摘要:
The methods for treatment using an adsorbent having a high adsorbability, and capable of adsorbing a large amount of toxins during a retention period in an intestine, and of remarkably increasing an adsorption amount of compounds having a large molecular weight.
摘要:
An object of the present invention is to provide a non-aqueous electrolyte secondary battery that has a large charge/discharge capacity, has a small irreversible capacity, which is the difference between the doping capacity and the de-doping capacity, and is capable of effectively using an active material. The problem described above can be solved by a method for producing a carbonaceous material for a non-aqueous electrolyte secondary battery anode, the method including: (1) an alkali metal compound impregnating step of adding an elemental alkali metal or a compound containing an elemental alkali metal to a carbonaceous precursor to obtain an alkali-impregnated carbonaceous precursor; (2) a heat treatment step of: (a) obtaining a heat-treated product by performing main heat treatment on the alkali-impregnated carbonaceous precursor at 800° C. to 1500° C. in a non-oxidizing gas atmosphere, or (b) obtaining a heat-treated product by performing pre-heat treatment on the alkali-impregnated carbonaceous precursor at a temperature of not lower than 400° C. and lower than 800° C. in a non-oxidizing gas atmosphere and then performing main heat treatment at 800° C. to 1500° C. in a non-oxidizing gas atmosphere; and (3) coating the heat-treated product with pyrolytic carbon.
摘要:
An object of the present invention is to provide a production method for suppressing the deformation of a negative electrode in the production of a negative electrode for an all-solid-state battery using turbostratic carbon and a solid electrolyte.The problem described above can be solved by a production method for a negative electrode for an all-solid-state battery comprising the steps of: (1) coating a carbonaceous material having a true density of from 1.30 g/cm3 to 2.10 g/cm3 determined by a butanol method with a solid electrolyte; and (2) pressure-molding the solid electrolyte-coated carbonaceous material.
摘要:
The object of the present invention is to provide a manufacturing method of carbonaceous material for a negative electrode of lithium ion capacitors, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium and iron are sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of lithium ion capacitors.The object can be solved by a method for manufacturing a carbonaceous material having an average diameter of 3 to 30 μm, for a negative electrode of lithium ion capacitors comprising the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 μm at 500° C. to 1250° C. under an inert gas atmosphere containing a halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by the demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at less than 1100° C. under a non-oxidizing gas atmosphere.
摘要:
The object of the present invention is to provide a carbonaceous material for an anode of a nonaqueous electrolyte secondary battery which uses a plant-derived organic material as a raw material, has high purity so that alkali metals such as the potassium element are sufficiently removed by de-mineral, and has excellent cycle characteristics, and to provide a lithium ion secondary battery using the carbonaceous material.The carbonaceous material for an anode of a nonaqueous electrolyte secondary battery is a carbonaceous material obtained by carbonizing a plant-derived organic material, the atom ratio of hydrogen atoms and carbon atoms (H/C) according to elemental analysis being at most 0.1, the average particle size Dv50 being from 2 to 50 μm, the average interlayer spacing of the 002 planes determined by X-ray diffraction being from 0.365 nm to 0.400 nm, the potassium element content being at most 0.5 mass %, the calcium element content being at most 0.02 mass %, and the true density determined by a pycnometer method using butanol being at least 1.44 g/cm3 and less than 1.54 g/cm3.
摘要翻译:本发明的目的是提供一种以植物来源的有机材料为原料的非水电解质二次电池的负极用碳质材料,其纯度高,使得钾元素等碱金属被充分地除去。 脱矿物质,并且具有优异的循环特性,并提供使用碳质材料的锂离子二次电池。 非水电解质二次电池的负极用碳质材料是通过碳化植物来源的有机材料得到的碳质材料,根据元素分析的氢原子和碳原子的原子比(H / C)为0.1以下, 平均粒径Dv50为2〜50μm,通过X射线衍射测定的002面平均层间距为0.365nm〜0.400nm,钾元素含量为0.5质量%以下,钙元素含量为 最大0.02质量%,并且通过使用丁醇的比重瓶法测定的真密度为至少1.44g / cm 3且小于1.54g / cm 3。
摘要:
The methods for treatment using an adsorbent having a high adsorbability, and capable of adsorbing a large amount of toxins during a retention period in an intestine, and of remarkably increasing an adsorption amount of compounds having a large molecular weight.
