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    PHASE-SEPARATING BLOCK COPOLYMERS COMPOSED OF INCOMPATIBLE HARD BLOCKS AND MOLDING MATERIALS WITH HIGH STIFFNESS
    1.
    发明申请
    PHASE-SEPARATING BLOCK COPOLYMERS COMPOSED OF INCOMPATIBLE HARD BLOCKS AND MOLDING MATERIALS WITH HIGH STIFFNESS 审中-公开
    组成不可分割硬块的相分离块状共聚物和具有高刚度的成型材料

    公开(公告)号：US20110257335A1

    公开(公告)日：2011-10-20

    申请号：US13141840

    申请日：2009-12-14

    申请人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

    发明人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner ,  Geert Verlinden ,  Roland Weidisch

    IPC分类号： C08L53/02 ,  C08F279/00

    CPC分类号： C08F297/04 ,  C08L25/06 ,  C08L25/10 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

    摘要： A block copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprisinga) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, andb) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., andc) at least one copolymer block (S/B)B composed of from 20 to 60% by weight of vinylaromatic monomers and from 40 to 80% by weight of dienes, with glass transition temperature TgB in the range from 0 to −80° C.,where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, and the proportion by weight of the entirety of all of the blocks (S/B)A and (S/B)B is in the range from 30 to 50% by weight, based in each case on the block copolymer A, and also mixtures thereof, and their use.

    摘要翻译： 一种重均摩尔质量Mw至少为100000g / mol的嵌段共聚物，包含a）至少一种由95-100％（重量）乙烯基芳族单体和0-5％（重量）二烯组成的嵌段S， 和b）由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的至少一种共聚物嵌段（S / B）A，玻璃化转变温度TgA在5至30℃的范围内 C）和c）由20至60重量％的乙烯基芳族单体和40至80重量％的二烯组成的至少一种共聚物嵌段（S / B）B，玻璃化转变温度TgB为0 至-80℃，其中全部块S的重量比例在50至70重量％的范围内，并且全部块的重量比（S / B ）A和（S / B）B在30至50重量％的范围内，基于嵌段共聚物A的每种情况，以及它们的混合物及其用途。

    TRANSPARENT, TOUGH AND RIGID MOLDING COMPOSITIONS BASED ON STYRENE-BUTADIENE BLOCK COPOLYMER MIXTURES
    4.
    发明申请
    TRANSPARENT, TOUGH AND RIGID MOLDING COMPOSITIONS BASED ON STYRENE-BUTADIENE BLOCK COPOLYMER MIXTURES 失效
    基于苯乙烯 - 丁二烯嵌段共聚物混合物的透明，粗糙和刚性成型组合物

    公开(公告)号：US20100304067A1

    公开(公告)日：2010-12-02

    申请号：US12677960

    申请日：2008-09-03

    申请人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner

    发明人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner

    IPC分类号： C08L53/02 ,  B32B3/12 ,  B32B1/08

    CPC分类号： C08L25/06 ,  C08K5/0016 ,  C08L25/10 ,  C08L53/02 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/24 ,  C08L2666/02

    摘要： A mixture which comprises a) from 95 to 30% by weight of a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) from 5 to 45% by weight of a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −70° to 0° C., c) from 0 to 40% by weight of polystyrene C, and d) from 0 to 30% by weight of a block copolymer D comprising at least one copolymer block (B/S)A which is respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., and comprising at least one diene block B or one copolymer block (B/S)B which is respectively composed of from 1 to 60% by weight of vinylaromatic monomers and of from 99 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −100° to 0° C., e) from 0 to 6% by weight of a plastifying agent, and its use for the production of packaging for electronics components.

    摘要翻译： 包含a）95至30重量％的共聚物或嵌段共聚物A，其包含一种或多种共聚物嵌段（B / S）A，其分别由65至95重量％的乙烯基芳族单体和 35〜5重量％的二烯，玻璃化转变温度TgA在40℃〜90℃的范围内，b）5〜45重量％的嵌段共聚物B，其包含至少一个硬嵌段S， 由乙烯基芳族单体组成，并且包含一种或多种共聚物嵌段（B / S）B，其分别由20至60重量％的乙烯基芳族单体和80至40重量％的二烯组成，并且其玻璃化转变 温度TgB在-70℃至0℃的范围内，c）0至40重量％的聚苯乙烯C，以及d）0至30重量％的嵌段共聚物D，其包含至少一个共聚物嵌段 （B / S）A，其分别由65至95重量％的乙烯基芳族单体和35至5重量％的重量 并且其玻璃化转变温度TgA在40℃至90℃的范围内，并且包含至少一个二烯嵌段B或一个共聚物嵌段（B / S）B，其分别由1至60个 乙烯基芳族单体的重量百分比和99至40重量％的二烯，其玻璃化转变温度TgB在-100℃至0℃的范围内，e）0至6重量％的塑化 代理商及其用于生产电子元件包装的用途。

