公开(公告)号：US4965325A

公开(公告)日：1990-10-23

申请号：US505343

申请日：1990-04-05

申请人： Theodor A. Liss ,  Leonard H. Beck

发明人： Theodor A. Liss ,  Leonard H. Beck

IPC分类号： D06M15/41

CPC分类号： D06M15/412

摘要： Synthetic polyamide textile substrate having deposited thereon a modified polymeric sulfonated phenol-formaldehyde condensation product comprising one (a) in which 10 to 25% of the polymer units contain SO.sub.3 (-) radicals and about 90 to 75% of the polymer units contain sulfone radicals and (b) in which a portion of the free hydroxyl groups thereof has been acylated or etherified, the number of said hydroxyl groups which has been acylated or etherified being sufficient to inhibit yellowing of said condensation product but insufficient to reduce materially the capacity of said condensation product to impart stain resistance to said synthetic polyamide textile substrate.

摘要翻译： 在其上沉积有改性聚合物磺化苯酚 - 甲醛缩合产物的合成聚酰胺纺织品基质，其包含一种（a）其中10-25％的聚合物单元含有SO 3（ - ）基和约90-75％的聚合物单元含有砜基 和（b）其中游离羟基的一部分已被酰化或醚化，已经酰化或醚化的所述羟基的数目足以抑制所述缩合产物的泛黄，但不足以大大降低所述 缩合产物以赋予所述合成聚酰胺织物基材耐污性。

公开(公告)号：US5202506A

公开(公告)日：1993-04-13

申请号：US864819

申请日：1992-04-02

申请人： Jack R. Kirchner ,  Leonard H. Beck ,  James E. Dowd

发明人： Jack R. Kirchner ,  Leonard H. Beck ,  James E. Dowd

IPC分类号： C07C29/09 ,  C07C29/124 ,  C07C31/38 ,  C07C31/40

CPC分类号： C07C29/124 ,  C07C31/40

摘要： A process for the formation of perfluoroalkylethyl alcohols from perfluoroalkylethyl iodides is disclosed. The process involves treatment of the perfluoroalkylethyl iodide with oleum.

摘要翻译： 公开了一种从全氟烷基乙基碘化物形成全氟烷基乙醇的方法。 该方法包括用发烟硫酸处理全氟烷基乙基碘。

公开(公告)号：US5097090A

公开(公告)日：1992-03-17

申请号：US530351

申请日：1990-05-30

申请人： Leonard H. Beck

发明人： Leonard H. Beck

IPC分类号： C07C29/06 ,  C07C29/12 ,  C07C31/40

CPC分类号： C07C31/40

摘要： In a process for the manufacture of 2-perfluoroalkylethyl alochols by sulfating 2-perfluoroalkylethyl iodides with oleum followed by hydrolysis of the resulting sulfated reaction mass with water, the improvement comprising carrying out both reactions in two similar continuous reactor systems, combined in series, in each of which one of the reactant streams is contacted with the reaction mass in a zone of intense agitation which forms part of a low volume recycle loop operated under pressure and at high rates of reecycle. Preferably the zone of intense agitation in the sulfation loop has an energy input of at least 0.05 horsepower per gallon per minute with a loop recycle time of 5 seconds or less, and the hydrolysis loop has an energy input of at least 0.4 horsepower per gallon per minute with a loop recycle time of 2 seconds or less. Most preferably, the energy input to the liquids in both loops is provided by centrifugal pumps.

摘要翻译： 在通过用发烟硫酸硫化2-全氟烷基乙基碘化物然后用水水解所得到的硫酸化反应物料的方法中，所述改进包括在两个类似的连续反应器体系中进行两个反应，其串联， 其中一个反应物流在强烈搅拌区域中与反应物质接触，其形成在压力下和高回收速率下操作的低体积循环回路的一部分。 优选地，硫酸化回路中的强烈搅拌区域具有至少0.05马力/加仑/分钟的能量输入，循环循环时间为5秒或更短，并且水解回路具有每加仑至少0.4马力的能量输入 分钟，循环回收时间为2秒或更短。 最优选地，通过离心泵提供输入到两个回路中的液体的能量。

公开(公告)号：US4963409A

公开(公告)日：1990-10-16

申请号：US124866

申请日：1987-11-23

申请人： Theodor A. Liss ,  Leonard H. Beck

发明人： Theodor A. Liss ,  Leonard H. Beck

IPC分类号： D06M15/41

CPC分类号： D06M15/412 ,  Y10S8/21 ,  Y10T428/23986 ,  Y10T428/2938 ,  Y10T428/2969 ,  Y10T442/2279 ,  Y10T442/2893

摘要： Synthetic polyamide textile substrate having deposited thereon a modified polymeric sulfonated phenol-formaldehyde condensation product comprising one (a) in which 10 to 25% of the polymer units contain SO.sub.3 (-) radicals and about 90 to 75% of the polymer units contain sulfone radicals and (b) in which a portion of the free hydroxyl groups thereof has been acylated or etherified, the number of said hydroxyl groups which has been acylated or etherified being sufficient to inhibit yellowing of said condensation product but insufficient to reduce materially the capacity of said condensation product to impart stain resistance to said synthetic polyamide textile substrate.

摘要翻译： 在其上沉积有改性聚合物磺化苯酚 - 甲醛缩合产物的合成聚酰胺纺织品基质，其包含一种（a）其中10-25％的聚合物单元含有SO 3（ - ）基和约90-75％的聚合物单元含有砜基 和（b）其中游离羟基的一部分已被酰化或醚化，已经酰化或醚化的所述羟基的数目足以抑制所述缩合产物的泛黄，但不足以大大降低所述 缩合产物以赋予所述合成聚酰胺织物基材耐污性。

公开(公告)号：US4618731A

公开(公告)日：1986-10-21

申请号：US800007

申请日：1985-11-20

申请人： Leonard H. Beck

发明人： Leonard H. Beck

IPC分类号： C07C29/12 ,  C07C17/23 ,  C07C17/25 ,  C07C29/88 ,  C07C31/38 ,  C07C45/29 ,  C07C29/74

CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C29/88 ,  C07C45/29

摘要： R.sub.f CH.sub.2 CH.sub.2 I and R.sub.f I present in sufficient quantities so as to cause discoloration of R.sub.f CH.sub.2 CH.sub.2 OH or products made from it are reacted with an excess of an aqueous alkali metal hydroxide and a C.sub.1 -C.sub.3 alcohol in a closed vessel at a temperature above 80.degree. C. until neither of said iodides can be detected in said final product. NaOH and isopropanol at 100.degree.-115.degree. C. are preferred.

摘要翻译： RfCH 2 CH 2 I和RfI的存在量足以使RfCH 2 CH 2 OH变色或由其制成的产物在过度的80℃以上的封闭容器中与过量的碱金属氢氧化物和C1-C3醇反应，直到 的所述碘化物可以在所述最终产物中检测。 NaOH和异丙醇在100-115℃是优选的。