公开(公告)号：US5989308A

公开(公告)日：1999-11-23

申请号：US817263

申请日：1997-04-17

申请人： Leopold-Werner Kepplinger ,  Konstantin Milionis ,  Dieter Siuka ,  Horst Wiesinger

发明人： Leopold-Werner Kepplinger ,  Konstantin Milionis ,  Dieter Siuka ,  Horst Wiesinger

IPC分类号： C21B11/00 ,  C21B13/00 ,  C21B13/14 ,  C22B5/12

CPC分类号： C21B13/0033 ,  C21B13/002 ,  C21B13/14 ,  Y02P10/122 ,  Y02P10/128 ,  Y02P10/136 ,  Y02P10/265 ,  Y02P10/283

摘要： A plant for the production of pig iron and/or sponge iron includes a direct-reduction shaft furnace for lumpy iron ore, a melter gasifier, a feed duct for a reducing gas connecting the melter gasifier with the shaft furnace, a conveying duct for the reduction product formed in the shaft furnace connecting the shaft furnace with the melter gasifier, a top-gas discharge duct departing from the shaft furnace, feed ducts for oxygen-containing gases and carbon carriers running into the melter gasifier and a tap for pig iron and slag provided at the melting vessel. In order to be able to process not only lumpy ore, but also fine ore within a wide variation range with regard to quantity in a manner optimized in terms of energy and product, the plant includes at least one fluidized bed reactor for receiving fine ore, a reducing-gas feed duct leading to the fluidized bed reactor, an offgas discharge duct departing from the fluidized bed reactor and a discharge means provided for the reduction product formed in the fluidized bed reactor, wherein the top-gas discharge duct of the shaft furnace and the offgas discharge duct of the fluidized bed reactor run into a purifier and subsequently into a heat exchanger from which the reducing-gas feed duct of the fluidized bed reactor departs.

摘要翻译： PCT No.PCT / AT95 / 00199 Sec。 371日期1997年04月17日 102（e）日期1997年4月17日PCT提交1995年10月12日PCT公布。 出版物WO96 / 12045 日期1996年04月25日生产生铁和/或海绵铁的工厂包括用于块状铁矿石的直接还原竖炉，熔炉气化器，用于将熔化炉气化器与竖炉连接的还原气体的进料管， 在竖炉中形成的用于还原产品的输送管道，其将竖炉与熔化器气化器连接起来，从立式炉排出的顶部气体排出管道，用于含氧气体的进料管和进入熔化炉气化器的碳载体， 在熔化容器处提供生铁和矿渣的水龙头。 为了能够在能量和产品方面优化的方式处理不仅块状矿石，而且能够处理在数量方面的广泛变化范围内的细矿石，该装置包括至少一个用于接收细矿石的流化床反应器， 通向流化床反应器的还原气进料管道，离开流化床反应器的废气排放管道和为流化床反应器中形成的还原产物提供的排放装置，其中竖炉的顶部排气管道 并且流化床反应器的废气排放管道进入净化器，随后进入热交换器，流化床反应器的还原气体进料管从该换热器排出。

公开(公告)号：US05997608A

公开(公告)日：1999-12-07

申请号：US817262

申请日：1997-07-22

申请人： Jorg Diehl ,  Gerald Rosenfellner ,  Leopold Werner Kepplinger ,  Konstantin Milionis ,  Dieter Siuka ,  Horst Wiesinger

发明人： Jorg Diehl ,  Gerald Rosenfellner ,  Leopold Werner Kepplinger ,  Konstantin Milionis ,  Dieter Siuka ,  Horst Wiesinger

IPC分类号： C21B11/00 ,  C21B13/00 ,  C21B13/14

CPC分类号： C21B13/0033 ,  C21B13/002 ,  C21B13/14 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/128 ,  Y02P10/136 ,  Y02P10/265 ,  Y02P10/283

