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    Selective hydrogenation of conjugation diolefin polymers with rare earth catalysts
    1.
    发明授权
    Selective hydrogenation of conjugation diolefin polymers with rare earth catalysts 失效
    用稀土催化剂选择性氢化共轭二烯烃聚合物

    公开(公告)号：US5177155A

    公开(公告)日：1993-01-05

    申请号：US699028

    申请日：1991-05-13

    申请人： Linda R. Chamberlain ,  Carma J. Gibler ,  Richard A. Kemp ,  Stanley E. Wilson ,  Thomas F. Brownscombe

    发明人： Linda R. Chamberlain ,  Carma J. Gibler ,  Richard A. Kemp ,  Stanley E. Wilson ,  Thomas F. Brownscombe

    IPC分类号： C08C19/02 ,  C08F8/04

    CPC分类号： C08C19/02 ,  C08F8/04

    摘要： This invention provides a catalyst and a process for the hydrogenation of conjugated diolefin polymers which first involves the polymerization or copolymerization of such monomers with an organo alkali metal polymerization initiator in a suitable solvent thereby creating a living polymer. The living polymer can be terminated by the addition of hydrogen. Finally, selective hydrogenation of the unsaturable double bonds in the conjugated diolefin units of the terminated polymer is carried out in the presence of an initiator and at least one rare earth compound of the formula*Cp.sub. MRwhere *Cp is pentamethylcyclopentadiene, M is a rare earth element and R is alkyl, aryl, aralkyl or hydrogen.

    摘要翻译： 本发明提供了一种用于共轭二烯烃聚合物的氢化的催化剂和方法，其首先涉及这种单体与有机碱金属聚合引发剂在合适的溶剂中的聚合或共聚，从而产生活性聚合物。 活性聚合物可以通过加入氢来终止。 最后，封端聚合物的共轭二烯烃单元中的不饱和双键的选择性氢化在引发剂和至少一种式* CpMR的稀土化合物的存在下进行，其中* Cp是五甲基环戊二烯，M是稀土 元素，R是烷基，芳基，芳烷基或氢。

    Selective hydrogenation of conjugated diolefin polymers
    2.
    发明授权
    Selective hydrogenation of conjugated diolefin polymers 失效
    选择性加氢共聚二烯丙基聚合物

    公开(公告)号：US5141997A

    公开(公告)日：1992-08-25

    申请号：US568113

    申请日：1990-08-15

    申请人： Linda R. Chamberlain ,  Carma J. Gibler ,  Richard A. Kemp ,  Stanley E. Wilson

    发明人： Linda R. Chamberlain ,  Carma J. Gibler ,  Richard A. Kemp ,  Stanley E. Wilson

    IPC分类号： C08F8/04 ,  C08C19/02 ,  C08F36/00 ,  C08F36/04 ,  C08F297/04

    CPC分类号： C08C19/02

    摘要： This invention provides a catalyst and a process for the hydrogenation of conjugated diolefin polymers which first involves the polymerization or copolymerization of such monomers with an organo alkali metal polymerization initiator in a suitable solvent thereby creating a living polymer. The living polymer is preferably terminated by the addition of hydrogen. Finally, selective hydrogenation of the unsaturated double bonds in the conjugated diolefin units of the terminated polymer is carried out in the presence of at least one bis(cyclopentadienyl)titanium (+3) compound of the formula:(C.sub.5 R".sub.5).sub.2 --Ti--Rwhere R is selected from the group consisting of alkyl, aralkyl, allyl, aryl, alkoxy, halogen, silyl or amine and R", which may be the same or different, is selected from the group consisting of hydrogen, alkyl, aralkyl or aryl.

    Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent
    4.
    发明授权
    Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent 失效
    用Tebbe试剂选择性氢化共轭二烯烃聚合物

    公开(公告)号：US5334566A

    公开(公告)日：1994-08-02

    申请号：US49689

    申请日：1993-04-16

    申请人： Carma J. Gibler ,  Stanley E. Wilson

    发明人： Carma J. Gibler ,  Stanley E. Wilson

    IPC分类号： C08C19/02 ,  C08F8/04 ,  B01J31/00

    CPC分类号： C08F8/04 ,  C08C19/02

    摘要： This is a process for the hydrogenation of conjugated diolefin polymers which comprises polymerizing or copolymerizing at least one conjugated diolefin with an organo alkali metal polymerization initiator in a suitable solvent thereby creating a living polymer, terminating the polymerization by the addition of hydrogen and effecting selective hydrogenation of the unsaturated double bonds in the conjugated diolefin units of the terminated polymer by contacting the polymer with hydrogen in the presence of an organo alkali metal promoter and Tebbe's reagent.

    摘要翻译： 这是一种用于共轭二烯烃聚合物氢化的方法，其包括在合适的溶剂中使至少一种共轭二烯烃与有机碱金属聚合引发剂聚合或共聚，从而产生活性聚合物，通过加入氢终止聚合并进行选择性氢化 通过在有机碱金属助催化剂和Tebbe试剂的存在下使聚合物与氢接触而使端基聚合物的共轭二烯烃单元中的不饱和双键结合。

    Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent
    5.
    发明授权
    Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent 失效
    用Tebbe试剂选择性氢化共轭二烯烃聚合物

    公开(公告)号：US5244980A

    公开(公告)日：1993-09-14

    申请号：US986200

    申请日：1992-12-07

    申请人： Carma J. Gibler ,  Stanley E. Wilson

    发明人： Carma J. Gibler ,  Stanley E. Wilson

    IPC分类号： C08C19/02 ,  C08F8/04

    CPC分类号： C08F8/04 ,  C08C19/02

    摘要： This is a process for the hydrogenation of conjugated diolefin polymers which comprises polymerizing or copolymerizing at least one conjugated diolefin with an organo alkali metal polymerization initiator in a suitable solvent thereby creating a living polymer, terminating the polymerization by the addition of hydrogen and effecting selective hydrogenation of the unsaturated double bonds in the conjugated diolefin units of the terminated polymer by contacting the polymer with hydrogen in the presence of an organo alkali metal promoter and Tebbe's reagent.

    摘要翻译： 这是一种用于共轭二烯烃聚合物氢化的方法，其包括在合适的溶剂中使至少一种共轭二烯烃与有机碱金属聚合引发剂聚合或共聚，从而产生活性聚合物，通过加入氢终止聚合并进行选择性氢化 通过在有机碱金属助催化剂和Tebbe试剂的存在下使聚合物与氢接触而使端基聚合物的共轭二烯烃单元中的不饱和双键结合。

    Olefin polymerization catalyst
    6.
    发明授权
    Olefin polymerization catalyst 失效
    烯烃聚合催化剂

    公开(公告)号：US5411926A

    公开(公告)日：1995-05-02

    申请号：US193302

    申请日：1994-02-08

    申请人： Stanley E. Wilson ,  Richard A. Kemp

    发明人： Stanley E. Wilson ,  Richard A. Kemp

    IPC分类号： C08F4/658 ,  C08F4/654 ,  C08F10/00 ,  B01J31/00

    CPC分类号： C08F10/00

    摘要： A high activity olefin polymerization catalyst catalyzes the production of polymeric lower .alpha.-olefin having good properties. The catalyst is produced from an organoaluminum cocatalyst, a selectivity control agent and a novel olefin polymerization procatalyst which is prepared by contacting a tetravalent titanium halide, an optional inert diluent, an electron donor and a novel solid procatalyst precursor obtained by contacting (a) a carbonated magnesium alkoxide of the general formula ##STR1## wherein R is a hydrocarbyl group having up to 12 carbon atoms and x is a number from 0.1 to about 2; and (b) at least one halogenating compound which is a non-transition metal halogenated compound or non-metallic halogenated compound. A process for polymerizing one or more .alpha.-olefins utilizing the novel high activity polymerization catalyst.

