公开(公告)号：US09017876B2

公开(公告)日：2015-04-28

申请号：US13275858

申请日：2011-10-18

申请人： Toshitsugu Sueki ,  Motoaki Nishijima ,  Koji Ohira ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Toshitsugu Sueki ,  Motoaki Nishijima ,  Koji Ohira ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/1391 ,  H01M4/58 ,  C01B25/45 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  C01B31/02 ,  H01M4/131 ,  H01M4/136 ,  H01M4/62 ,  H01M10/052 ,  H01M4/02

CPC分类号： H01M4/5825 ,  C01B25/45 ,  C01B32/05 ,  H01M4/131 ,  H01M4/136 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/622 ,  H01M4/623 ,  H01M10/052 ,  H01M2004/021

摘要： A method of producing a positive electrode active material, comprising the steps of: preparing a solution by dissolving, in a solvent, respective predetermined amounts of a lithium source, a M source, a phosphorus source and a X source necessary for forming a positive electrode active material represented by the following general formula (1) having an olivine structure; gelating the obtained solution by addition of a cyclic ether; and calcinating the generated gel to obtain a carbon-coated lithium-containing composite oxide, wherein the positive electrode active material is represented by the general formula (1): LixMyP1-zXzO4  (1) wherein M is at least one element selected from the group consisting of Fe, Ni, Mn, Zr, Sn, Al and Y, X is at least one selected from the group consisting of Si and Al, and 0

摘要翻译： 一种制造正极活性物质的方法，包括以下步骤：通过在溶剂中溶解规定量的锂源，M源，磷源和形成正极所需的X源来制备溶液 由具有橄榄石结构的以下通式（1）表示的活性物质; 通过加入环醚使所得溶液凝胶化; 并煅烧所生成的凝胶，得到含碳的含锂复合氧化物，其中正极活性物质由通式（1）表示：LixMyP1-zXzO4（1）其中M为选自下列的至少一种元素 由Fe，Ni，Mn，Zr，Sn，Al和Y构成的X，X是选自Si和Al中的至少一种，0

公开(公告)号：US20120100429A1

公开(公告)日：2012-04-26

申请号：US13275858

申请日：2011-10-18

申请人： Toshitsugu SUEKI ,  Motoaki Nishijima ,  Koji Ohira ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Toshitsugu SUEKI ,  Motoaki Nishijima ,  Koji Ohira ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/485 ,  H01M4/505 ,  H01M4/525

CPC分类号： H01M4/5825 ,  C01B25/45 ,  C01B32/05 ,  H01M4/131 ,  H01M4/136 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/622 ,  H01M4/623 ,  H01M10/052 ,  H01M2004/021

摘要： A method of producing a positive electrode active material, comprising the steps of: preparing a solution by dissolving, in a solvent, respective predetermined amounts of a lithium source, a M source, a phosphorus source and a X source necessary for forming a positive electrode active material represented by the following general formula (1) having an olivine structure; gelating the obtained solution by addition of a cyclic ether; and calcinating the generated gel to obtain a carbon-coated lithium-containing composite oxide, wherein the positive electrode active material is represented by the general formula (1): LixMyP1-zXzO4  (1) wherein M is at least one element selected from the group consisting of Fe, Ni, Mn, Zr, Sn, Al and Y, X is at least one selected from the group consisting of Si and Al, and 0

摘要翻译： 一种制造正极活性物质的方法，包括以下步骤：通过在溶剂中溶解规定量的锂源，M源，磷源和形成正极所需的X源来制备溶液 由具有橄榄石结构的以下通式（1）表示的活性物质; 通过加入环醚使所得溶液凝胶化; 并煅烧所生成的凝胶，得到含碳的含锂复合氧化物，其中正极活性物质由通式（1）表示：LixMyP1-zXzO4（1）其中M为选自下列的至少一种元素 由Fe，Ni，Mn，Zr，Sn，Al和Y组成的组中的至少一种，X是选自Si和Al中的至少一种，并且0

公开(公告)号：US20120070708A1

公开(公告)日：2012-03-22

申请号：US13321717

申请日：2010-05-20

申请人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/525 ,  H01B1/14 ,  H01M4/00

CPC分类号： H01M4/5825 ,  C01B33/20 ,  H01M4/131 ,  H01M4/136 ,  H01M4/525 ,  H01M4/623 ,  H01M4/625 ,  H01M10/0481 ,  H01M10/052 ,  H01M10/0585 ,  H01M10/0587 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P20/133 ,  Y10T29/4911

摘要： A cathode active material of the present invention is a cathode active material having a composition represented by General Formula (1) below, LiFe1-xMxP1-ySiyO4  (1), where: an average valence of Fe is +2 or more; M is an element having a valence of +2 or more and is at least one type of element selected from the group consisting of Zr, Sn, Y, and Al; the valence of M is different from the average valence of Fe; 0

