公开(公告)号：US20090173383A1

公开(公告)日：2009-07-09

申请号：US12406760

申请日：2009-03-18

申请人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

发明人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC分类号： H01L31/0216 ,  H01B1/02

CPC分类号： B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y−+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2.times.292 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2.times.3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘和两个相邻的八面体（2.282），以形成沿着纤维轴发展的无限链。 根据本发明，作为共享边缘的结果，两个相邻的链形成双线（2/3.27埃）。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。

公开(公告)号：US07524482B2

公开(公告)日：2009-04-28

申请号：US10502399

申请日：2003-01-14

申请人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

发明人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC分类号： C01G25/02 ,  C01G27/02 ,  C04B35/00

CPC分类号： B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z (x+y+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2×2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2×3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘和两个相邻的八面体（2x2.92埃），以便形成沿着纤维轴发展的无限链。 根据本发明，由于共享边缘（2x3.27），两个相邻的链形成双线。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。

公开(公告)号：US07723610B2

公开(公告)日：2010-05-25

申请号：US12406760

申请日：2009-03-18

申请人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

发明人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC分类号： C01G25/02 ,  C01G27/02 ,  C04B35/00 ,  H01L35/00 ,  H01B1/02 ,  H01M6/30

CPC分类号： B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y−+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2.times.2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2.times.3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘，其中两个相邻的八面体（2. 2.92埃）以形成沿着纤维轴发展的无限链。 根据本发明，作为共享边缘的结果，两个相邻的链形成双线（2/3.27埃）。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。

公开(公告)号：US20050163702A1

公开(公告)日：2005-07-28

申请号：US10502399

申请日：2003-01-14

申请人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

发明人： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC分类号： C01G23/04 ,  B01J13/00 ,  C01G23/053 ,  H01L31/04 ,  H01M14/00

CPC分类号： B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2×2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2×3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含（x + y +）（x + y + z） z = 3）凝胶或溶胶形式的氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 2六面体共享两个相邻的边缘和两个相邻的八面体（2x2.92），以形成沿轴线发展的无限链 的纤维。 根据本发明，由于共享边缘（2x3.27），两个相邻的链形成双线。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。

公开(公告)号：US07858064B2

公开(公告)日：2010-12-28

申请号：US10555926

申请日：2004-04-29

申请人： Luc Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Hélène Terrisse

发明人： Luc Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Hélène Terrisse

IPC分类号： C01G23/00

CPC分类号： B01J35/004 ,  B01J27/135 ,  B82Y30/00 ,  C01G23/02 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/85 ,  C01P2004/03 ,  C01P2004/64

摘要： The invention relates to a titanium aquo-oxo chloride and to a method for its preparation. The compound is in the form of crystals and has the following composition by weight: 26.91% Ti; 21.36% Cl; and 4.41% H, which corresponds to the formula [Ti8O12(H2O)24]Cl8.HCl.7H2O. The method of preparation consists in hydrolyzing TiOCl2 either in an atmosphere whose moisture content is maintained between 50 and 60%, or by an alkali metal carbonate A2CO3, in order to obtain a titanium aquo-oxo chloride. The compound is useful as a semiconductor element of a photovoltaic cell or as a photocatalyst in air or water purification treatments.

摘要翻译： 本发明涉及一种钛 - 含氧氯化钛及其制备方法。 该化合物为晶体形式，重量百分比如下：26.91％Ti; 21.36％Cl; 和4.41％H，其对应于式[Ti8O12（H2O）24] Cl8·HCl·7H2O。 制备方法包括在水分含量保持在50至60％的气氛中或通过碱金属碳酸盐A2CO3水解TiOCl 2，以获得钛 - 氧代氯化钛。 该化合物在空气或水净化处理中可用作光伏电池的半导体元件或光催化剂。

公开(公告)号：US20070041890A1

公开(公告)日：2007-02-22

申请号：US10555926

申请日：2004-04-29

申请人： Lue Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Helene Terrisse

发明人： Lue Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Helene Terrisse

IPC分类号： C01G23/00

CPC分类号： B01J35/004 ,  B01J27/135 ,  B82Y30/00 ,  C01G23/02 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/85 ,  C01P2004/03 ,  C01P2004/64

摘要： The invention relates to a titanium aquo-oxo chloride and to a method for its preparation. The compound is in the form of crystals and has the following composition by weight: 26.91% Ti; 21.36% Cl; and 4.41% H, which corresponds to the formula [Ti8O12(H2O)24]Cl8.HCl.7H2O. The method of preparation consists in hydrolyzing TiOCl2 either in an atmosphere whose moisture content is maintained between 50 and 60%, or by an alkali metal carbonate A2CO3, in order to obtain a titanium aquo-oxo chloride. The compound is useful as a semiconductor element of a photovoltaic cell or as a photocatalyst in air or water purification treatments.

摘要翻译： 本发明涉及一种钛 - 含氧氯化钛及其制备方法。 该化合物为晶体形式，重量百分比如下：26.91％Ti; 21.36％Cl; 和4.41％H，其对应于式[Ti 8 O 12（H 2 O）24] C 8 H 12，HCl 7 H 2 O。 制备方法包括在水分含量保持在50至60％的气氛中或通过碱金属碳酸盐A 2 N 2 CO 2水解TiOCl 2， 3 N，以获得钛 - 氧代氯化钛。 该化合物在空气或水净化处理中可用作光伏电池的半导体元件或光催化剂。