摘要:
The object of the present invention is to provide a carbonaceous material for an anode of a nonaqueous electrolyte secondary battery which uses a plant-derived organic material as a raw material, has high purity so that alkali metals such as the potassium element and alkali earth metals such as the calcium element are sufficiently removed by de-mineral treatment, and has excellent discharge capacity and efficiency, a novel manufacturing method capable of efficiently mass-producing the carbonaceous material, and a lithium ion secondary battery using the carbonaceous material.The problem described above can be solved by a carbonaceous material for an anode of a nonaqueous electrolyte secondary battery obtained by carbonizing a plant-derived organic material, the atom ratio (H/C) of hydrogen atoms and carbon atoms according to elemental analysis being at most 0.1, the average particle size Dv50 being from 2 to 50 μm, the average interlayer spacing of the 002 planes determined by powder X-ray diffraction being from 0.365 nm to 0.400 nm, the potassium element content being at most 0.5 mass %, and the calcium element content being at most 0.02 mass %.
摘要:
The object of the present invention is to provide a carbonaceous material for an anode of a nonaqueous electrolyte secondary battery which uses a plant-derived organic material as a raw material, has high purity so that alkali metals such as the potassium element are sufficiently removed by de-mineral, and has excellent cycle characteristics, and to provide a lithium ion secondary battery using the carbonaceous material.The carbonaceous material for an anode of a nonaqueous electrolyte secondary battery is a carbonaceous material obtained by carbonizing a plant-derived organic material, the atom ratio of hydrogen atoms and carbon atoms (H/C) according to elemental analysis being at most 0.1, the average particle size Dv50 being from 2 to 50 μm, the average interlayer spacing of the 002 planes determined by X-ray diffraction being from 0.365 nm to 0.400 nm, the potassium element content being at most 0.5 mass %, the calcium element content being at most 0.02 mass %, and the true density determined by a pycnometer method using butanol being at least 1.44 g/cm3 and less than 1.54 g/cm3.
摘要翻译:本发明的目的是提供一种以植物来源的有机材料为原料的非水电解质二次电池的负极用碳质材料,其纯度高,使得钾元素等碱金属被充分地除去。 脱矿物质,并且具有优异的循环特性,并提供使用碳质材料的锂离子二次电池。 非水电解质二次电池的负极用碳质材料是通过碳化植物来源的有机材料得到的碳质材料,根据元素分析的氢原子和碳原子的原子比(H / C)为0.1以下, 平均粒径Dv50为2〜50μm,通过X射线衍射测定的002面平均层间距为0.365nm〜0.400nm,钾元素含量为0.5质量%以下,钙元素含量为 最大0.02质量%,并且通过使用丁醇的比重瓶法测定的真密度为至少1.44g / cm 3且小于1.54g / cm 3。
摘要:
Provided are a toxin separator and the like which are capable of selectively separating toxin present in a biological fluid by binding to protein, from the toxin and the protein. The toxin separator of the present invention also includes activated carbon of which a pore volume of pores having a pore diameter from 1.4 to 35 nm as measured by a nitrogen adsorption method is 0.06 cm3/g or greater.
摘要:
Provided is a carbonaceous material for a non-aqueous electrolyte secondary battery anode having high discharge capacity per unit volume and excellent storage characteristics.The carbonaceous material for a non-aqueous electrolyte secondary battery anode of the present invention has a true density (ρBt) determined by a pycnometer method using butanol of not less than 1.55 g/cm3 and less than 1.75 g/cm3 and a discharge capacity of an anode at 0.05 V to 1.5 V in terms of a lithium reference electrode standard of not less than 180 mAh/g. Furthermore, the slope 0.9/X (Vg/Ah) of a discharge curve calculated from a discharge capacity X (Ah/g) and a potential difference of 0.9 (V) corresponding to 0.2 V to 1.1 V in terms of a lithium reference electrode standard is not greater than 0.75 (Vg/Ah), and an absorbed moisture quantity after storage for 100 hours in a 25° C. 50% RH air atmosphere is not greater than 1.5 wt %.
摘要:
To provide a carbonaceous material for a non-aqueous electrolyte secondary battery anode that yields an anode for a non-aqueous electrolyte secondary battery having excellent input/output characteristics, and a non-aqueous electrolyte secondary battery having high discharge capacity per unit volume, and a non-aqueous electrolyte secondary battery and a vehicle comprising this non-aqueous electrolyte secondary battery anode.The carbonaceous material for a non-aqueous electrolyte secondary battery anode of the present invention has a number average particle size of from 0.1 to 2.0 μm, a value of a number average particle size divided by a volume average particle size of not greater than 0.3, an average interlayer spacing d002 of an (002) plane determined by X-ray diffraction of from 0.340 to 0.390 nm, and an atomic ratio (H/C) of hydrogen and carbon of not greater than 0.10.
摘要:
An object of the present invention is to provide a carbonaceous material for a negative electrode for producing a nonaqueous electrolyte secondary battery capable of rapid charge and discharge and having excellent rate characteristics (output characteristics) while maintaining a large discharge capacity.The problem described above can be solved by a carbonaceous material for a nonaqueous electrolyte secondary battery negative electrode of the present invention obtained by heat-treating a non-graphitizable carbon precursor which is pulverized and contains from 13 to 80 wt. % of a volatile component. With the present invention, it is possible to provide a carbonaceous material for a nonaqueous electrolyte secondary battery negative electrode, whereby a nonaqueous electrolyte secondary battery having a large charge-discharge capacity and having excellent rate characteristics can be produced.
摘要:
The object of the present invention is to provide a carbonaceous material which is obtainable from plant-derived char and has a decreased specific surface area. Further, the object of the present invention is to provide a non-aqueous electrolyte secondary battery having excellent dedoping capacity (discharge capacity), non-dedoping capacity (irreversible capacity), and charge-discharge efficiency.The object can be solved by a carbonaceous material for non-aqueous electrolyte secondary batteries characterized in that the carbonaceous material is obtained by heat-treating plant-derived char which is demineralized in gas-phase, and carbon precursor (i.e. non-graphitizable carbon precursor, graphitizable carbon, or mixture thereof) or volatile organic compound under a non-oxidizing gas atmosphere; and a specific surface area determined by a BET method is 10 m2/g or less. Further, the object can be solved by a carbonaceous material for non-aqueous electrolyte secondary batteries characterized in that the carbonaceous material is obtained by heating plant-derived char, and hydrocarbon compound having 1 to 20 carbon atoms; and a specific surface area determined by a BET method is 15 m2/g or less.