摘要翻译： 本发明的正极活性物质是具有下述通式（1）表示的组成的LiFe1-xMxP1-ySiyO4（1）的正极活性物质，其中：Fe的平均化合价为+2以上; M是价数为+2以上的元素，为选自Zr，Sn，Y和Al中的至少一种元素; M的化合价与Fe的平均化合价不同; 0

公开(公告)号：US08999576B2

公开(公告)日：2015-04-07

申请号：US13321717

申请日：2010-05-20

申请人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shogo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/134 ,  H01M4/58 ,  H01M4/136 ,  H01M10/052

CPC分类号： H01M4/5825 ,  C01B33/20 ,  H01M4/131 ,  H01M4/136 ,  H01M4/525 ,  H01M4/623 ,  H01M4/625 ,  H01M10/0481 ,  H01M10/052 ,  H01M10/0585 ,  H01M10/0587 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P20/133 ,  Y10T29/4911

摘要： A cathode active material of the present invention is a cathode active material having a composition represented by General Formula (1) below, LiFe1-xMxP1-ySiyO4  (1), where: an average valence of Fe is +2 or more; M is an element having a valence of +2 or more and is at least one type of element selected from the group consisting of Zr, Sn, Y, and Al; the valence of M is different from the average valence of Fe; 0

摘要翻译： 本发明的正极活性物质是具有下述通式（1）表示的组成的LiFe1-xMxP1-ySiyO4（1）的正极活性物质，其中：Fe的平均化合价为+2以上; M是价数为+2以上的元素，为选自Zr，Sn，Y和Al中的至少一种元素; M的化合价与Fe的平均化合价不同; 0

公开(公告)号：US08609280B2

公开(公告)日：2013-12-17

申请号：US13175300

申请日：2011-07-01

申请人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/58 ,  H01M4/00

CPC分类号： H01B1/08 ,  H01M4/5825 ,  H01M4/621 ,  H01M4/625 ,  H01M10/052

摘要： A positive electrode active substance comprising a lithium-containing metal oxide represented by the following general formula (1): LiFe1-xMxP1-ySiyO4  (1) wherein M represents an element selected from group III to group XIV; 0

摘要翻译： 包含由以下通式（1）表示的含锂金属氧化物的正极活性物质：LiFe1-xMxP1-ySiyO4（1）其中M表示选自III〜XIV族的元素; 0

公开(公告)号：US20120003537A1

公开(公告)日：2012-01-05

申请号：US13175300

申请日：2011-07-01

申请人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Koji Ohira ,  Motoaki Nishijima ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/485 ,  H01B1/08 ,  H01M4/131 ,  H01M4/525 ,  H01M4/54

CPC分类号： H01B1/08 ,  H01M4/5825 ,  H01M4/621 ,  H01M4/625 ,  H01M10/052

摘要： A positive electrode active substance comprising a lithium-containing metal oxide represented by the following general formula (1): LiFe1-xMxP1-ySiyO4  (1) wherein M represents an element selected from group III to group XIV; 0

摘要翻译： 包含由以下通式（1）表示的含锂金属氧化物的正极活性物质：LiFe1-xMxP1-ySiyO4（1）其中M表示选自III〜XIV族的元素; 0

公开(公告)号：US09293234B2

公开(公告)日：2016-03-22

申请号：US13809551

申请日：2011-06-16

申请人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01B1/08 ,  H01M4/00 ,  C01B25/45 ,  C01B33/20 ,  H01M4/485 ,  H01M4/58 ,  H01M4/136 ,  H01M4/36 ,  H01M4/131 ,  H01M4/525 ,  H01M4/62

CPC分类号： H01B1/08 ,  C01B25/45 ,  C01B33/20 ,  H01M4/131 ,  H01M4/136 ,  H01M4/364 ,  H01M4/485 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  Y02E60/122

摘要： Provided is a positive electrode active material giving nonaqueous-electrolyte secondary batteries superior in cycle characteristics. The positive electrode active material according to the present invention includes a lithium-containing composite metal oxide having the composition represented by the following General Formula (1): LizFe1-xMxP1-ySiyO4  (1) (wherein M is at least one metal element selected from Zr, Sn, Y, and Al, 0.05 z>0.9 to 0.75 or 0.25 to 0.1>z>0; the positive electrode active material has two crystalline phases of the lithium-containing composite oxides represented by the following General Formulae (2) and (3) when 0.9 to 0.75>z>0.25 to 0.1: LiaFe1-xMxP1-ySiyO4  (2) (wherein 0.75 to 0.9≦a≦1.00, 0.05

摘要翻译： 提供了具有优异的循环特性的非水电解质二次电池的正极活性物质。 根据本发明的正极活性物质包括具有以下通式（1）表示的组成的锂复合金属氧化物：LizFe1-xMxP1-ySiyO4（1）（其中M是选自以下的至少一种金属元素： Zr，Sn，Y和Al，0.05 z> 0.9至0.75或0.25至0.1> z> 0时; 当0.9〜0.75> z> 0.25〜0.1：LiaFe1-xMxP1-ySiyO4（2）（2）时，正极活性物质由以下通式（2）和（3）表示的含锂复合氧化物的两个结晶相 0.75至0.9＆nlE; a＆nlE; 1.00,0.05

