represents an organic group having at lease one functional group selected from the group consisting of hydroxyl group, carboxyl group, epoxy group, acid anhydride group and amino group); and an electrolyte salt.

摘要翻译： 本发明提供了热性能，物理性质和离子传导性优异且接近实用水平的聚合物固体电解质; 特别是完全固体电解质及其制造用组合物。 用于聚合物固体电解质的组合物包括具有由式（I）表示的重复单元的共聚物：其中R 1至R 3各自独立地表示氢原子或C 1 -C 10烃基; R 4a和R 4b独立地表示氢原子或甲基 基团; R 5表示氢原子，烃基，酰基或甲硅烷基; m为1〜100的整数），以及由式（II）表示的重复单元：（式中，R 6和R 8各自独立地表示 氢原子或C1-C10烃基; R9表示具有至少一个选自羟基，羧基，环氧基，酸酐基和氨基的官能团的有机基团）; 和电解质盐。

公开(公告)号：US20070142504A1

公开(公告)日：2007-06-21

申请号：US10595974

申请日：2004-11-25

申请人： Koichiro Aoyagi ,  Takeshi Niitani

发明人： Koichiro Aoyagi ,  Takeshi Niitani

IPC分类号： C08K9/06

CPC分类号： C08F12/16 ,  C08F4/06 ,  C08G83/005

摘要： The aim of the present invention is to provide a multi-branched polymer, in which branch terminals can be easily modified and which have a high degree of branching and narrow dispersion. By polymerizing a compound having 2 or more polymerization-initiation sites and polymerizable unsaturated bonds with a living radical polymerization method using a metal catalyst, it is possible to produce a multi-branched polymer with narrow dispersion and a high degree of branching and having repeating units represented by the formula (I): wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, R1 may be bonded to R3 to form a ring; X represents a connecting group having a valence of 3 or higher; Y may be the same or different and each represents a functional group which may have a halogen atom at a terminal thereof; and a is an integer of 2 or larger.

摘要翻译： 本发明的目的是提供一种多支化聚合物，其中分支端子可以容易地改性并且具有高度的支化度和窄的分散性。 通过使用金属催化剂通过活性自由基聚合法聚合具有2个以上聚合引发部位和聚合性不饱和键的化合物，可以制造具有窄分散性和高支化度的重复单元的多支链聚合物 由式（I）表示：其中R 1至R 3各自独立地表示氢或烃基，R 1可以键合到 R 3形成环; X表示3价以上的连接基， Y可以相同或不同，表示可以在其末端具有卤素原子的官能团; a为2以上的整数。

公开(公告)号：US20070040145A1

公开(公告)日：2007-02-22

申请号：US10571998

申请日：2004-01-23

申请人： Hiroo Muramoto ,  Takeshi Nitani ,  Koichiro Aoyagi

发明人： Hiroo Muramoto ,  Takeshi Nitani ,  Koichiro Aoyagi

IPC分类号： H01G9/02 ,  H01M10/40 ,  C08J5/22

CPC分类号： C08J5/2231 ,  C08F290/062 ,  C08J2325/08 ,  H01B1/122 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082

摘要： The present invention provides a polymer solid electrolyte excellent in thermal properties, physical properties and ion conductivity and being close to practical level; especially, a totally solid electrolyte and a composition for producing the same. A composition for polymer solid electrolyte includes a copolymer having repeating units represented by Formula (I): (wherein each of R1 to R3 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R4a and R4b independently represents a hydrogen atom or a methyl group; R5 represents a hydrogen atom, a hydrocarbon group, an acyl group or a silyl group; and m is an integer of 1 to 100), and repeating units represented by Formula (II): (wherein each of R6 and R8 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R9 represents an organic group having at lease one functional group selected from the group consisting of hydroxyl group, carboxyl group, epoxy group, acid anhydride group and amino group); and an electrolyte salt.

摘要翻译： 本发明提供了热性能，物理性质和离子传导性优异且接近实用水平的聚合物固体电解质; 特别是完全固体电解质及其制造用组合物。 用于聚合物固体电解质的组合物包括具有由式（I）表示的重复单元的共聚物：其中R 1至R 3各自独立地表示氢原子或C 1 -C 10烃基; R 4a和R 4b独立地表示氢原子或甲基; R 5表示氢原子，烃 基团，酰基或甲硅烷基; m为1至100的整数）和由式（II）表示的重复单元：其中R 6和R 8中的每一个 独立地表示氢原子或C1-C10烃基; R 9表示具有至少一个选自羟基，羧基，环氧基的官能团的有机基团 ，酸酐基和氨基）; 和电解质盐。

公开(公告)号：US06492404B1

公开(公告)日：2002-12-10

申请号：US09763478

申请日：2001-02-20

申请人： Yasushi Shibata ,  Koichiro Aoyagi ,  Hidemitsu Takahashi ,  Takao Iwasa ,  Tomohiro Take

发明人： Yasushi Shibata ,  Koichiro Aoyagi ,  Hidemitsu Takahashi ,  Takao Iwasa ,  Tomohiro Take

IPC分类号： C07D27730

CPC分类号： C07D417/04 ,  A01N43/78 ,  C07D277/30

摘要： Compounds represented by the general formula (1); and pest controlling agents containing one or more of the compounds as the active ingredients, wherein A is substituted phenyl, C1-C6 alkly or the like; B is hydrogen, optionally substituted phenyl or the like; R is C1-C6 alkly, a group represented by the general formula: COR1 (wherein R1 is C1-C12 alkyl, C1-C6 alkoxy, C1-C6 haloalkyl or the like) or the like; X is halogeno, C1-C6 alkyl, C1-C6 haloalkyl or the like; and n is an integer of 1 to 5.

摘要翻译： 由通式（1）表示的化合物; 和含有一种或多种化合物作为活性成分的害虫控制剂，其中A是取代的苯基，C 1 -C 6烷基等; B是氢，任选取代的苯基等; R是C1-C6烷基，由通式COR1表示的基团（其中R1是C1-C12烷基，C1-C6烷氧基，C1-C6卤代烷基等）等; X是卤代，C 1 -C 6烷基，C 1 -C 6卤代烷基等; n为1〜5的整数。