摘要:
A non-aqueous electrolyte secondary battery having a charge/discharge capacity, and a small irreversible capacity, which is a difference between a doping capacity and a de-doping capacity, and utilizing an active material efficiently, is provided. Such a non-aqueous electrolyte secondary battery can be provided by using a carbonaceous material for a non-aqueous electrolyte secondary battery anode of the present invention, a production method of which includes: (1) impregnating an alkali metal to a carbonaceous material precursor by adding a compound including an elemental alkali metal to obtain an alkali-impregnated carbonaceous precursor; (2) subjecting the alkali-impregnated carbonaceous precursor to heat treatment by: (a) subjecting the alkali-impregnated carbonaceous precursor to main heat treatment in a non-oxidizing gas atmosphere at a temperature from 800° C. to 1500° C.; wherein a true density is from 1.35 to 1.60 g/cm3; a specific surface area obtained by BET method using nitrogen adsorption is not greater than 30 m2/g; an average particle size is not greater than 50 μm; and an atomic ratio of hydrogen and carbon obtained by elemental analysis, H/C, is not greater than 0.1.
摘要:
An object of the present invention is to provide a carbonaceous molded article for electrodes having high charge/discharge capacity, high initial charge/discharge efficiency, and excellent cycle life without a polymeric binder.The above object can be achieved by the carbonaceous molded article for electrodes of the present invention comprising a carbon fiber nonwoven fabric, the article having a thickness of not greater than 1 mm, an atomic ratio (H/C) of hydrogen atoms and carbon atoms according to elemental analysis of not greater than 0.1, a porosity determined from a bulk density and a butanol true density of the molded article of 25 to 80%, and a volatile content of not greater than 5.0 wt %.
摘要:
To provide a carbonaceous material for a non-aqueous electrolyte secondary battery anode that yields an anode for a non-aqueous electrolyte secondary battery having excellent input/output characteristics, and a non-aqueous electrolyte secondary battery having high discharge capacity per unit volume, and a non-aqueous electrolyte secondary battery and a vehicle comprising this non-aqueous electrolyte secondary battery anode.The carbonaceous material for a non-aqueous electrolyte secondary battery anode of the present invention has a number average particle size of from 0.1 to 2.0 μm, a value of a number average particle size divided by a volume average particle size of not greater than 0.3, an average interlayer spacing d002 of an (002) plane determined by X-ray diffraction of from 0.340 to 0.390 nm, and an atomic ratio (H/C) of hydrogen and carbon of not greater than 0.10.
摘要:
An object of the present invention is to provide a material for non-aqueous electrolyte secondary battery negative electrodes containing a graphitic material and a non-graphitizable carbonaceous material, the material having excellent resistance against deterioration due to moisture absorption and excellent charge/discharge cycle resistance; a non-aqueous electrolyte secondary battery negative electrode using the same; and a non-aqueous electrolyte secondary battery using these, that has low resistance and excellent cycle durability.The present invention comprises a carbonaceous material obtained by carbonizing a plant-derived organic material having a potassium content of 0.5% by mass or less, an average particle size Dv50 of 2 μm to 50 μm, an average interlayer spacing of (002) plane determined by powder X-ray diffraction of 0.365 nm to 0.400 nm, an atomic ratio (H/C) of hydrogen atoms to carbon atoms determined by elemental analysis of 0.1 or less, and a true density determined by a pycnometer method using butanol of 1.51 g/cm3 or greater but 1.65 g/cm3 or less; and a graphitic material having an average interlayer spacing determined by powder X-ray diffraction of 0.345 nm or less, and a true density determined by a pycnometer method using butanol of 1.9 g/cm3 or greater.
摘要翻译:本发明包括通过将钾含量为0.5质量%以下,平均粒径Dv50为2μm〜50μm的植物来源的有机材料碳化,将(002)面的平均层间距决定的碳质材料 通过0.365nm〜0.400nm的粉末X射线衍射,通过元素分析测定的氢原子与碳原子的原子比(H / C)为0.1以下,通过比重瓶法使用1.51g的丁醇测定的真密度 cm 3以上,但1.65g / cm 3以下; 和通过粉末X射线衍射测定的平均层间距为0.345nm以下的石墨材料,以及使用1.9g / cm 3以上的丁醇的比重瓶法测定的真密度。