摘要： In a process for the production of molten pig iron or molten steel pre-products and sponge iron from charging materials consisting of iron ore and, if desired, fluxes, direct reduction of the charging materials to sponge iron is carried out in a fixed-bed reduction zone, the sponge iron is melted in a meltdown gasifying zone under supply of carbon carriers as well as an oxygen-containing gas and a CO- and H.sub.2 -containing reducing gas is produced which is fed to the reduction zone, is reacted there and is drawn off as an export gas, and the drawn-off export gas is subjected to CO.sub.2 elimination and for the production of sponge iron is along with part of the reducing gas formed in the meltdown gasifying zone as an at least largely CO.sub.2 free reducing gas conveyed to a further reduction zone for the direct reduction of iron ore. In order to save investment costs incurred for the plant and to increase productivity, part of the reducing gas produced in the meltdown gasifying zone is branched off and fed to the further reduction zone while avoiding CO.sub.2 elimination.

摘要翻译： PCT No.PCT / AT95 / 00198 Sec。 371日期1997年7月22日 102（e）日期1997年7月22日PCT提交1995年10月12日PCT公布。 出版物WO96 / 12044 日期1996年04月25日在由铁矿石和如果需要的话，由铁矿石填充材料生产熔融生铁或钢水预制品和海绵铁的过程中，进行充电材料直接还原成海绵铁 在固定床还原区中，海绵铁在碳载体和含氧气体的供应下在熔化气化区中熔化，并且产生含CO和H 2的还原气体，其被供给到还原区 在那里反应，作为出口气体排出，排出的出口气体进行二氧化碳消除，海绵铁的生产与熔化气化区中形成的一部分还原气体一起至少 大部分不含CO 2的还原气体被输送到另一个还原区域以直接还原铁矿石。 为节省厂房投资成本，提高生产效率，在熔化气化区生产的部分还原气体被分支，并进入进一步还原区，同时避免二氧化碳排放。

公开(公告)号：US06183534B2

公开(公告)日：2001-02-06

申请号：US09148780

申请日：1998-09-04

申请人： Leopold Werner Kepplinger ,  Konstantin Milionis ,  Dieter Siuka ,  Horst Wiesinger

发明人： Leopold Werner Kepplinger ,  Konstantin Milionis ,  Dieter Siuka ,  Horst Wiesinger

IPC分类号： C21B1314

CPC分类号： C21B13/0033 ,  C21B13/002 ,  C21B13/14 ,  C21B2100/282 ,  C21B2100/44 ,  C21B2100/66 ,  Y02P10/122 ,  Y02P10/128 ,  Y02P10/136

摘要： In a plant for the production of pig iron and/or sponge iron, comprising at least one fluidized bed reactor adapted to receive fine ore, a reducing-gas feed duct leading to said fluidized bed reactor, an off gas discharge duct departing from the fluidized bed reactor and a discharge means, preferably a briquetting means, provided for the reduction product formed in the fluidized bed reactor, the off gas discharge duct of the fluidized bed reactor runs into a purification means, such as a scrubber, subsequently into a heating means and finally into the reducing gas feed duct of the fluidized bed reactor. To produce a product having a high quality standard at a minimum energy input, the heating means is constructed such that it comprises two stages including a heat exchanger as the heating means for the reducing gas and, connected serially therewith, a partial combustion means for the reducing gas with an oxygen feeding means.

摘要翻译： 在用于生产生铁和/或海绵铁的设备中，包括至少一个适于接收细矿石的流化床反应器，通向所述流化床反应器的还原气进料管，离开流化床 床式反应器和为在流化床反应器中形成的还原产物提供的排出装置，优选压块装置，流化床反应器的废气排放管道进入净化装置，例如洗涤器，随后进入加热装置 最后进入流化床反应器的还原气体进料管道。 为了以最小能量输入产生具有高质量标准的产品，加热装置被构造成使得其包括两个级，包括作为用于还原气体的加热装置的热交换器，并且与其串联连接的部分燃烧装置 用氧气供给装置还原气体。

公开(公告)号：US06336954B1

公开(公告)日：2002-01-08

申请号：US09505559

申请日：2000-02-17

申请人： Siegfried Zeller ,  Konstantin Milionis ,  Johann Reidetschläger ,  Leopold Werner Kepplinger ,  Johann Zirngast ,  Johannes Schenk ,  Roy Hubert Whipp, Jr.

