摘要:
In a process for the preparation of epoxy group-containing alkoxy silanes by hydrosililation of a terminally unsaturated epoxy compound with a hydro-alkoxy silane using a platinum catalyst, the improvement comprising carrying out the hydrosililation in the presence of an alcohol. By this process formation of the internally sililated isomer can be suppressed and the desired terminally sililated poduct can be produced at an approximately 100% selectivity.
摘要:
A process for preparing aminopropyl alkoxy silanes comprising reacting an allylamine having at least one active hydrogen atom attached to the amine nitrogen atom with a hydro-alkoxy silane having from 1 to 3 alkoxy groups attached to the silicon atom in the presence of a rhodium complex having inorganic ligands, at least one of said ligands being carbonyl. By this process the desired gamma-isomer can be prepared in a high selectivity and yield within a short reaction time. When the reaction is carried out in the presence of carbon monoxide and/or a cyclic olefinic compound, the selectivity and yield of the gamma-isomer can be further improved. The presence of carbon monooxide in the reaction system further serves to lengthen the catalyst life and to reduce the amount of the catalyst to be used.
摘要:
A process for preparing a hydrosilylation catalyst by dissolving chloroplatinic acid H.sub.2 PtCl.sub.6 in a cyclic ether or cyclic ester containing at least 3 carbon atoms, and maintaining the resulting solution at a temperature of at least 30.degree. C.
摘要:
A process for preparing aminopropyl silanes comprises reacting an allylamine with a hydrosilane in the presence of a ruthenium compound having at least one tertiary phosphine ligand as a catalyst. By the proposed process the corresponding gamma-aminopropyl silane can be prepared in a high yield in a short period of reaction time.
摘要:
A process for improving the catalyst life of zeolites employed in the conversion of alcohols (e.g. methanol) and/or their ether derivatives (e.g. dimethyl ether) wherein a suitable zeolite is modified in a 2-stage procedure by providing a controlled low amount of a coke precursor deposit on the external surface of the zeolite, and then heating this treated zeolite in an inert gas at specifically controlled temperatures for a minimum time is disclosed. A process of employing this modified zeolite to produce lower olefins is also disclosed.
摘要:
The invention relates to a method for the manufacture of ketones which comprises oxidizing an n-olefin in the presence of a catalyst containing palladium, copper, a halogen, and at least one of specific tertiary amines.
摘要:
Tertiary alcohols are produced by the hydration of an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer, and a polyhydric neo-type alcohol such as neopentyl glycol. The process is useful for separating isobutylene from a hydrocarbon mixture containing its isomers via preparation of the alcohol, separation from the unreacted hydrocarbons and dehydration of the tertiary butyl alcohol to isobutylene.
摘要:
An intruder detection device provides first and second detection areas which are covered by first and second PIR sensors. When intrusion of an object is detected in these areas, the detection signals are amplified by amplifiers, and then processed in a control unit such that orders for generating alarms are output from alarm output units to a monitoring station. While these processed detection signals are output to the alarm output units, the control unit sends other processed signals to LED display units, so that the LED display units turn on alarm lights. The intruder detection device also has a device for separating the object detection areas of the first and second PIR sensors such that their detection areas do not overlap.
摘要:
Disclosed are a process for producing a tubular nonwoven fabric and tubular nonwoven fabrics produced by the same. In the process, a web is formed on a first rotating cylinder by catching fibers carried to the surface of the first rotating cylinder by a fluid, the web is transferred to a second rotating cylinder, a tube of the transferred web is formed on and around the second rotating cylinder, and the tube is drawn in the axial direction of the second rotating cylinder to form a tubular nonwoven fabric. The tubular nonwoven fabric with a high unit weight can be produced without elongating or breaking the nonwoven fabric, and the diameter of the tubular nonwoven fabric can be freely changed.
摘要:
Disclosed are a process for producing a tubular nonwoven fabric and tubular nonwoven fabrics produced by the same. In the process, a web is formed on a first rotating cylinder by catching fibers carried to the surface of the first rotating cylinder by a fluid, the web is transferred to a second rotating cylinder, a tube of the transferred web is formed on and around the second rotating cylinder, and the tube is drawn in the axial direction of the second rotating cylinder to form a tubular nonwoven fabric. The tubular nonwoven fabric with a high unit weight can be produced without elongating or breaking the nonwoven fabric, and the diameter of the tubular nonwoven fabric can be freely changed.