    Transparent, tough and rigid molding compositions based on styrene-butadiene block copolymer mixtures
    5.
    发明授权
    Transparent, tough and rigid molding compositions based on styrene-butadiene block copolymer mixtures 失效
    基于苯乙烯 - 丁二烯嵌段共聚物混合物的透明，坚韧和刚性的模塑组合物

    公开(公告)号：US08575269B2

    公开(公告)日：2013-11-05

    申请号：US12677960

    申请日：2008-09-03

    申请人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner

    发明人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner

    IPC分类号： C08L53/02 ,  B32B3/12 ,  B32B1/08

    CPC分类号： C08L25/06 ,  C08K5/0016 ,  C08L25/10 ,  C08L53/02 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/24 ,  C08L2666/02

    摘要： A mixture which contains a) a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −70° to 0° C., c) a polystyrene C, and its use for the production of packaging for electronics components.

    摘要翻译： 包含a）共聚物或嵌段共聚物A的组合物，其包含一种或多种共聚物嵌段（B / S）A，它们分别由65至95重量％的乙烯基芳族单体和35至5重量％的二烯 并且其玻璃化转变温度TgA在40℃至90℃的范围内，b）嵌段共聚物B，其包含至少一个由乙烯基芳族单体组成的硬质块S，并且包含一个或多个共聚物嵌段（B / S）B，其分别由20至60重量％的乙烯基芳族单体和80至40重量％的二烯组成，并且其玻璃化转变温度TgB在-70℃至0℃的范围内， c）聚苯乙烯C及其用于生产电子元件包装的用途。

    Styrene butadiene block copolymer mixtures for shrink-wrap films
    6.
    发明授权
    Styrene butadiene block copolymer mixtures for shrink-wrap films 有权
    用于收缩膜的苯乙烯丁二烯嵌段共聚物混合物

    公开(公告)号：US08759445B2

    公开(公告)日：2014-06-24

    申请号：US13000817

    申请日：2009-06-23

    申请人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

    发明人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

    IPC分类号： C08L53/02 ,  C08F297/04

    CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L2666/02 ,  C08L2666/24

    摘要： A mixture which comprises a) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C., c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, and d) from 0 to 6% by weight of processing aids D, where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.

    摘要翻译： 一种混合物，其包含a）5至95重量％的共聚物A，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％ 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内，b）95至5重量％的嵌段共聚物B，其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯，并且包含一种或多种共聚物嵌段（B / S）A，各自由65至95重量％的乙烯基芳族单体和35至5重量％ 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA，并且包含一种或多种共聚物嵌段（B / S）B，各自由20至60重量％的乙烯基芳族单体组成， 80〜40重量％的二烯，玻璃化转变温度TgB在-70℃〜0℃的范围内，c）0〜45％的重量 除了A和B之外的热塑性聚合物C，以及d）0至6重量％的加工助剂D，其中A至D的总量为100重量％，以及其用于生产收缩膜的用途。

    ELASTOMERIC BLOCK COPOLYMERS HAVING STAR-SHAPED MOLECULAR ARCHITECTURE, WHERE THE STAR-SHAPED MOLECULAR ARCHITECTURE HAS AT LEAST TWO DIFFERENT ARMS IN THE STAR
    7.
    发明申请
    ELASTOMERIC BLOCK COPOLYMERS HAVING STAR-SHAPED MOLECULAR ARCHITECTURE, WHERE THE STAR-SHAPED MOLECULAR ARCHITECTURE HAS AT LEAST TWO DIFFERENT ARMS IN THE STAR 有权
    具有星型分子结构的弹性体嵌段共聚物，星型分子结构在星形中至少有两种不同的结构

    公开(公告)号：US20120107540A1

    公开(公告)日：2012-05-03

    申请号：US13283275

    申请日：2011-10-27

    申请人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colmbo ,  Geert Verlinden

    发明人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colmbo ,  Geert Verlinden

    IPC分类号： B32B1/08 ,  C08F8/00 ,  C08F8/42 ,  C08F297/00

    CPC分类号： B32B7/12 ,  C08F8/04 ,  C08F297/044 ,  Y10T428/139

    摘要： Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.