发明人： Siegfried Zeller ,  Konstantin Milionis ,  Johann Reidetschläger ,  Leopold Werner Kepplinger ,  Johann Zirngast ,  Johannes Schenk ,  Roy Hubert Whipp, Jr.

IPC分类号： C21B1300

CPC分类号： C21B13/0033 ,  Y02P10/122 ,  Y02P10/128 ,  Y02P10/136 ,  Y02P10/143

摘要： A process for the direct reduction of particulate iron-oxide-containing material by fluidization. A synthesis gas is introduced as a reducing gas into several fluidized bed zones consecutively arranged in series for the reducing gas. The reducing gas is conducted from one fluidized bed zone to another fluidized bed zone in counterflow to the particulate iron-oxide containing material. In order to reduce operating costs and, in particular, the energy demand, the temperature of the iron-oxide-containing material is adjusted in the first fluidized bed zone to be either below 400° C. (and, preferably, below 350° C.), or above 580° C. (and preferably about 650° C.), or to a temperature ranging from 400° C. to 580° C. If the temperature of the iron-oxide-containing material in the first fluidized bed zone is adjusted to be below 400° C., the temperature range in the following fluidized bed zone between 400° C. and 580° C. is passed through within a period of 10 minutes and, preferably, within 5 minutes. If the temperature of the iron-oxide-containing material in the first fluidized bed zone is adjusted to be above 580° C., the temperature range in the first fluidized bed zone between 400° C. and 580° C. is passed through within a period of time of maximally 10 minutes and, preferably, 5 minutes. If the temperature of the iron-oxide-containing material in the first fluidized bed zone is adjusted to be in the range of from 400° C. to 580° C., the iron-oxide-containing material remains within that temperature range for a maximum of 10 minutes and, preferably, 5 minutes, and the material is passed on into the following fluidized bed zone immediately after having reached the desired temperature.

摘要翻译： 一种通过流化直接还原含氧化铁颗粒物质的方法。 将合成气作为还原气体引入连续排列为还原气体的多个流化床区域。 还原气体从一个流化床区域传导到另一个流化床区域，与含铁氧化物颗粒材料相反。 为了降低运行成本，特别是能量需求，将含铁氧化物的材料的温度在第一流化床区域调节至低于400℃（优选低于350℃） ），或高于580℃（优选约650℃），或达到400℃至580℃的温度。如果第一流化床中含氧化铁的材料的温度 将区域调节至低于400℃，在下述流化床区域中在400℃至580℃之间的温度范围在10分钟内优选在5分钟内通过。 如果将第一流化床区域中含氧化铁的材料的温度调节至高于580℃，则在400℃至580℃之间的第一流化床区域内的温度范围通过 时间最长为10分钟，最好为5分钟。 如果将第一流化床区域中含氧化铁的材料的温度调节至400℃至580℃的范围内，则含铁氧化物的材料保持在该温度范围内 最多10分钟，优选5分钟，并且在达到所需温度之后立即将材料通入下一流化床区。

公开(公告)号：US07597739B2

公开(公告)日：2009-10-06

申请号：US11820749

申请日：2007-06-20

申请人： Leopold Werner Kepplinger ,  Johann Reidetschlager ,  Johannes Schenk ,  Siegfried Zeller ,  Konstantin Milionis ,  Hanspeter Ofner

发明人： Leopold Werner Kepplinger ,  Johann Reidetschlager ,  Johannes Schenk ,  Siegfried Zeller ,  Konstantin Milionis ,  Hanspeter Ofner

IPC分类号： C21B13/14

CPC分类号： C21B13/0033 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/128 ,  Y02P10/136

