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公开(公告)号:US20170088482A1
公开(公告)日:2017-03-30
申请号:US15117044
申请日:2015-02-06
发明人: Torben Höfel , Harald Schmaderer , Ernst Haidegger , Clara Delhomme-Neudecker , Helmut Fritz , Marianne Ponceau
摘要: A method (100) for producing olefins is proposed, wherein a first gas mixture (b) is produced by means of a steam cracking process (1) and a second gas mixture (s) is produced by means of an oxygenate-to-olefin process (2), the first gas mixture (b) and the second gas mixture (s) each containing at least hydrocarbons with one to four carbon atoms. It is proposed that from the first gas mixture (b) a first fraction (h) is formed which contains at least the great majority of the hydrocarbons with four carbon atoms previously contained in the first gas mixture (b), from the second gas mixture (s) a second fraction (y) is formed which contains at least the great majority of the hydrocarbons with four carbon atoms previously contained in the second gas mixture (s), and that the hydrocarbons contained in the second fraction (y) and previously in the second gas mixture (s) are predominantly subjected in the steam cracking process (1) to cracking conditions under which any n-butane present is reacted by less than 92%. The invention further relates to an apparatus for this purpose.
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公开(公告)号:US09090543B2
公开(公告)日:2015-07-28
申请号:US14375891
申请日:2013-01-15
发明人: Nicole Schoedel , Ernst Haidegger , Holger Schmigalle , Axel Behrens , Volker Goeke , Christian Thaller , Harald Schmaderer
CPC分类号: C07C41/01 , C01B3/34 , C01B2203/0238 , C01B2203/062 , C07C1/20 , C07C1/22 , C07C2523/72 , Y02P30/42 , C07C43/043 , C07C11/04 , C07C11/06
摘要: The invention relates to processes for production of dimethyl ether from methane or natural gas comprising: a dry-reforming step, wherein methane and carbon dioxide are converted into carbon monoxide and hydrogen, and a DME synthesis step, wherein the carbon monoxide and hydrogen formed in the dry-reforming step are converted into dimethyl ether, wherein the dry-reforming step and the synthesis step are carried out at identical pressures or at pressures, which do not differ more than 3 bar, preferably not more than 1 bar.
摘要翻译: 本发明涉及从甲烷或天然气生产二甲醚的方法,包括:干重整步骤,其中甲烷和二氧化碳转化成一氧化碳和氢气,以及DME合成步骤,其中一氧化碳和氢气形成在 干重整步骤转化为二甲醚,其中干重整步骤和合成步骤在相同压力或压力下进行,其压差不超过3巴,优选不超过1巴。
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公开(公告)号:US20160347688A1
公开(公告)日:2016-12-01
申请号:US15116997
申请日:2015-02-06
发明人: Torben Höfel , Clara Delhomme-Neudecker , Ernst Haidegger , Harald Schmaderer , Heinz Zimmermann , Nicole Schödel , Gunther Kracker-Semler
CPC分类号: C07C7/005 , B01D3/143 , C07C1/20 , C07C7/04 , C07C7/163 , C10G3/00 , C10G9/36 , C10G45/32 , C10G69/02 , C10G69/06 , C10G2400/20 , C10G2400/22 , Y02P30/20 , C07C11/02
摘要: A method (100) for obtaining olefins is proposed, wherein a first gas mixture (b), which is produced by a steam cracking process (1), is at least partially used to form a first separation feedstock (f) which contains hydrocarbons with one to five carbon atoms, and from which at least a first separation product (g) and a second separation product (h, o) are produced, the first separation product (g) containing at least the greater proportion of the hydrocarbons with one carbon atom and of the hydrocarbons with two carbon atoms contained in the first separation feedstock (f), and the second separation product (h, o) containing at least the greater proportion of the hydrocarbons with four carbon atoms and of the hydrocarbons with five carbon atoms contained in the first separation feedstock (f), and wherein a second gas mixture (r) which is produced by an oxygenate-to-olefin process (2) is used at least partially to form a second separation feedstock (t) which contains hydrocarbons with one to five carbon atoms, and from which at least a third separation product (e, y) and a fourth separation product (l, z) are produced, the third separation product (e, y) containing at least the greater proportion of the hydrocarbons with one carbon atom and of the hydrocarbons with two carbon atoms contained in the second separation feedstock (t), and the fourth separation product (l, z) containing at least the greater proportion of the hydrocarbons with four or five carbon atoms contained in the second separation feedstock (t). The third separation product (e, y) is also at least partially used to form the first separation feedstock (f), and a third separation feedstock (h, l) (o, z) is formed from at least part of the fourth separation product (l, z) and of the second separation product (h, o) and is subjected to a separation (14).
