公开(公告)号：US06727333B2

公开(公告)日：2004-04-27

申请号：US10207067

申请日：2002-07-30

申请人： Kotohiro Nomura ,  Seiki Kiuchi ,  Tatsuya Miyatake

发明人： Kotohiro Nomura ,  Seiki Kiuchi ,  Tatsuya Miyatake

IPC分类号： C08F200

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/027 ,  C08F4/6546 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10 ,  C08F2500/24

摘要： There are disclosed: (i) a first solid catalyst component (A1) obtained by contacting (a) a carrier of carboxyl group-carrying polymer particles having an average particle size of from about 1 to 200 &mgr;m, (b) an organometallic compound of the number 1, 2 or 13 group of metals in the periodic table of elements, and (c) a transition metal compound of the number 4 group of metals of the periodic table of elements, and a second solid catalyst component (A2) obtained by contacting (a), (b), (c) and (d) a phenol compound, and production processes of the solid catalyst components (A1) and (A2), (ii) a catalyst obtained by combining the solid catalyst component (A1) or (A2) with an organoaluminum compound (B); and (iii) a process for producing an olefin polymer with a catalyst of the invention, wherein the polymer produced is extremely low in its content of lower molecular weight components and low crystallinity components, and superior in its powder properties.

摘要翻译： 公开了：（i）第一固体催化剂组分（A1），其通过使（a）平均粒径为约1-200μm的含羧基的聚合物颗粒的载体与（b）有机金属化合物 元素周期表中第1,2族或第13族金属，以及（c）元素周期表第4族金属的过渡金属化合物和第二固体催化剂成分（A2），通过 （a），（b），（c）和（d）的酚化合物，以及固体催化剂组分（A1）和（A2）的制备方法，（ii）将固体催化剂组分 ）或（A2）与有机铝化合物（B）反应; 和（iii）用本发明的催化剂生产烯烃聚合物的方法，其中所制备的聚合物的低分子量组分和低结晶度组分的含量极低，并且其粉末性能优异。

公开(公告)号：US06468937B1

公开(公告)日：2002-10-22

申请号：US09281212

申请日：1999-03-30

申请人： Kotohiro Nomura ,  Seiki Kiuchi ,  Tatsuya Miyatake

发明人： Kotohiro Nomura ,  Seiki Kiuchi ,  Tatsuya Miyatake

IPC分类号： B01J3100

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/027 ,  C08F4/6546 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10 ,  C08F2500/24

摘要： There are disclosed: (i) a first solid catalyst component obtained by contacting (a) a carrier of carboxyl group-carrying polymer particles having an average particle size of from about 1 to 200 &mgr;m with spherical or elliptical particles morphology (b) an organometallic compound of the number 1, 2 or 13 group of metals in the periodic table of elements, and (c) a transition metal compound of the number 4 group of metals of the periodic table of elements, and a second solid catalyst component obtained by contacting (a), (b), (c) and (d) a phenol compound, and production processes of the two solid catalyst components, (ii) a catalyst obtained by combining the two solid catalyst components with an organoaluminum compound; and (iii) a process for producing an olefin polymer with a catalyst of the invention, wherein the polymer produced is extremely low in its content of lower molecular weight components and low crystallinity components, and superior in its powder properties.

摘要翻译： 公开了：（i）第一固体催化剂组分，其通过使（a）具有平均粒径为约1-200μm的含羧基的聚合物颗粒的载体与球形或椭圆形颗粒形态（b）接触而获得;（b）有机金属 元素周期表中第1,2族或13族金属的化合物，和（c）元素周期表第4族金属的过渡金属化合物和通过接触获得的第二固体催化剂组分 （a），（b），（c）和（d）酚化合物和两种固体催化剂组分的制备方法，（ii）通过将两种固体催化剂组分与有机铝化合物组合获得的催化剂; 和（iii）用本发明的催化剂生产烯烃聚合物的方法，其中所制备的聚合物的低分子量组分和低结晶度组分的含量极低，并且其粉末性能优异。

