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公开(公告)号:US10606183B2
公开(公告)日:2020-03-31
申请号:US16269020
申请日:2019-02-06
Applicant: Konica Minolta, Inc.
Inventor: Koji Shibata , Takuya Takahashi , Futoshi Kadonome , Shinya Obara
Abstract: Provided is an electrostatic latent image developing toner including toner mother particles having an external additive on a surface of the toner mother particles, wherein the external additive contains inorganic particles and aliphatic acid metal salt particles; the inorganic particles have a number average particle diameter in the range of 10 to 50 nm, and have a Mohs hardness of 8 or more; and the aliphatic acid metal salt particles have a number average particle diameter in the range of 0.4 to 2.0 μm.
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公开(公告)号:US10437166B2
公开(公告)日:2019-10-08
申请号:US16138485
申请日:2018-09-21
Applicant: Konica Minolta, Inc.
Inventor: Koji Shibata , Shinya Obara , Satoshi Uchino
Abstract: Provided is a two-component developer for developing an electrostatic latent image incorporating: toner particles each containing a toner mother particle having an external additive on a surface of the toner mother particle; and carrier particles each having a core material particle and a covering layer containing a resin on a surface of the core material particle, wherein the external additive contains inorganic particles; the inorganic particles are subjected to surface modification with silicone oil; a carbon content remained on a surface of the inorganic particle after the surface modification is within 3.0 to 10.0 mass %; a free carbon ratio on the surface of the inorganic particle is 70.0% or more; the carrier particles have a resistance in the range of 1.0×109 to 5.0×1010 Ω·cm; and the resin in the covering layer contains a resin formed from a monomer containing an alicyclic methacrylic acid ester monomer.
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公开(公告)号:US11079694B2
公开(公告)日:2021-08-03
申请号:US16793401
申请日:2020-02-18
Applicant: Konica Minolta, Inc.
Inventor: Kenshi Miyajima , Shinya Obara , Ikuko Sakurada
Abstract: A toner for electrostatic charge image development is a toner for electrostatic charge image development including toner particles containing a binder resin and an external additive, wherein the binder resin contains a crystalline polyester resin and an amorphous polyester resin, the external additive includes Al—Si composite oxide particles, and a Si element content of the Al—Si composite oxide particles is in the range of 50 to 90 mass % and a Si element ratio on surfaces of the Al—Si composite oxide particles is in the range of 3 to 35 at %.
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公开(公告)号:US20190212666A1
公开(公告)日:2019-07-11
申请号:US16194631
申请日:2018-11-19
Applicant: Konica Minolta, Inc.
Inventor: Junya UEDA , Shinya Obara , Takuya Takahashi , Ikuko Sakurada , Satoshi Uchino
CPC classification number: G03G9/09708 , G03G9/0819 , G03G9/08711 , G03G9/09716 , G03G15/0865
Abstract: Provided is an electrostatic image developing toner containing toner mother particles having external additives on a surface of the mother particle, wherein the external additives contains calcium titanate particles having an average primary particle size in the range of 50 to 150 nm, and alumina particles; and an average primary particle size of the alumina particles is less than the average primary particle size of the calcium titanate particles.
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公开(公告)号:US20150309433A1
公开(公告)日:2015-10-29
申请号:US14682708
申请日:2015-04-09
Applicant: Konica Minolta Inc.
Inventor: Ikuko SAKURADA , Satoshi Uchino , Yasuko Uchino , Shinya Obara , Futoshi Kadonome , Hiroyuki Kozuru
CPC classification number: G03G9/08711 , G03G9/0819 , G03G9/08724 , G03G9/08755 , G03G9/08795 , G03G9/09725
Abstract: An electrostatic charge image developing toner includes: toner matrix particles containing a binder resin; and an external additive added to the toner matrix particles, wherein the external additive includes joined particles each including a secondary particle including a plurality of spherical primary particles joined together, the joined particles include at least particles with a secondary particle size d2 in the range of 70 nm to 400 nm, and particles with a ratio d2/d1 in the range of 1.6 to 4.2 make up at least 50% by number of the particles with a secondary particle size d2 in the range of 70 nm to 400 nm, wherein d1 is the diameter of primary particles in the joined particle, and d2 is the secondary particle size.
Abstract translation: 静电荷图像显影调色剂包括:含有粘合剂树脂的调色剂基质颗粒; 和添加到调色剂基质颗粒中的外部添加剂,其中外部添加剂包括各自包括连接在一起的包括多个球形初级颗粒的二次颗粒的接合颗粒,所接合的颗粒至少包括二次颗粒尺寸为d2的颗粒在 70nm〜400nm的范围,d2 / d1在1.6〜4.2的范围内的粒子的二次粒径d2在70nm〜400nm的范围内至少为50%,其中d1 是连接颗粒中一次颗粒的直径,d2是二次颗粒尺寸。
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公开(公告)号:US20150248069A1
公开(公告)日:2015-09-03
申请号:US14628831
申请日:2015-02-23
Applicant: Konica Minolta, Inc.
