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公开(公告)号：US4888436A
公开(公告)日：1989-12-19
申请号：US174493
申请日：1988-03-28
申请人： Kouji Shiozawa , Haruko Takai , Kazutoshi Takatsuna , Nobukazu Okamoto , Yoshiharu Okumura , Chihiro Imai
发明人： Kouji Shiozawa , Haruko Takai , Kazutoshi Takatsuna , Nobukazu Okamoto , Yoshiharu Okumura , Chihiro Imai
CPC分类号： C07F7/1876
摘要： A process for preparing aminopropyl alkoxy silanes comprising reacting an allylamine having at least one active hydrogen atom attached to the amine nitrogen atom with a hydro-alkoxy silane having from 1 to 3 alkoxy groups attached to the silicon atom in the presence of a rhodium complex having inorganic ligands, at least one of said ligands being carbonyl. By this process the desired gamma-isomer can be prepared in a high selectivity and yield within a short reaction time. When the reaction is carried out in the presence of carbon monoxide and/or a cyclic olefinic compound, the selectivity and yield of the gamma-isomer can be further improved. The presence of carbon monooxide in the reaction system further serves to lengthen the catalyst life and to reduce the amount of the catalyst to be used.
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公开(公告)号：US4897501A
公开(公告)日：1990-01-30
申请号：US226086
申请日：1988-07-29
CPC分类号： C07F7/0801 , C07F7/1876
摘要： In a process for preparing aminopropyl alkoxy silanes comprising reacting an allylamine with a hydro-alkoxy silane in the presence of a rhodium catalyst, the improvement which comprises use of a rhodium phosphide or its oligomer as said rhodium catalyst. By this process the desired gamma-isomer can be prepared in a high selectivity and yield within a short reaction time.
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公开(公告)号：US4820674A
公开(公告)日：1989-04-11
申请号：US149092
申请日：1988-01-27
CPC分类号： B01J31/0204 , B01J31/0209 , B01J31/30 , C07F7/0801 , B01J2231/323 , B01J27/10
摘要： A process for preparing a hydrosilylation catalyst by dissolving chloroplatinic acid H.sub.2 PtCl.sub.6 in a cyclic ether or cyclic ester containing at least 3 carbon atoms, and maintaining the resulting solution at a temperature of at least 30.degree. C.
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公开(公告)号：US4927953A
公开(公告)日：1990-05-22
申请号：US404964
申请日：1989-09-11
CPC分类号： C07F7/1876
摘要： A process for preparing aminopropyl silanes comprises reacting an allylamine with a hydrosilane in the presence of a ruthenium compound having at least one tertiary phosphine ligand as a catalyst. By the proposed process the corresponding gamma-aminopropyl silane can be prepared in a high yield in a short period of reaction time.
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5.发明授权Processes for the preparation of .gamma.-methacryloxypropylsilane compounds 失效制备（游离）甲基丙烯酰基硅氧烷化合物的方法
公开(公告)号：US5145979A
公开(公告)日：1992-09-08
申请号：US748557
申请日：1991-08-22
申请人： Kazutoshi Takatsuna , Masaaki Ishii , Hideaki Ogawa , Akihito Shinohara , Kouji Shiozawa , Yoshiharu Okumura , Masako Ishikawa
发明人： Kazutoshi Takatsuna , Masaaki Ishii , Hideaki Ogawa , Akihito Shinohara , Kouji Shiozawa , Yoshiharu Okumura , Masako Ishikawa
CPC分类号： C07F7/089 , C07F7/0879 , C07F7/1876 , C08G77/045 , C08G77/38
摘要： There are provided processes for the preparation of .gamma.-methacryloxypropylsilane compounds which comprise carrying out the reaction of allyl methacrylate with a hydrosilane compound in the presence of a platinum catalyst, while allowing at least one of a hindered phenol compound and an aromatic amine compound to coexist in the reaction system with an alkylamine compound or an amide compound, or with a gas containing molecular oxygen, or with a phenol compound having an aminoalkylene group. By using these processes as provided, gelation of the reaction mixture in the reaction system and during the course of purification thereof by distillation can effectively be avoided, and the desired .gamma.-methacryloxypropylsilane compounds can be obtained in good yield.
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公开(公告)号：US4725420A
公开(公告)日：1988-02-16
申请号：US909193
申请日：1986-09-19
IPC分类号： C07F7/12 , B01J31/02 , B01J31/06 , B01J31/16 , C01B33/04 , C01B33/107 , C08F8/40 , B01J31/00
CPC分类号： C08F8/40 , B01J31/06 , B01J31/165 , C01B33/043 , C01B33/10773 , B01J31/0268 , B01J31/122
摘要： Silanes are produced by the disproportionation and/or redistribution reaction of chlorosilanes using a novel catalyst having a longer life and consisting of a quaternary phosphonium salt bonded to an organic macromolecule or polymer, represented by the following general formula: ##STR1## wherein .circle.P is an organic macromolecule or polymer, A is a bridging group between phosphorus and the organic macromolecule or polymer, R.sup.1, R.sup.2 and R.sup.3 are selected from the group consisting of hydrogen, C.sub.1 -C.sub.20 alkyl groups and aralkyl groups such as benzyl and phenethyl groups, which can contain oxygen or halogen atoms, and X is a halogen atom.
