公开(公告)号：US07678860B2

公开(公告)日：2010-03-16

申请号：US10571998

申请日：2004-01-23

申请人： Hiroo Muramoto ,  Takeshi Niitani ,  Koichiro Aoyagi

发明人： Hiroo Muramoto ,  Takeshi Niitani ,  Koichiro Aoyagi

IPC分类号： C08F118/02 ,  H01G9/02

CPC分类号： C08J5/2231 ,  C08F290/062 ,  C08J2325/08 ,  H01B1/122 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082

摘要： The present invention provides a polymer solid electrolyte excellent in thermal properties, physical properties and ion conductivity and being close to practical level; especially, a totally solid electrolyte and a composition for producing the same. A composition for polymer solid electrolyte includes a copolymer having repeating units represented by Formula (I): (wherein each of R1 to R3 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R4a and R4b independently represents a hydrogen atom or a methyl group; R5 represents a hydrogen atom, a hydrocarbon group, an acyl group or a silyl group; and m is an integer of 1 to 100), and repeating units represented by Formula (II): (wherein each of R6 and R8 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R9 represents an organic group having at lease one functional group selected from the group consisting of hydroxyl group, carboxyl group, epoxy group, acid anhydride group and amino group); and an electrolyte salt.

摘要翻译： 本发明提供了热性能，物理性质和离子传导性优异且接近实用水平的聚合物固体电解质; 特别是完全固体电解质及其制造用组合物。 用于聚合物固体电解质的组合物包括具有由式（I）表示的重复单元的共聚物：其中R 1至R 3各自独立地表示氢原子或C 1 -C 10烃基; R 4a和R 4b独立地表示氢原子或甲基 基团; R 5表示氢原子，烃基，酰基或甲硅烷基; m为1〜100的整数），以及由式（II）表示的重复单元：（式中，R 6和R 8各自独立地表示 氢原子或C1-C10烃基; R9表示具有至少一个选自羟基，羧基，环氧基，酸酐基和氨基的官能团的有机基团）; 和电解质盐。

公开(公告)号：US07579401B2

公开(公告)日：2009-08-25

申请号：US10523085

申请日：2003-07-23

申请人： Hiroo Muramoto ,  Takeshi Niitani

发明人： Hiroo Muramoto ,  Takeshi Niitani

IPC分类号： C08F118/02

CPC分类号： C08F290/062 ,  C08F293/005 ,  C08F2438/01 ,  H01B1/122 ,  H01M10/0525 ,  H01M10/0565 ,  H01M2300/0082

摘要： An object of the present invention is to provide a practical solid polymer electrolyte that exhibits excellent thermal characteristics, physical characteristics, and ionic conductivity, and in particular, to provide a completely solid electrolyte and a copolymer composition that functions as the substrate for producing such an electrolyte. A solid polymer electrolyte comprising an electrolyte salt, and a copolymer in which a block chain A containing a repeating unit represented by a formula (I) shown below, a block chain B containing a repeating unit represented by a formula (II) shown below: (wherein, R9 represents an aryl group), and a block chain C containing a repeating unit represented by a formula (III) shown below: (wherein, R13 represents an aryl group or a heteroaryl group) are arranged in the sequence B, A, C.

摘要翻译： 本发明的目的是提供一种表现出优异的热特性，物理特性和离子导电性的实用固体聚合物电解质，特别是提供完全固体电解质和共同组合物，其用作制备这种 电解液 包含电解质盐的固体高分子电解质和含有下述式（I）表示的重复单元的嵌段链A，含有下述式（II）所示的重复单元的嵌段链B的共聚物， （其中，R9表示芳基）和含有下述式（III）表示的重复单元的嵌段链C（其中，R 13表示芳基或杂芳基）按顺序B，A ， C。

公开(公告)号：US20050256256A1

公开(公告)日：2005-11-17

申请号：US10523085

申请日：2003-07-23

申请人： Hiroo Muramoto ,  Takeshi Niitani

发明人： Hiroo Muramoto ,  Takeshi Niitani

IPC分类号： C08F293/00 ,  C08F290/06 ,  C08F297/00 ,  H01B1/06 ,  H01B1/12 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/36 ,  C08F118/02

CPC分类号： C08F290/062 ,  C08F293/005 ,  C08F2438/01 ,  H01B1/122 ,  H01M10/0525 ,  H01M10/0565 ,  H01M2300/0082

摘要： An object of the present invention is to provide a practical solid polymer electrolyte that exhibits excellent thermal characteristics, physical characteristics, and ionic conductivity, and in particular, to provide a completely solid electrolyte and a copolymer composition that functions as the substrate for producing such an electrolyte. A solid polymer electrolyte comprising an electrolyte salt, and a copolymer in which a block chain A containing a repeating unit represented by a formula (I) shown below, a block chain B containing a repeating unit represented by a formula (II) shown below: (wherein, R9 represents an aryl group), and a block chain C containing a repeating unit represented by a formula (III) shown below: (wherein, R13 represents an aryl group or a heteroaryl group) are arranged in the sequence B, A, C.

