公开(公告)号：US08835560B2

公开(公告)日：2014-09-16

申请号：US13283275

申请日：2011-10-27

申请人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colombo ,  Geert Verlinden

发明人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colombo ,  Geert Verlinden

IPC分类号： C08F297/04 ,  C08F8/00 ,  B32B7/12

CPC分类号： B32B7/12 ,  C08F8/04 ,  C08F297/044 ,  Y10T428/139

摘要： Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.

摘要翻译： 具有星形分子结构的弹性嵌段共聚物，其中星形分子结构具有至少两个不同的星形臂，制备弹性体嵌段共聚物的方法，弹性体嵌段共聚物用于生产模制品或粘合剂 多层箔; 作为密封; 作为木塑复合材料中的粘合促进剂或热塑性组分; 作为热熔胶组件; 用于冲击改性热塑性塑料或弹性体，或用于增容，以及由至少一种弹性体嵌段共聚物组成的箔，泡沫，热塑性塑料，注射成型品，柔性管或型材挤出物。

公开(公告)号：US20110257335A1

公开(公告)日：2011-10-20

申请号：US13141840

申请日：2009-12-14

申请人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

发明人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

IPC分类号： C08L53/02 ,  C08F279/00

CPC分类号： C08F297/04 ,  C08L25/06 ,  C08L25/10 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

摘要： A block copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprisinga) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, andb) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., andc) at least one copolymer block (S/B)B composed of from 20 to 60% by weight of vinylaromatic monomers and from 40 to 80% by weight of dienes, with glass transition temperature TgB in the range from 0 to −80° C.,where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, and the proportion by weight of the entirety of all of the blocks (S/B)A and (S/B)B is in the range from 30 to 50% by weight, based in each case on the block copolymer A, and also mixtures thereof, and their use.

摘要翻译： 一种重均摩尔质量Mw至少为100000g / mol的嵌段共聚物，包含a）至少一种由95-100％（重量）乙烯基芳族单体和0-5％（重量）二烯组成的嵌段S， 和b）由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的至少一种共聚物嵌段（S / B）A，玻璃化转变温度TgA在5至30℃的范围内 C）和c）由20至60重量％的乙烯基芳族单体和40至80重量％的二烯组成的至少一种共聚物嵌段（S / B）B，玻璃化转变温度TgB为0 至-80℃，其中全部块S的重量比例在50至70重量％的范围内，并且全部块的重量比（S / B ）A和（S / B）B在30至50重量％的范围内，基于嵌段共聚物A的每种情况，以及它们的混合物及其用途。

公开(公告)号：US08536279B2

公开(公告)日：2013-09-17

申请号：US13141870

申请日：2009-12-14

申请人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

发明人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

IPC分类号： C08L53/02 ,  C08F279/00

CPC分类号： C08L25/10 ,  C08F257/02 ,  C08F279/02 ,  C08F297/04 ,  C08F297/044 ,  C08L25/06 ,  C08L51/003 ,  C08L51/06 ,  C08L53/02 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/06

摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.

摘要翻译： 包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％ 的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

公开(公告)号：US20120061287A1

公开(公告)日：2012-03-15

申请号：US13141870

申请日：2009-12-14

申请人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

发明人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

IPC分类号： B65D85/86 ,  C08L53/02 ,  C08F12/08

CPC分类号： C08L25/10 ,  C08F257/02 ,  C08F279/02 ,  C08F297/04 ,  C08F297/044 ,  C08L25/06 ,  C08L51/003 ,  C08L51/06 ,  C08L53/02 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/06

摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.

摘要翻译： 包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的组分 的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

公开(公告)号：US08759445B2

公开(公告)日：2014-06-24

申请号：US13000817

申请日：2009-06-23

申请人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

发明人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

IPC分类号： C08L53/02 ,  C08F297/04

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L2666/02 ,  C08L2666/24

摘要： A mixture which comprises a) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C., c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, and d) from 0 to 6% by weight of processing aids D, where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.

摘要翻译： 一种混合物，其包含a）5至95重量％的共聚物A，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％ 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内，b）95至5重量％的嵌段共聚物B，其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯，并且包含一种或多种共聚物嵌段（B / S）A，各自由65至95重量％的乙烯基芳族单体和35至5重量％ 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA，并且包含一种或多种共聚物嵌段（B / S）B，各自由20至60重量％的乙烯基芳族单体组成， 80〜40重量％的二烯，玻璃化转变温度TgB在-70℃〜0℃的范围内，c）0〜45％的重量 除了A和B之外的热塑性聚合物C，以及d）0至6重量％的加工助剂D，其中A至D的总量为100重量％，以及其用于生产收缩膜的用途。

公开(公告)号：US20120107540A1

公开(公告)日：2012-05-03

申请号：US13283275

申请日：2011-10-27

申请人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colmbo ,  Geert Verlinden

发明人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colmbo ,  Geert Verlinden

IPC分类号： B32B1/08 ,  C08F8/00 ,  C08F8/42 ,  C08F297/00

CPC分类号： B32B7/12 ,  C08F8/04 ,  C08F297/044 ,  Y10T428/139

摘要： Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.

摘要翻译： 具有星形分子结构的弹性嵌段共聚物，其中星形分子结构具有至少两个不同的星形臂，制备弹性体嵌段共聚物的方法，弹性体嵌段共聚物用于生产模制品或粘合剂 多层箔; 作为密封; 作为木塑复合材料中的粘合促进剂或热塑性组分; 作为热熔胶组件; 用于冲击改性热塑性塑料或弹性体，或用于增容，以及由至少一种弹性体嵌段共聚物组成的箔，泡沫，热塑性塑料，注射成形品，柔性管或型材挤出物。

公开(公告)号：US20110098401A1

公开(公告)日：2011-04-28

申请号：US13000817

申请日：2009-06-23

申请人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

发明人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

IPC分类号： C08L53/02

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L2666/02 ,  C08L2666/24

摘要： A mixture which comprisesa) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C.,b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C.,c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, andd) from 0 to 6% by weight of processing aids D,where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.

摘要翻译： 一种混合物，其包含a）5至95重量％的共聚物A，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％ 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内，b）95至5重量％的嵌段共聚物B，其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯，并且包含一种或多种共聚物嵌段（B / S）A，各自由65至95重量％的乙烯基芳族单体和35至5重量％ 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA，并且包含一种或多种共聚物嵌段（B / S）B，各自由20至60重量％的乙烯基芳族单体组成， 80〜40重量％的二烯，玻璃化转变温度TgB在-70℃〜0℃的范围内，c）0〜45％的重量 除了A和B之外的热塑性聚合物C，以及d）0至6重量％的加工助剂D，其中A至D的总量为100重量％，以及其用于生产收缩膜的用途。