摘要翻译： 硅烷通过氯硅烷的歧化和/或再分布反应，使用具有更长寿命的新型催化剂并与由下列通式表示的与有机大分子或聚合物结合的季鏻盐组成：＆lt; IMAGE＆gt;其中＆cir＆P 有机高分子或聚合物，A是磷与有机高分子或聚合物之间的桥连基团，R 1，R 2和R 3选自氢，C 1 -C 20烷基和芳烷基如苄基和苯乙基，其中 可以含有氧或卤原子，X是卤原子。
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公开(公告)号：US4775651A
公开(公告)日：1988-10-04
申请号：US122237
申请日：1987-11-17
IPC分类号： C07F7/12 , B01J31/02 , B01J31/06 , B01J31/16 , C01B33/04 , C01B33/107 , C08F8/40 , B01J31/08
CPC分类号： C08F8/40 , B01J31/06 , B01J31/165 , C01B33/043 , C01B33/10773 , B01J31/0268 , B01J31/122
摘要： Silanes are produced by the disproportionation and/or redistribution reaction of chlorosilanes using a novel catalyst having a longer life and consisting of a quaternary phosphonium salt bonded to an organic macromolecule or polymer, represented by the following general formula: ##STR1## wherein .circle.P.circle. is an organic macromolecule or polymer, A is a bridging group between phosphorus and the organic macromolecule or polymer, R.sup.1, R.sup.2 and R.sup.3 are selected from the group consisting of hydrogen, C.sub.1 -C.sub.20 alkyl groups and aralkyl groups such as benzyl and phenethyl groups, which can contain oxygen or halogen atoms, and X is a halogen atom.
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公开(公告)号：US4966981A
公开(公告)日：1990-10-30
申请号：US490540
申请日：1990-03-05
申请人： Haruko Takai , Taiji Sakiyama , Kimishige Matsuzaki , Toshio Nozaki , Yoshiharu Okumura , Chihiro Imai
发明人： Haruko Takai , Taiji Sakiyama , Kimishige Matsuzaki , Toshio Nozaki , Yoshiharu Okumura , Chihiro Imai
CPC分类号： C07F7/1876
摘要： In a process for the preparation of epoxy group-containing alkoxy silanes by hydrosililation of a terminally unsaturated epoxy compound with a hydro-alkoxy silane using a platinum catalyst, the improvement comprising carrying out the hydrosililation in the presence of an alcohol. By this process formation of the internally sililated isomer can be suppressed and the desired terminally sililated poduct can be produced at an approximately 100% selectivity.
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公开(公告)号：US4921988A
公开(公告)日：1990-05-01
申请号：US280727
申请日：1988-12-06
申请人： Kazutoshi Takatsuna , Mamoru Tachikawa , Kouji Shinozawa , Masashi Nakajima , Akihito Shinohara , Yoshiharu Okumura
发明人： Kazutoshi Takatsuna , Mamoru Tachikawa , Kouji Shinozawa , Masashi Nakajima , Akihito Shinohara , Yoshiharu Okumura
CPC分类号： C07F7/1876
摘要： A process for preparing aminopropyl silanes in which an allylamine is reacted with a hydrosilane in the presence of a catalyst comprising (i) metallic rhodium or a rhodium compound and (ii) a basic compound. By the proposed process the corresponding gammaaminopropyl silane can be prepared in a high selectivity and yield within a short period of reaction time.
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公开(公告)号：US4225727A
公开(公告)日：1980-09-30
申请号：US82004
申请日：1979-10-05
IPC分类号： C07C67/055
CPC分类号： C07C67/055
摘要： The invention relates to a process for the production of an unsaturated glycol diester by the reaction of a conjugated diene compound, a carboxylic acid and molecular oxygen in the presence of a solid catalyst. For example, 1,4-diacetoxy-2-butene is prepared at high conversion and high selectivity by reacting butadiene, molecular oxygen and acetic acid in the presence of a solid catalyst containing palladium, tellurium and at least one element selected from the group consisting of tin, germanium and lead. The product is an intermediate for the preparation of 1,4-butanediol.
摘要翻译： 本发明涉及通过共轭二烯化合物，羧酸和分子氧在固体催化剂存在下反应制备不饱和二醇二酯的方法。 例如，在含有钯，碲和至少一种选自以下的元素的固体催化剂的存在下，通过丁二烯，分子氧和乙酸的反应，以高转化率和高选择性制备1,4-二乙酰氧基-2-丁烯。 锡，锗和铅。 该产品是制备1,4-丁二醇的中间体。
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