    摘要翻译： 高活性烯烃聚合催化剂催化生产具有良好性能的聚合低级α-烯烃。 催化剂由有机铝助催化剂，选择性控制剂和新型烯烃聚合主催化剂制备，其通过使四价钛卤化物，任选的惰性稀释剂，电子给体和新型固体前催化剂前体接触来制备，所述前体催化剂通过使（a） 碳酸化的通式为“IMAGE”的烷醇镁，其中R是具有至多12个碳原子的烃基，x是0.1至约2的数; 和（b）至少一种卤化化合物，其是非过渡金属卤化化合物或非金属卤化化合物。 利用新的高活性聚合催化​​剂聚合一种或多种α-烯烃的方法。

    Process for olefin polymerization
    7.
    发明授权
    Process for olefin polymerization 失效
    烯烃聚合方法

    公开(公告)号：US5498676A

    公开(公告)日：1996-03-12

    申请号：US367651

    申请日：1995-01-03

    申请人： Stanley E. Wilson ,  Richard A. Kemp

    发明人： Stanley E. Wilson ,  Richard A. Kemp

    IPC分类号： C08F4/658 ,  C08F4/654 ,  C08F10/00 ,  C08F4/44 ,  B01J31/38

    CPC分类号： C08F10/00

    摘要： A high activity olefin polymerization catalyst catalyzes the production of polymeric lower .alpha.-olefin having good properties. The catalyst is produced from an organoaluminum cocatalyst, a selectivity control agent and a novel olefin polymerization procatalyst which is prepared by contacting a tetravalent titanium halide, an optional inert diluent, an electron donor and a novel solid procatalyst precursor obtained by contacting (a) a carbonated magnesium alkoxide of the general formula ##STR1## wherein R is a hydrocarbyl group having up to 12 carbon atoms and x is a number from 0.1 to about 2; and (b) at least one halogenating compound which is a non-transition metal halogenated compound or non-metallic halogenated compound. A process for polymerizing one or more .alpha.-olefins utilizing the novel high activity polymerization catalyst.

    摘要翻译： 高活性烯烃聚合催化剂催化生产具有良好性能的聚合低级α-烯烃。 催化剂由有机铝助催化剂，选择性控制剂和新型烯烃聚合主催化剂制备，其通过使四价钛卤化物，任选的惰性稀释剂，电子给体和新型固体前催化剂前体接触来制备，所述前体催化剂通过使（a） 碳酸化的通式为“IMAGE”的烷醇镁，其中R是具有至多12个碳原子的烃基，x是0.1至约2的数; 和（b）至少一种卤化化合物，其是非过渡金属卤化化合物或非金属卤化化合物。 利用新的高活性聚合催化​​剂聚合一种或多种α-烯烃的方法。

    Catalyst composition and polymerization process using mixture of silane electron donors
    8.
    发明授权
    Catalyst composition and polymerization process using mixture of silane electron donors 失效
    催化剂组合物和聚合方法使用硅烷电子给体的混合物

    公开(公告)号：US07521512B2

    公开(公告)日：2009-04-21

    申请号：US10555548

    申请日：2004-05-27

    申请人： Stanley E. Wilson

    发明人： Stanley E. Wilson

    IPC分类号： C08F4/616

    CPC分类号： C08F110/06 ,  C08F4/6465 ,  C08F2500/12

    摘要： A catalyst composition for the polymerization of olefins comprising the combination of one or more Ziegler-Natta procatalysts comprising one or more transition metal compounds; one or more aluminum containing cocatalysts; and a mixture comprising two or more selectivity control agents (SCA's), corresponding to the formula: (CH3O)nSi(OR)4-n, wherein R, independently each occurrence, is C2-12 alkyl, C3-12 cycloalkyl, C6-18 aryl or (poly)alkyl-substituted aryl, or C7-18 poly(aryl)-substituted alkyl, and n is an integer from zero to 4.

    摘要翻译： 一种用于烯烃聚合的催化剂组合物，其包含一种或多种包含一种或多种过渡金属化合物的齐格勒 - 纳塔前催化剂的组合; 一种或多种含铝助催化剂; 对应于式（CH3O）nSi（OR）4-n的两种或多种选择性控制剂（SCA）的混合物，其中R各自独立地为C 2-12烷基，C 3-12环烷基， 18芳基或（多）烷基取代的芳基或C7-18聚（芳基） - 取代的烷基，n为0至4的整数。