公开(公告)号：US06544921B1

公开(公告)日：2003-04-08

申请号：US09661296

申请日：2000-09-13

申请人： Tatsuya Miyatake ,  Masaaki Nabika ,  Seiki Kiuchi

发明人： Tatsuya Miyatake ,  Masaaki Nabika ,  Seiki Kiuchi

IPC分类号： B01J3100

CPC分类号： C08F210/16 ,  C08F4/6421 ,  C08F4/027 ,  C08F4/651 ,  C08F210/08 ,  C08F2500/10 ,  C08F2500/12

摘要： There are provided: (I) a solid catalyst component (A-1) for olefin polymerization, which is obtained by a process comprising the step of contacting: (a-1) a carrier of carboxyl group-carrying polymer particles having an average particle diameter of from 1 to 300 &mgr;m, and (b) a transition metal compound of the number 4 group of metals in the periodic table of elements; (II) a catalyst for olefin polymerization, which is obtained by a process comprising the step of contacting: (A-1) the above solid catalyst component, and (B) at least one compound selected from the group consisting of an organoaluminum compound and an organoaluminumoxy compound; (III) a process for producing an olefin polymer, which comprises the step of polymerizing an olefin in the presence of the above catalyst; and (IV) a process for producing the above solid catalyst component (A-1), which comprises the step of contacting: (a-1) the above carrier, and (b) the above transition metal compound.

摘要翻译： 提供：（I）用于烯烃聚合的固体催化剂组分（A-1），其通过包括以下步骤的方法获得：（a-1）具有平均颗粒的含羧基的聚合物颗粒的载体 直径为1至300μm，和（b）元素周期表中第4族金属的过渡金属化合物;（II）通过包括以下步骤的方法获得的烯烃聚合催化剂： ：（A-1）上述固体催化剂组分，和（B）至少一种选自有机铝化合物和有机铝氧化合物的化合物;（III）烯烃聚合物的制备方法，包括以下步骤： 在上述催化剂存在下使烯烃聚合; 和（Ⅳ）上述固体催化剂组分（A-1）的制备方法，其包括使上述载体（a-1）与（b）上述过渡金属化合物接触的步骤。

公开(公告)号：US06828396B2

公开(公告)日：2004-12-07

申请号：US10347396

申请日：2003-01-21

申请人： Tatsuya Miyatake ,  Masaaki Nabika ,  Seiki Kiuchi

发明人： Tatsuya Miyatake ,  Masaaki Nabika ,  Seiki Kiuchi

IPC分类号： C08F442

CPC分类号： C08F210/16 ,  C08F4/6421 ,  C08F4/027 ,  C08F4/651 ,  C08F210/08 ,  C08F2500/10 ,  C08F2500/12

摘要： There are provided: (I) a solid catalyst component (A-1) for olefin polymerization, which is obtained by a process comprising the step of contacting: (a-1) a carrier of carboxyl group-carrying polymer particles having an average particle diameter of from 1 to 300 &mgr;m, and (b) a transition metal compound of the number 4 group of metals in the periodic table of elements; (II) a catalyst for olefin polymerization, which is obtained by a process comprising the step of contacting: (A-1) the above solid catalyst component, and (B) at least one compound selected from the group consisting of an organoaluminum compound and an organoaluminumoxy compound; (III) a process for producing an olefin polymer, which comprises the step of polymerizing an olefin in the presence of the above catalyst; and (IV) a process for producing the above solid catalyst component (A-1), which comprises the step of contacting: (a-1) the above carrier, and (b) the above transition metal compound.

摘要翻译： 提供：（I）用于烯烃聚合的固体催化剂组分（A-1），其通过包括以下步骤的方法获得：（a-1）具有平均颗粒的含羧基的聚合物颗粒的载体 直径为1至300μm，和（b）元素周期表中第4族金属的过渡金属化合物;（II）通过包括以下步骤的方法获得的烯烃聚合催化剂： ：（A-1）上述固体催化剂组分，和（B）至少一种选自有机铝化合物和有机铝氧化合物的化合物;（III）烯烃聚合物的制备方法，包括以下步骤： 在上述催化剂存在下使烯烃聚合; 和（Ⅳ）上述固体催化剂组分（A-1）的制备方法，其包括使上述载体（a-1）与（b）上述过渡金属化合物接触的步骤。