摘要： In a process for reducing iron-ore-containing particulate material in at least a two-stage process, reducing gas is conducted through at least two reaction zones consecutively arranged in series and formed by a moving particulate material and the particulate material passes through the reaction zones in reverse order to the reducing gas, with the particulate material being heated in the reaction zone arranged first for the particulate material and being reduced in the further reaction zone.In order to achieve a maximum preheating temperature without any formation of magnetite, the reducing gas added to the first reaction zone is conditioned such that no or hardly any reduction takes place, although for the particulate material a preheating temperature within the fringe range of starting a reduction is achieved, whereby either the degree of oxidation of the reducing gas is increased or the temperature of the reducing gas is decreased or both measures are carried out jointly and whereby, in the reactor zone arranged second for the iron ore, a temperature level of at least about 600° C., preferably in the range of between 600 and 700° C., in particular of between 620 and 660° C., is adjusted and the iron-oxide-containing material is reduced to wuestite (FIG. 1).

摘要翻译： 在至少两阶段工艺中还原含铁矿石颗粒材料的方法中，还原气体通过至少两个串联连续排列的反应区进行，并由移动的颗粒材料形成，颗粒材料通过反应 区域与还原气体相反，其中颗粒材料在反应区域中被加热，首先用于颗粒材料并在另外的反应区域中被还原。 为了达到最大预热温度而没有任何形成磁铁矿，添加到第一反应区域的还原气体被调节，使得不发生或几乎不发生任何还原，尽管对于颗粒材料，预热温度在起始 由此可以减少还原气体的氧化程度，还原气体的温度降低或两者兼而有之，由此在铁矿石排列第二的反应器区域中， 至少约600℃，优选在600和700℃之间，特别是在620和660℃之间，并且将含铁氧化物的材料还原成为硅酸盐（图1 ）。

公开(公告)号：US06569377B2

公开(公告)日：2003-05-27

申请号：US10045061

申请日：2002-01-15

申请人： Siegfried Zeller ,  Konstantin Milionis ,  Johann Reidetschläger ,  Leopold Werner Kepplinger ,  Johann Zirngast ,  Johannes Schenk ,  Roy Hubert Whipp, Jr.

发明人： Siegfried Zeller ,  Konstantin Milionis ,  Johann Reidetschläger ,  Leopold Werner Kepplinger ,  Johann Zirngast ,  Johannes Schenk ,  Roy Hubert Whipp, Jr.

IPC分类号： C21B1300

CPC分类号： C21B13/0033 ,  Y02P10/122 ,  Y02P10/128 ,  Y02P10/136 ,  Y02P10/143

摘要： In a process for the direct reduction of particulate iron-oxide-containing material by fluidization, a synthesis gas is introduced as a reducing gas into several fluidized bed zones consecutively arranged in series. The reducing gas is conducted from one fluidized bed zone to another fluidized bed zone in counterflow to a flow of particulate iron-oxide containing material through the fluidized bed zones. In order to reduce operating costs and, in particular, the energy demand, various process parameters are varied according to the temperature of the iron-oxide-containing material in the first fluidized bed zone being adjusted to be below 400° C. (and, preferably, below 350° C.), above 580° C. (and preferably about 650° C.), or to a temperature within the range of from 400° C. to 580° C. If the temperature of the iron-oxide-containing material in the first fluidized bed zone is maintained to be below 400° C., the temperature of the iron-oxide-containing material in the following fluidized bed zone is passed through the temperature range between 400° C. and 580° C. within a period of 10 minutes and, preferably, within 5 minutes. If the temperature of the iron-oxide-containing material in the first fluidized bed zone is adjusted to a temperature above 580° C., the temperature range of between 400° C. and 580° C. in the first fluidized bed zone is passed through within a maximum period of time of 10 minutes and, preferably, 5 minutes. If the temperature of the iron-oxide-containing material in the first fluidized bed zone is adjusted to be within the range of from 400° C. to 580° C., the iron-oxide-containing material remains in the first fluidized bed zone within that temperature range for a maximum of 10 minutes and, preferably, 5 minutes, and the material is then passed on into the following fluidized bed zone immediately after having reached the desired temperature.

