公开(公告)号：US11731926B2

公开(公告)日：2023-08-22

申请号：US17183204

申请日：2021-02-23

申请人： LanzaTech, Inc.

发明人： Ralph Gillespie ,  Michelle Kocal ,  Wyatt Eric Allen ,  Richard R Rosin ,  Donovan Tran

IPC分类号： C07C29/84 ,  C07C29/88 ,  B01D3/00 ,  B01D3/14 ,  C07C29/76 ,  B01D15/36 ,  C12P7/06

CPC分类号： C07C29/84 ,  B01D3/002 ,  B01D3/143 ,  B01D15/362 ,  C07C29/76 ,  C07C29/88 ,  C12P7/06

摘要： The disclosure is directed to an apparatus and method for recovering ethanol from a fermentation broth. The fermentation broth comprises microbial biomass, ethanol, methanol, ethyl acetate, at least one thiol, and at least one compound having 3 or more carbon atoms. The method comprises separating at least microbial biomass from the fermentation broth to generate a process stream; removing, in any order, from the process stream: ethyl acetate by reacting ethyl acetate with a base compound followed by distillation; at least one thiol by adsorption or reaction to disulfide; methanol by distillation; compounds having 3 or more carbon atoms by distillation; and recovering ethanol by distillation; wherein the distillations may be conducted in a single column or two or more columns.

公开(公告)号：US20210284592A1

公开(公告)日：2021-09-16

申请号：US17183204

申请日：2021-02-23

申请人： LanzaTech, Inc.

发明人： Ralph Gillespie ,  Michelle Kocal ,  Wyatt Eric Allen ,  Richard R Rosin ,  Donovan Tran

IPC分类号： C07C29/84 ,  C07C29/76 ,  C07C29/88 ,  C12P7/06 ,  B01D3/00 ,  B01D3/14 ,  B01D15/36

摘要： The disclosure is directed to an apparatus and method for recovering ethanol from a fermentation broth. The fermentation broth comprises microbial biomass, ethanol, methanol, ethyl acetate, at least one thiol, and at least one compound having 3 or more carbon atoms. The method comprises separating at least microbial biomass from the fermentation broth to generate a process stream; removing, in any order, from the process stream: ethyl acetate by reacting ethyl acetate with a base compound followed by distillation; at least one thiol by adsorption or reaction to disulfide; methanol by distillation; compounds having 3 or more carbon atoms by distillation; and recovering ethanol by distillation; wherein the distillations may be conducted in a single column or two or more columns.

公开(公告)号：US20230357112A1

公开(公告)日：2023-11-09

申请号：US18352623

申请日：2023-07-14

申请人： LanzaTech, Inc.

发明人： Ralph Gillespie ,  Michelle Kocal ,  Wyatt Eric Allen ,  Richard R. Rosin ,  Donovan Tran

IPC分类号： C07C29/84 ,  C07C29/76 ,  C07C29/88 ,  B01D15/36 ,  B01D3/00 ,  B01D3/14 ,  C12P7/06

CPC分类号： C07C29/84 ,  C07C29/76 ,  C07C29/88 ,  B01D15/362 ,  B01D3/002 ,  B01D3/143 ,  C12P7/06

摘要： The disclosure is directed to an apparatus and method for recovering ethanol from a fermentation broth. The fermentation broth comprises microbial biomass, ethanol, methanol, ethyl acetate, at least one thiol, and at least one compound having 3 or more carbon atoms. The method comprises separating at least microbial biomass from the fermentation broth to generate a process stream; removing, in any order, from the process stream: ethyl acetate by reacting ethyl acetate with a base compound followed by distillation; at least one thiol by adsorption or reaction to disulfide; methanol by distillation; compounds having 3 or more carbon atoms by distillation; and recovering ethanol by distillation; wherein the distillations may be conducted in a single column or two or more columns.

公开(公告)号：US20200239798A1

公开(公告)日：2020-07-30

申请号：US16774163

申请日：2020-01-28

申请人： LanzaTech, Inc.

发明人： Ralph Gillespie ,  Michelle Kocal

IPC分类号： C10L3/12 ,  C12P7/06 ,  C07C51/12 ,  B01J31/02 ,  B01J23/656 ,  C07C1/24 ,  C07C5/03

摘要： The disclosure provides methods for the production of liquefied petroleum gas from sustainable feedstocks, including methods comprising conversion of alcohols produced by gas fermentation for the production of propane and/or butane.

公开(公告)号：US20230340349A1

公开(公告)日：2023-10-26

申请号：US18311440

申请日：2023-05-03

申请人： LanzaTech, Inc.

发明人： Ralph Gillespie ,  Michelle Kocal

IPC分类号： C10L3/12 ,  B01J31/02 ,  B01J23/656 ,  C12P7/06 ,  C07C1/24 ,  C07C51/12 ,  C07C5/03

CPC分类号： C10L3/12 ,  B01J23/6567 ,  B01J31/0205 ,  C07C1/24 ,  C07C5/03 ,  C07C51/12 ,  C12P7/065 ,  C07C9/10

摘要： The disclosure provides methods for the production of liquefied petroleum gas from sustainable feedstocks, including methods comprising conversion of alcohols produced by gas fermentation for the production of propane and/or butane.

公开(公告)号：US11680216B2

公开(公告)日：2023-06-20

申请号：US16774163

申请日：2020-01-28

申请人： LanzaTech, Inc.

发明人： Ralph Gillespie ,  Michelle Kocal

IPC分类号： C10L3/12 ,  C12P7/06 ,  C07C1/24 ,  C07C5/03 ,  C07C51/12 ,  B01J31/02 ,  B01J23/656 ,  C07C9/10 ,  C07C53/122 ,  C07C9/08

CPC分类号： C10L3/12 ,  B01J23/6567 ,  B01J31/0205 ,  C07C1/24 ,  C07C5/03 ,  C07C51/12 ,  C12P7/065 ,  B01J2531/822 ,  C07C9/08 ,  C07C9/10 ,  C07C53/122

摘要： The disclosure provides methods for the production of liquefied petroleum gas from sustainable feedstocks, including methods comprising conversion of alcohols produced by gas fermentation for the production of propane and/or butane.