摘要翻译： 本发明的目的是提供一种表现出优异的热特性，物理特性和离子导电性的实用固体聚合物电解质，特别是提供完全固体电解质和共同组合物，其用作制备这种 电解液 包含电解质盐的固体高分子电解质和含有下述式（I）表示的重复单元的嵌段链A，含有下述式（II）所示的重复单元的嵌段链B的共聚物， （其中R 9表示芳基）和含有如下所示的式（III）表示的重复单元的嵌段链C（式中，R 13表示 芳基或杂芳基）以序列B，A，C排列。

公开(公告)号：US07732549B2

公开(公告)日：2010-06-08

申请号：US10595974

申请日：2004-11-25

申请人： Koichiro Aoyagi ,  Takeshi Niitani

发明人： Koichiro Aoyagi ,  Takeshi Niitani

IPC分类号： C08F4/06 ,  C08F12/16 ,  C08F20/22

CPC分类号： C08F12/16 ,  C08F4/06 ,  C08G83/005

摘要： The aim of the present invention is to provide a multi-branched polymer, in which branch terminals can be easily modified and which have a high degree of branching and narrow dispersion. By polymerizing a compound having 2 or more polymerization-initiation sites and polymerizable unsaturated bonds with a living radical polymerization method using a metal catalyst, it is possible to produce a multi-branched polymer with narrow dispersion and a high degree of branching and having repeating units represented by the formula (I): wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, R1 may be bonded to R3 to form a ring; X represents a connecting group having a valence of 3 or higher; Y may be the same or different and each represents a functional group which may have a halogen atom at a terminal thereof; and a is an integer of 2 or larger.

摘要翻译： 本发明的目的是提供一种多支化聚合物，其中分支端子可以容易地改性并且具有高度的支化度和窄的分散性。 通过使用金属催化剂通过活性自由基聚合法聚合具有2个以上聚合引发部位和聚合性不饱和键的化合物，可以制造具有窄分散性和高支化度的重复单元的多支链聚合物 由式（I）表示：其中R 1至R 3各自独立地表示氢或烃基，R 1可以与R 3结合形成环; X表示3价以上的连接基， Y可以相同或不同，表示可以在其末端具有卤素原子的官能团; a为2以上的整数。

公开(公告)号：US20070142504A1

公开(公告)日：2007-06-21

申请号：US10595974

申请日：2004-11-25

申请人： Koichiro Aoyagi ,  Takeshi Niitani

发明人： Koichiro Aoyagi ,  Takeshi Niitani

IPC分类号： C08K9/06

CPC分类号： C08F12/16 ,  C08F4/06 ,  C08G83/005

摘要： The aim of the present invention is to provide a multi-branched polymer, in which branch terminals can be easily modified and which have a high degree of branching and narrow dispersion. By polymerizing a compound having 2 or more polymerization-initiation sites and polymerizable unsaturated bonds with a living radical polymerization method using a metal catalyst, it is possible to produce a multi-branched polymer with narrow dispersion and a high degree of branching and having repeating units represented by the formula (I): wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, R1 may be bonded to R3 to form a ring; X represents a connecting group having a valence of 3 or higher; Y may be the same or different and each represents a functional group which may have a halogen atom at a terminal thereof; and a is an integer of 2 or larger.

摘要翻译： 本发明的目的是提供一种多支化聚合物，其中分支端子可以容易地改性并且具有高度的支化度和窄的分散性。 通过使用金属催化剂通过活性自由基聚合法聚合具有2个以上聚合引发部位和聚合性不饱和键的化合物，可以制造具有窄分散性和高支化度的重复单元的多支链聚合物 由式（I）表示：其中R 1至R 3各自独立地表示氢或烃基，R 1可以键合到 R 3形成环; X表示3价以上的连接基， Y可以相同或不同，表示可以在其末端具有卤素原子的官能团; a为2以上的整数。