公开(公告)号：US5554206A

公开(公告)日：1996-09-10

申请号：US398562

申请日：1995-03-03

申请人： Karl Czermak ,  Konstantin Milionis ,  Gero Tessmer ,  Roy H. Whipp, Jr.

发明人： Karl Czermak ,  Konstantin Milionis ,  Gero Tessmer ,  Roy H. Whipp, Jr.

IPC分类号： C21B13/08 ,  B65G53/12 ,  B65G53/22 ,  C21B13/00 ,  C21B13/06 ,  F27D3/18

CPC分类号： C21B13/00 ,  Y02P10/122 ,  Y02P10/136

摘要： A method of and apparatus for charging fine-grained ore into a reactor pressure vessel through which process gas flows. The heated ore at first is introduced into a conveying pressure vessel, is pressurized within the same by compressed gas and subsequently is conveyed into the reactor pressure vessel through a conveying duct by aid of the compressed gas. In order to ensure favorable utilization of the reactor pressure vessel under uniform stress and to safeguard troublefree progression of reduction while directly charging the ore, a portion of the ore is introduced into at least one further conveying pressure vessel and is pressurized within the same also by compressed gas. Charging of the ore into the reactor pressure vessel is effected continuously by alternately feeding once from the one conveying pressure vessel and subsequently from the other conveying pressure vessel. The compressed gas is taken from the process gas as a quantitative or as a component portion of the process gas and is fed back to the same along with the ore.

摘要翻译： 将细粒矿石装入反应堆压力容器中的方法和装置，工艺气体通过该压力容器流动。 首先将加热的矿石引入输送压力容器中，通过压缩气体在其内加压，随后通过压缩气体通过输送管道输送到反应堆压力容器中。 为了确保反应堆压力容器在均匀应力下的有利利用，并且在直接对矿石进行充电的同时保证无故障地进行还原，一部分矿石被引入到至少一个另外的输送压力容器中，并且通过 压缩气体。 通过从一个输送压力容器和随后的另一个输送压力容器交替地进料一次，连续地进料矿石进入反应堆压力容器。 压缩气体作为工艺气体的定量或组分部分从工艺气体中取出，并与矿石一起反馈到其中。

公开(公告)号：US4720299A

公开(公告)日：1988-01-19

申请号：US857238

申请日：1986-04-29

申请人： Konstantin Milionis

发明人： Konstantin Milionis

IPC分类号： C21B13/02

CPC分类号： C21B13/02 ,  C21B2100/02 ,  C21B2100/04 ,  Y02P10/136 ,  Y02P10/143 ,  Y02P10/265 ,  Y02P10/283

摘要： A method for the direct reduction of particulate iron-oxide-containing material. The method is carried out in a shaft furnace, wherein reformed gas from a reformer is fed as reducing gas to a reducing zone of the shaft furnace, the directly reduced ferrous particles are discharged from the shaft furnace and the top gas forming during reduction is extracted from the upper section of the shaft furnace. A hydrocarbon-containing gas is injected into the shaft furnace. Natural gas is separated into a first fraction enriched with low hydrocarbons and a second fraction enriched with higher hydrocarbons. The first fraction is conducted through the reformer and the second fraction is fed into the shaft furnace.

摘要翻译： 一种用于直接还原含氧化铁颗粒物质的方法。 该方法在立式炉中进行，其中来自重整器的重整气体作为还原气体进料到竖炉的还原区，直接还原的亚铁颗粒从竖炉排出，还原期间形成顶部气体 从竖炉的上部。 将烃类气体注入竖炉。 将天然气分离成富含低碳氢化合物的第一馏分和富含高级烃的第二馏分。 第一馏分通过重整器进行，第二馏分进料到竖炉中。

公开(公告)号：US20070245853A1

公开(公告)日：2007-10-25

申请号：US11820749

申请日：2007-06-20

申请人： Leopold Kepplinger ,  Johann Reidetschlager ,  Johannes Schenk ,  Siegfried Zeller ,  Konstantin Milionis ,  Hanspeter Ofner