摘要翻译: 提出了一种用于获得烯烃的方法(100),其中通过蒸汽裂解方法(1)产生的第一气体混合物(b)至少部分地用于形成含有烃的第一分离原料(f) 1至5个碳原子,并且从其中产生至少第一分离产物(g)和第二分离产物(h,o),第一分离产物(g)至少含有较大比例的烃与一个碳 原子和含有第一分离原料(f)中的两个碳原子的烃,以及含有至少较大比例的具有四个碳原子的烃和具有五个碳原子的烃的第二分离产物(h,o) 包含在第一分离原料(f)中,并且其中使用由含氧化合物至烯烃方法(2)生产的第二气体混合物(r)至少部分地用于形成含有烃的第二分离原料(t) 与o 从而从其中产生至少第三分离产物(e,y)和第四分离产物(1,z),所述第三分离产物(e,y)至少含有较大比例的 具有一个碳原子的烃和在第二分离原料(t)中包含两个碳原子的烃,以及含有至少较大比例的含有四个或五个碳原子的烃的第四分离产物(1,z) 第二分离原料(t)。 第三分离产物(e,y)还至少部分地用于形成第一分离原料(f),并且第三分离原料(h,l)(o,z)由第四分离 产物(l,z)和第二分离产物(h,o)并进行分离(14)。
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公开(公告)号:US20150045456A1
公开(公告)日:2015-02-12
申请号:US14375891
申请日:2013-01-15
发明人: Nicole Schoedel , Ernst Haidegger , Holger Schmigalle , Axel Behens , Volker Goeke , Christian Thaller , Harald Schmaderer
CPC分类号: C07C41/01 , C01B3/34 , C01B2203/0238 , C01B2203/062 , C07C1/20 , C07C1/22 , C07C2523/72 , Y02P30/42 , C07C43/043 , C07C11/04 , C07C11/06
摘要: The invention relates to processes for production of dimethyl ether from methane or natural gas comprising: a dry-reforming step, wherein methane and carbon dioxide are converted into carbon monoxide and hydrogen, and a DME synthesis step, wherein the carbon monoxide and hydrogen formed in the dry-reforming step are converted into dimethyl ether, wherein the dry-reforming step and the synthesis step are carried out at identical pressures or at pressures, which do not differ more than 3 bar, preferably not more than 1 bar.
摘要翻译: 本发明涉及从甲烷或天然气生产二甲醚的方法,包括:干重整步骤,其中甲烷和二氧化碳转化成一氧化碳和氢气,以及DME合成步骤,其中一氧化碳和氢气形成在 干重整步骤转化为二甲醚,其中干重整步骤和合成步骤在相同压力或压力下进行,其压差不超过3巴,优选不超过1巴。
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公开(公告)号:US20150018582A1
公开(公告)日:2015-01-15
申请号:US14375479
申请日:2013-01-15
发明人: Nicole Schodel , Ernst Haidegger , Holger Schmigalle , Christian Thaller , Harald Schmaderer , Akos Tota
IPC分类号: C07C41/01
摘要: The invention concerns processes for preparing dimethyl ether from synthesis gas, comprising a synthesis step, wherein synthesis gas comprising hydrogen and carbon monoxide is converted into dimethyl ether and carbon dioxide, and a separation step, wherein unconverted synthesis gas is separated from carbon dioxide, wherein unconverted synthesis gas is separated from carbon dioxide by a membrane.
摘要翻译: 本发明涉及从合成气制备二甲醚的方法,包括合成步骤,其中包含氢气和一氧化碳的合成气转化为二甲醚和二氧化碳,以及分离步骤,其中未转化的合成气与二氧化碳分离,其中 未转化的合成气通过膜与二氧化碳分离。
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公开(公告)号:US20150018592A1
公开(公告)日:2015-01-15
申请号:US14375256
申请日:2013-01-15
发明人: Nicole Schodel , Ernst Haidegger , Holger Schmigalle , Volker Goke , Christian Thaller , Harald Schmaderer
CPC分类号: C07C41/01 , C01B3/34 , C01B2203/0238 , C01B2203/062 , C07C1/20 , C07C1/22 , C07C2523/72 , Y02P30/42 , C07C43/043 , C07C11/04 , C07C11/06
摘要: The invention relates to a process for production of DME (17) comprising the steps of: generating a syngas (12) containing CO and H2 in a device (11) for syngas generation, passing the syngas (12) into a DME reactor (13) for direct synthesis of DME by catalysed conversion of the syngas (12) by means of a catalyst to form a product stream (14) containing DME, CO2, H2O, CH3OH and unconverted syngas (12). The invention provides that the direct synthesis is carried out at or close to the chemical equilibrium.
摘要翻译: 本发明涉及一种生产DME(17)的方法,包括以下步骤:在用于产生合成气的装置(11)中产生含有CO和H 2的合成气(12),将合成气(12)通入DME反应器 ),用于通过催化剂催化转化合成气(12)直接合成DME以形成含有DME,CO 2,H 2 O,CH 3 OH和未转化的合成气(12)的产物流(14)。 本发明提供直接合成在或接近化学平衡下进行。
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