公开(公告)号：US09018311B2

公开(公告)日：2015-04-28

申请号：US13879159

申请日：2011-11-02

申请人： Takeshi Niitani ,  Toshiaki Okado ,  Hidenori Naruse ,  Tooru Kajita

发明人： Takeshi Niitani ,  Toshiaki Okado ,  Hidenori Naruse ,  Tooru Kajita

IPC分类号： C09D11/326 ,  C08F265/04 ,  C08F297/02

CPC分类号： C08F265/04 ,  C08F297/026 ,  C09D11/326

摘要： An object of the present invention is to provide a novel copolymer useful as a pigment dispersing agent in the field of color liquid crystal displays and the like. A copolymer of the present invention contains a block chain (A) comprising at least one repeating unit selected from the group consisting of a repeating unit having a tertiary amino group and a repeating unit having a quaternary ammonium base; and a block chain (B) comprising a repeating unit represented by formula (I) (wherein R1 represents a hydrogen atom or the like, R2 and R3 each independently represent a hydrogen atom or the like, Q represents an oxygen-containing saturated heterocyclic group optionally having an alkyl group as a substituent or the like, and n represents an integer of 0 to 6), and a repeating unit represented by formula (II) (wherein R4 represents a hydrogen atom or the like and R5 represents a saturated aliphatic hydrocarbon group or the like), and a copolymerization ratio of the repeating unit represented by formula (II) is 90 wt % or more in the block chain (B) excluding the repeating unit represented by formula (I).

摘要翻译： 本发明的目的是提供一种在彩色液晶显示器等领域中可用作颜料分散剂的新型共聚物。 本发明的共聚物含有包含至少一个选自具有叔氨基的重复单元和具有季铵碱基的重复单元的重复单元的嵌段链（A） 和包含由式（I）表示的重复单元的嵌段链（B）（其中R 1表示氢原子等，R 2和R 3各自独立地表示氢原子等，Q表示含氧饱和杂环基 任选具有烷基作为取代基等，n表示0〜6的整数）和由式（II）表示的重复单元（式中，R 4表示氢原子等，R 5表示饱和脂肪族烃 基团等），除式（I）表示的重复单元以外的嵌段链（B）中，由式（II）表示的重复单元的共聚比为90重量％以上。

公开(公告)号：US08142929B2

公开(公告)日：2012-03-27

申请号：US13067198

申请日：2011-05-16

申请人： Nobuhiro Sakitani ,  Naoki Imachi ,  Atsushi Kaizuka ,  Takeshi Niitani ,  Masato Amaike

发明人： Nobuhiro Sakitani ,  Naoki Imachi ,  Atsushi Kaizuka ,  Takeshi Niitani ,  Masato Amaike

IPC分类号： H01M4/60 ,  C08F118/02 ,  C08L31/02 ,  C09J167/06

CPC分类号： H01M4/621 ,  H01M4/60 ,  H01M4/602 ,  H01M4/604 ,  H01M2008/1095

摘要： A positive electrode for non-aqueous electrolyte battery includes a positive electrode active material layer containing at least a positive electrode active material and a binder and a coating layer containing a polymer provided on the positive electrode active material layer, wherein the polymer has a block chain A composed of a random copolymer containing a repeating unit (I) represented by formula (I) and a repeating unit (II) represented by formula (II) and a block chain B containing a repeating unit (III) represented by formula (III) wherein R1-R3, R4a, R4b, R5-R13 are as defined herein.

摘要翻译： 非水电解质电池用正极包括至少含有正极活性物质和粘合剂的正极活性物质层和在正极活性物质层上含有聚合物的被覆层，其中，聚合物具有嵌段链 A由含有式（I）表示的重复单元（I）和式（II）表示的重复单元（II）和含有式（III）表示的重复单元（III）的嵌段链B）的无规共聚物组成， 其中R1-R3，R4a，R4b，R5-R13如本文所定义。

公开(公告)号：US20080214685A1

公开(公告)日：2008-09-04

申请号：US11573635

申请日：2005-08-11

申请人： Takeshi Niitani ,  Kiyoshi Kawamura ,  Akihiro Shirai

发明人： Takeshi Niitani ,  Kiyoshi Kawamura ,  Akihiro Shirai

IPC分类号： C08J5/20

CPC分类号： C08F220/14 ,  C08F12/32 ,  C08F12/34 ,  C08F220/18 ,  H01M2/168 ,  H01M4/622 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082

摘要： The present invention provides a multibranched polymer represented by the following formula (I), and a method for producing the multibranched polymer: wherein A represents an organic group having 3 or more branched chains, Xa represents a linking group containing any atom of Groups 14 to 16 in the Periodic Table, Y represents a functional group having a structure capable of having an active halogen atom, Q represents an arm moiety having a repeating unit derived from a polymerizable unsaturated bond, m1 represents any integer of 1 to the number of branched chains of A, m2 represents the number of branched chains of A, n1 represents an integer of 0 or 1 or more, and Ra represents an organic group which is not associated with the polymerization reaction.