Inventor: Satoshi UCHINO , Shinya Obara , Yasuko Uchino , Ikuko Sakurada
IPC: G03G9/08
CPC classification number: G03G9/0819 , G03G9/0825 , G03G9/0827 , G03G9/08711 , G03G9/08755 , G03G9/09716 , G03G9/09725
Abstract: An image forming method includes: charging a surface of an electrostatic latent image holder with a charging roller; exposing the charged surface so as to form an electrostatic latent image; and developing the formed electrostatic latent image with toner. The toner contains at least a toner base particle and an external additive minute particle. The external additive minute particle contains a silica-polymer composite minute particle. A silicon atom abundance ratio obtained from abundances of a carbon atom, an oxygen atom and a silicon atom present on an outermost surface and within 3 nm from the outermost surface in a depth direction of the silica-polymer composite minute particle are measured with an x-ray photoelectron spectrometer satisfies at least the following condition A. 15.0 atm %≦silicon atom abundance ratio ({Si/(C+O+Si)}×100)≦30.0 atm % [Condition A]
Abstract translation: 图像形成方法包括:利用充电辊对静电潜像保持器的表面进行充电; 暴露带电表面以形成静电潜像; 并用调色剂显影形成的静电潜像。 调色剂至少含有调色剂基础颗粒和外部添加剂微粒。 外部添加剂微粒包含二氧化硅 - 聚合物复合微粒。 从二氧化硅 - 聚合物复合微粒的深度方向的最外表面3nm以内,存在于最外表面的碳原子,氧原子和硅原子的丰度得到的硅原子丰度比用x -ray光电子能谱仪满足以下条件A. 15.0atm%≦̸硅原子丰度比({Si /(C + O + Si)}×100)≦̸ 30.0atm%[条件A]
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公开(公告)号:US09904194B2
公开(公告)日:2018-02-27
申请号:US15282177
申请日:2016-09-30
Applicant: Konica Minolta, Inc.
Inventor: Noriyuki Kimpara , Satoshi Uchino , Shinya Obara , Futoshi Kadonome , Ikuko Sakurada , Takuya Takahashi
CPC classification number: G03G9/08755 , G03G9/0819 , G03G9/08788 , G03G9/08797 , G03G9/09791
Abstract: An electrostatic latent image developing toner of the present invention includes toner base particles and particles containing a fatty acid metal salt. The toner base particles contain a crystalline resin containing a segment of a first resin and a segment of a second resin chemically bonded to each other and an amorphous resin containing at least the second resin. The crystalline resin is a hybrid crystalline polyester resin. The first resin is a crystalline polyester resin. The second resin is an amorphous resin. The volume-based median diameter (Da) of the toner base particles and the volume-based median diameter (Db) of the particles containing the fatty acid metal salt satisfy the relations represented by Expressions (1) and (2) below: 0.5 μm≦Db≦2.0 μm Expression (1) 0.1 Db/Da≦0.5. Expression (2)
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公开(公告)号:US09823596B2
公开(公告)日:2017-11-21
申请号:US15267808
申请日:2016-09-16
Applicant: Konica Minolta, Inc.
Inventor: Futoshi Kadonome , Satoshi Uchino , Shinya Obara , Noriyuki Kimpara , Ikuko Sakurada , Takuya Takahashi
CPC classification number: G03G9/09783 , G03G9/0819 , G03G9/08711 , G03G9/08755 , G03G9/0918 , G03G9/09716 , G03G9/09725 , G03G9/113 , G03G9/1133
Abstract: Provided is an electrostatic image developing toner including a toner mother particle containing a colorant and a binder resin comprising a crystalline resin and an amorphous resin; and an external additive. The external additive includes an inorganic fine particle having a number average major axis in a range of 50 to 100 nm, an average aspect ratio in a range of 3 to 10, and a volume resistivity in a range of 1×1010 to 1×1012 Ω·cm in primary particles.
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公开(公告)号:US20190278192A1
公开(公告)日:2019-09-12
申请号:US16269020
申请日:2019-02-06
Applicant: Konica Minolta, Inc.
Inventor: Koji Shibata , Takuya Takahashi , Futoshi Kadonome , Shinya Obara
IPC: G03G9/08
Abstract: Provided is an electrostatic latent image developing toner including toner mother particles having an external additive on a surface of the toner mother particles, wherein the external additive contains inorganic particles and aliphatic acid metal salt particles; the inorganic particles have a number average particle diameter in the range of 10 to 50 nm, and have a Mohs hardness of 8 or more; and the aliphatic acid metal salt particles have a number average particle diameter in the range of 0.4 to 2.0 μm.
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公开(公告)号:US10409189B2
公开(公告)日:2019-09-10
申请号:US15799354
申请日:2017-10-31
Applicant: Konica Minolta, Inc.
Inventor: Junya Ueda , Satoshi Uchino , Shinya Obara , Takuya Takahashi
Abstract: The disclosure concerns an electrostatic latent image developer including: a toner having toner base particles and an external additive; and a carrier, wherein the external additive contains silicone oil-treated silica and titanium oxide, Net intensity of titanium (Ti) in the toner to be measured by X-ray fluorescence analysis is 0.5 to 5 kcps, the carrier has a resin coating layer coating core material particles, and the resin coating layer has a constituent unit formed from an alicyclic (meth)acrylic acid ester.
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