公开(公告)号：US3833625A

公开(公告)日：1974-09-03

申请号：US19319971

申请日：1971-10-27

Applicant: LABOFINA SA

Inventor： BERTRAND J ,  VAERMAN J

IPC: C07C51/245 ,  C07C51/28

CPC classification number: C07C51/245

Abstract: A PROCESS FOR THE OXIDATION OF KETONES IN THE LIQUID PHASE WHICH COMPRISES SUBJECTING AN ASYMMETRICAL KETONE R-CO-R'', WHERE R IS A PARAFFINIC OR OLEFINC HYDROCARBON RADICAL CONTAINING AT LEAST 2 CARBON ATOMS, SUBSTITUTED OR NOT, AND R'' IS A SATURATED ALIPHATIC RADICAL CONTAINING NOT MORE THAN 2 CARBON ATOMS, TO OXIDATION IN THE PRESENCE OF MOLECULAR OXYGEN AT A PARTIAL PRESSURE OF 0.1 TO 50 ATMOSPHERES AND IN THE PRESENCE OF A MANGANESE SALT, THE MOLAR RATIO OF MANGANIC SALT TO KETONE BEING HIGHER THAN 0.1, AT A TEMPERATURE FROM 20 TO 130*C., WITH THE SELECTIVE FORMATION OF THE ACID R-COOH WHEREIN R IS AS DEFINED ABOVE.

公开(公告)号：US3755391A

公开(公告)日：1973-08-28

申请号：US3755391D

申请日：1971-10-27

Applicant: LABOFINA SA

Inventor： BERTRAND J ,  VAERMAN J

IPC: C07C51/245 ,  C07C51/41 ,  C07F13/00

CPC classification number: C07F13/005 ,  C07C51/245 ,  C07C51/412 ,  C07C53/10 ,  C07C53/122

Abstract: A PROCESS FOR THE PRODUCTION OF THE MANGANIC SALT OF AN ALIPHATIC CARBOXYLIC ACID, WHICH COMPRISES TREATING IN LIQUID PHASE BY AN OXYGEN CONTAINING GAS, A MANGANOUS COMPOUND FROM THE GROUP CONSISTING OF MANGANOUS SALT OF SAID CARBOXYLIC ACID, AMANGANOUS SALT OF A WEAKER THAN SAID CARBOXYLIC ACID, MANGANOUS OXIDE AND MANGANOUS HYDROXIDE, IN THE PRESENCE OF A KETONE HAVING THE FORMULA R-CO-R1, WHEREIN R IS AN ALIPHATIC OR AROMATIC RADICAL AND R1 IS AN ALIPHATIC RADICAL OR FORMS WITH R A CYCLOALKANE RADICAL, AND IN THE PRESENCE OF SAID CARBOXYLIC ACID OF WHICH SAID MANGANIC SALT IS A DERIVATIVE, AT A TEMPERATURE FROM 50 TO 130*C.

公开(公告)号：US3758557A

公开(公告)日：1973-09-11

申请号：US3758557D

申请日：1969-07-24

Applicant: LABOFINA SA

Inventor： DE RADZITZKY DOSTROWICK P ,  HANOTIER J ,  VAERMAN J

IPC: C07C29/48 ,  C07C29/50 ,  C07C29/52 ,  C07C45/28 ,  C07C45/30 ,  C07C45/33 ,  C07C27/16 ,  C07C45/02 ,  C07C67/00

CPC classification number: C07C45/33 ,  C07C29/48 ,  C07C29/50 ,  C07C29/52 ,  C07C45/28 ,  C07C45/30 ,  C07C49/04 ,  C07C31/125

Abstract: Straight-chain paraffins are non-destructively and selectively oxidized to introduce oxy and oxo functions predominantly at the 2 position by an oxidizing system comprising a compound of group II - VI metals in higher valent form and an acidic activator of dissociation constant gerater than 5.10 3 or boron trifluoride, with or without molecular oxygen and with or without a solvent.

Abstract translation: 直链烷烃是非破坏性和选择性氧化的，以通过包含高价形式的II-VI族金属化合物和解离常数gerater酸性活化剂的氧化体系主要在2位引入氧和氧官能团， - > 3或三氟化硼，有或没有分子氧，有或没有溶剂。