摘要翻译： 本发明提供由下式（I）表示的多分支聚合物及其制备方法：其中A表示具有3个或更多个支链的有机基团，X代表连接 含有周期表中第14至16族的任何原子的基团，Y表示具有能够具有活性卤素原子的结构的官能团，Q表示具有源自聚合性不饱和键的重复单元的臂部分， 1 表示与A的支链数相同的1的整数，m 2表示A的支链数，n表示0〜 0或1或更多，并且R a a表示与聚合反应无关的有机基团。

公开(公告)号：US20130217832A1

公开(公告)日：2013-08-22

申请号：US13879159

申请日：2011-11-02

申请人： Takeshi Niitani ,  Toshiaki Okado ,  Hidenori Naruse ,  Tooru Kajita

发明人： Takeshi Niitani ,  Toshiaki Okado ,  Hidenori Naruse ,  Tooru Kajita

IPC分类号： C08F265/04

CPC分类号： C08F265/04 ,  C08F297/026 ,  C09D11/326

摘要： An object of the present invention is to provide a novel copolymer useful as a pigment dispersing agent in the field of color liquid crystal displays and the like. A copolymer of the present invention contains a block chain (A) comprising at least one repeating unit selected from the group consisting of a repeating unit having a tertiary amino group and a repeating unit having a quaternary ammonium base; and a block chain (B) comprising a repeating unit represented by formula (I) (wherein R1 represents a hydrogen atom or the like, R2 and R3 each independently represent a hydrogen atom or the like, Q represents an oxygen-containing saturated heterocyclic group optionally having an alkyl group as a substituent or the like, and n represents an integer of 0 to 6), and a repeating unit represented by formula (II) (wherein R4 represents a hydrogen atom or the like and R5 represents a saturated aliphatic hydrocarbon group or the like), and a copolymerization ratio of the repeating unit represented by formula (II) is 90 wt % or more in the block chain (B) excluding the repeating unit represented by formula (I).

摘要翻译： 本发明的目的是提供一种在彩色液晶显示器等领域中可用作颜料分散剂的新型共聚物。 本发明的共聚物含有包含至少一个选自具有叔氨基的重复单元和具有季铵碱基的重复单元的重复单元的嵌段链（A） 和包含由式（I）表示的重复单元的嵌段链（B）（其中R 1表示氢原子等，R 2和R 3各自独立地表示氢原子等，Q表示含氧饱和杂环基 任选具有烷基作为取代基等，n表示0〜6的整数）和由式（II）表示的重复单元（式中，R 4表示氢原子等，R 5表示饱和脂肪族烃 基团等），除式（I）表示的重复单元以外的嵌段链（B）中，由式（II）表示的重复单元的共聚比为90重量％以上。

公开(公告)号：US08436103B2

公开(公告)日：2013-05-07

申请号：US11991595

申请日：2006-09-07

申请人： Takeshi Niitani

发明人： Takeshi Niitani

IPC分类号： C08F293/00 ,  C08F257/02 ,  C08G81/02

CPC分类号： C08F289/00 ,  C08F4/00 ,  C08F265/04 ,  C08F285/00 ,  C08F291/00 ,  C08F293/00 ,  C08F293/005 ,  C08F297/00 ,  C08F297/02 ,  C08G81/00 ,  C08G83/003 ,  C08L53/00 ,  C08L2666/02

摘要： The present invention provides a novel narrow distribution dendrimer-like star polymer having a controlled molecular structure, and a method capable of easily producing the star polymer. Disclosed is a polymer comprising a core portion and an arm portion, wherein the arm portion includes a first generation composed of a polymer chain and a second generation composed of a polymer chain formed at the outer shell of the first generation, the number of arms of the second generation is larger than the number of arms of the first generation, the first generation composed of the polymer chain is a polymer chain derived from a monomer having a polymerizable double bond, and the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), (Mw/Mn), of the star polymer is within a range from 1.001 to 2.50. A compound containing a functional group capable of reacting with an anion, which serves as a core portion, is reacted with a polymer chain containing two or more functional groups and an anion end which serves as an arm portion.

摘要翻译： 本发明提供了具有受控分子结构的新型窄分布树枝状大分子星形聚合物和能够容易地制备星形聚合物的方法。 公开了一种包含芯部分和臂部分的聚合物，其中臂部分包括由聚合物链组成的第一代和由在第一代的外壳形成的聚合物链构成的第二代， 第二代大于第一代的臂数，由聚合物链构成的第一代是衍生自具有可聚合双键的单体的聚合物链，并且重均分子量（Mw）与 星形聚合物的数均分子量（Mn）（Mw / Mn）在1.001〜2.50的范围内。 使含有能够与作为核心部分的阴离子反应的官能团的化合物与含有两个以上官能团的聚合物链和作为臂部分的阴离子末端反应。