发明人： Leopold Kepplinger ,  Johann Reidetschlager ,  Johannes Schenk ,  Siegfried Zeller ,  Konstantin Milionis ,  Hanspeter Ofner

IPC分类号： B22F1/00

CPC分类号： C21B13/0033 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/128 ,  Y02P10/136

摘要： In a process for reducing iron-ore-containing particulate material in at least a two-stage process, reducing gas is conducted through at least two reaction zones consecutively arranged in series and formed by a moving particulate material and the particulate material passes through the reaction zones in reverse order to the reducing gas, with the particulate material being heated in the reaction zone arranged first for the particulate material and being reduced in the further reaction zone. In order to achieve a maximum preheating temperature without any formation of magnetite, the reducing gas added to the first reaction zone is conditioned such that no or hardly any reduction takes place, although for the particulate material a preheating temperature within the fringe range of starting a reduction is achieved, whereby either the degree of oxidation of the reducing gas is increased or the temperature of the reducing gas is decreased or both measures are carried out jointly and whereby, in the reactor zone arranged second for the iron ore, a temperature level of at least about 600° C., preferably in the range of between 600 and 700° C., in particular of between 620 and 660° C., is adjusted and the iron-oxide-containing material is reduced to wuestite (FIG. 1).

摘要翻译： 在至少两阶段工艺中还原含铁矿石颗粒材料的方法中，还原气体通过至少两个串联连续排列的反应区进行，并由移动的颗粒材料形成，颗粒材料通过反应 区域与还原气体相反，其中颗粒材料在反应区域中被加热，首先用于颗粒材料并在另外的反应区域中被还原。 为了达到最大预热温度而没有任何形成磁铁矿，添加到第一反应区域的还原气体被调节，使得不发生或几乎不发生任何还原，尽管对于颗粒材料，预热温度在起始 由此可以减少还原气体的氧化程度，还原气体的温度降低或两者兼而有之，由此在铁矿石排列第二的反应器区域中， 至少约600℃，优选在600和700℃之间，特别是在620和660℃之间，并且将含铁氧化物的材料还原成为乌素（图1 ）。

公开(公告)号：US5833734A

公开(公告)日：1998-11-10

申请号：US849838

申请日：1997-07-24

申请人： Gerhard Cip ,  Gottfried Rossmann ,  Konstantin Milionis ,  Roy Hubert Whipp, Jr.

发明人： Gerhard Cip ,  Gottfried Rossmann ,  Konstantin Milionis ,  Roy Hubert Whipp, Jr.

IPC分类号： C21B13/00 ,  C22B5/14

CPC分类号： C21B13/0033 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/128 ,  Y02P10/136 ,  Y02P10/143

摘要： With a process for the direct reduction of particulate iron-containing material by fluidization, reformed gas, at least partially freed from CO.sub.2, is supplied to a fluidized-bed reduction zone as a reducing gas and is carried off from the same as a top gas and at least a portion of the top gas together with reformed gas is utilized for direction reduction. To economize on parts of the plant that are impinged on by reducing gas and in order to achieve savings in terms of heating costs, CH.sub.4 and N.sub.2 are, in addition to CO.sub.2, at least partially removed by adsorption, from 50 to 100% of the reformed as and 0 to 100% of the top gas, and the tail gas removed from the reformed gas and/or the top gas by adsorption is utilized as a heating gas.

摘要翻译： PCT No.PCT / AT96 / 00190 Sec。 371日期1997年7月24日 102（e）1997年7月24日PCT PCT 1996年10月8日PCT公布。 公开号WO97 / 13879 日期1997年04月17日为了通过流化直接还原颗粒状含铁材料的方法，至少部分从CO 2中除去的重整气体作为还原气体被供给到流化床还原区，并从 与顶部气体相同，并且顶部气体的至少一部分与重整气体一起用于方向减少。 为了节省通过减少气体冲击的工厂的部分，为了节约加热成本，CH4和N2除CO2之外至少部分通过吸附除去，从50％到100％的 重整为顶部气体的0〜100％，通过吸附从重整气体和/或顶部气体除去的尾气被用作加热气体。