公开(公告)号：US20130115514A1

公开(公告)日：2013-05-09

申请号：US13809551

申请日：2011-06-16

申请人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/58 ,  H01M4/136 ,  H01M4/36

CPC分类号： H01B1/08 ,  C01B25/45 ,  C01B33/20 ,  H01M4/131 ,  H01M4/136 ,  H01M4/364 ,  H01M4/485 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  Y02E60/122

摘要： Provided is a positive electrode active material giving nonaqueous-electrolyte secondary batteries superior in cycle characteristics. The positive electrode active material according to the present invention includes a lithium-containing composite metal oxide having the composition represented by the following General Formula (1): LizFe1-xMxP1-ySiyO4   (1) (wherein M is at least one metal element selected from Zr, Sn, Y, and Al, 0.05 z>0.9 to 0.75 or 0.25 to 0.1>z>0; the positive electrode active material has two crystalline phases of the lithium-containing composite oxides represented by the following General Formulae (2) and (3) when 0.9 to 0.75>z>0.25 to 0.1: LiaFe1-xMxP1-ySiyO4   (2) (wherein 0.75 to 0.9≦a≦1.00, 0.05

摘要翻译： 提供了具有优异的循环特性的非水电解质二次电池的正极活性物质。 根据本发明的正极活性物质包括具有以下通式（1）表示的组成的锂复合金属氧化物：LizFe1-xMxP1-ySiyO4（1）（其中M是选自以下的至少一种金属元素： Zr，Sn，Y和Al，0.05 z> 0.9至0.75或0.25至0.1> z> 0时; 当0.9〜0.75> z> 0.25〜0.1：LiaFe1-xMxP1-ySiyO4（2）（2）时，正极活性物质由以下通式（2）和（3）表示的含锂复合氧化物的两个结晶相 0.75至0.9 @ a @ 1.00,0.05

公开(公告)号：US08968936B2

公开(公告)日：2015-03-03

申请号：US13701273

申请日：2011-06-01

申请人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/1391 ,  H01M4/58 ,  C01B25/45 ,  C01B33/20

CPC分类号： H01M4/5825 ,  C01B25/45 ,  C01B33/20

摘要： The present invention provides a method for producing a lithium-containing composite oxide represented by general formula (1) below, the method at least including a step of preparing a solution by dissolving a lithium source, an element M source, a phosphorus source, and an element X source that serve as source materials in a solvent, the phosphorus source being added after at least the element M source is dissolved; a step of gelating the resulting solution; and a step of calcining the resulting gel: LixMyP1-zXzO4  (1) (where M represents at least one element selected from the group consisting of Fe, Ni, Mn, Zr, Sn, Al, and Y; X represents at least one element selected from the group consisting of Si and Al; and 0

摘要翻译： 本发明提供一种由下述通式（1）表示的含锂复合氧化物的制造方法，该方法至少包括通过将锂源，元素M源，磷源和 在溶剂中作为原料的元素X源，在至少元素M源溶解之后添加磷源; 凝胶化所得溶液的步骤; 和煅烧所得凝胶的步骤：LixMyP1-zXzO4（1）（其中M表示选自Fe，Ni，Mn，Zr，Sn，Al和Y中的至少一种元素; X表示至少一种元素 选自Si和Al;和0

公开(公告)号：US20130075673A1

公开(公告)日：2013-03-28

申请号：US13701273

申请日：2011-06-01

申请人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/58

CPC分类号： H01M4/5825 ,  C01B25/45 ,  C01B33/20

摘要： The present invention provides a method for producing a lithium-containing composite oxide represented by general formula (1) below, the method at least including a step of preparing a solution by dissolving a lithium source, an element M source, a phosphorus source, and an element X source that serve as source materials in a solvent, the phosphorus source being added after at least the element M source is dissolved; a step of gelating the resulting solution; and a step of calcining the resulting gel: LixMyP1-zXzO4  (1) (where M represents at least one element selected from the group consisting of Fe, Ni, Mn, Zr, Sn, Al, and Y; X represents at least one element selected from the group consisting of Si and Al; and 0

摘要翻译： 本发明提供一种由下述通式（1）表示的含锂复合氧化物的制造方法，该方法至少包括通过将锂源，元素M源，磷源和 在溶剂中作为原料的元素X源，在至少元素M源溶解之后添加磷源; 凝胶化所得溶液的步骤; 和煅烧所得凝胶的步骤：LixMyP1-zXzO4（1）（其中M表示选自Fe，Ni，Mn，Zr，Sn，Al和Y中的至少一种元素; X表示至少一种元素 选自Si和Al;和0