    摘要翻译： 具有星形分子结构的弹性嵌段共聚物，其中星形分子结构具有至少两个不同的星形臂，制备弹性体嵌段共聚物的方法，弹性体嵌段共聚物用于生产模制品或粘合剂 多层箔; 作为密封; 作为木塑复合材料中的粘合促进剂或热塑性组分; 作为热熔胶组件; 用于冲击改性热塑性塑料或弹性体，或用于增容，以及由至少一种弹性体嵌段共聚物组成的箔，泡沫，热塑性塑料，注射成形品，柔性管或型材挤出物。

    STYRENE BUTADIENE BLOCK COPOLYMER MIXTURES FOR SHRINK-WRAP FILMS
    8.
    发明申请
    STYRENE BUTADIENE BLOCK COPOLYMER MIXTURES FOR SHRINK-WRAP FILMS 有权
    苯乙烯丁二烯嵌段共聚物混合胶带

    公开(公告)号：US20110098401A1

    公开(公告)日：2011-04-28

    申请号：US13000817

    申请日：2009-06-23

    申请人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

    发明人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

    IPC分类号： C08L53/02

    CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L2666/02 ,  C08L2666/24

    摘要： A mixture which comprisesa) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C.,b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C.,c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, andd) from 0 to 6% by weight of processing aids D,where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.

    摘要翻译： 一种混合物，其包含a）5至95重量％的共聚物A，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％ 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内，b）95至5重量％的嵌段共聚物B，其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯，并且包含一种或多种共聚物嵌段（B / S）A，各自由65至95重量％的乙烯基芳族单体和35至5重量％ 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA，并且包含一种或多种共聚物嵌段（B / S）B，各自由20至60重量％的乙烯基芳族单体组成， 80〜40重量％的二烯，玻璃化转变温度TgB在-70℃〜0℃的范围内，c）0〜45％的重量 除了A和B之外的热塑性聚合物C，以及d）0至6重量％的加工助剂D，其中A至D的总量为100重量％，以及其用于生产收缩膜的用途。

    Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms in the star
    9.
    发明授权
    Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms in the star 有权
    具有星形分子结构的弹性嵌段共聚物，其中星形分子结构在星形中具有至少两个不同的臂

    公开(公告)号：US08835560B2

    公开(公告)日：2014-09-16

    申请号：US13283275

    申请日：2011-10-27

    申请人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colombo ,  Geert Verlinden

    发明人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colombo ,  Geert Verlinden

    IPC分类号： C08F297/04 ,  C08F8/00 ,  B32B7/12

    CPC分类号： B32B7/12 ,  C08F8/04 ,  C08F297/044 ,  Y10T428/139

    摘要： Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.

    摘要翻译： 具有星形分子结构的弹性嵌段共聚物，其中星形分子结构具有至少两个不同的星形臂，制备弹性体嵌段共聚物的方法，弹性体嵌段共聚物用于生产模制品或粘合剂 多层箔; 作为密封; 作为木塑复合材料中的粘合促进剂或热塑性组分; 作为热熔胶组件; 用于冲击改性热塑性塑料或弹性体，或用于增容，以及由至少一种弹性体嵌段共聚物组成的箔，泡沫，热塑性塑料，注射成型品，柔性管或型材挤出物。

    Highly transparent and tough-stiff styrene-butadiene block copolymer mixtures
    10.
    发明授权
    Highly transparent and tough-stiff styrene-butadiene block copolymer mixtures 有权
    高度透明和坚韧的苯乙烯 - 丁二烯嵌段共聚物混合物

    公开(公告)号：US08217104B2

    公开(公告)日：2012-07-10

    申请号：US12306258

    申请日：2007-06-13

    申请人： Jennifer Stewart ,  Peter Merkel ,  Daniel Wagner ,  Konrad Knoll ,  Jürgen Koch

    发明人： Jennifer Stewart ,  Peter Merkel ,  Daniel Wagner ,  Konrad Knoll ,  Jürgen Koch

    IPC分类号： C08F293/00 ,  C08F295/00 ,  C08F297/04 ,  C08L53/00 ,  C08L53/02

    CPC分类号： C08F297/044 ,  C08F297/04 ,  C08L53/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/24 ,  C08L25/06

    摘要： A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.

    摘要翻译： 一种混合物，其包含a）25至75重量％的嵌段共聚物A，其包含至少一种由乙烯基芳族单体组成的硬质块S，并且包含一种或多种软块BA，每种情况由0至5重量％ 的乙烯基芳族单体和95〜100重量％的二烯，其中嵌段共聚物A中的硬质块S的重量比为65〜90重量％ b）5至25重量％的嵌段共聚物B，其包含至少一种由乙烯基芳族单体组成的硬质块S，并且包含一种或多种共聚物嵌段（B / S）B，每种情况下由20至60％由 乙烯基芳族单体的重量和80〜40重量％的二烯，其中嵌段共聚物B中的硬质块S的重量比为25〜70重量％ c）0至70重量％的聚苯乙烯或除A和B之外的嵌段共聚物C，以及d）0至6重量％的增塑剂D，其中组分A）至D）的总量为100 重量％，用于透明热成型箔或透明注塑件。