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公开(公告)号：US20050163702A1
公开(公告)日：2005-07-28
申请号：US10502399
申请日：2003-01-14
申请人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
发明人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
IPC分类号： C01G23/04 , B01J13/00 , C01G23/053 , H01L31/04 , H01M14/00
CPC分类号： B82Y30/00 , C01G23/0536 , C01P2002/76 , C01P2004/10 , C01P2004/64 , C01P2006/60
摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2×2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2×3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.
摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含（x + y +）（x + y + z） z = 3）凝胶或溶胶形式的氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 2六面体共享两个相邻的边缘和两个相邻的八面体（2x2.92），以形成沿轴线发展的无限链 的纤维。 根据本发明，由于共享边缘（2x3.27），两个相邻的链形成双线。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。
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公开(公告)号：US20090173383A1
公开(公告)日：2009-07-09
申请号：US12406760
申请日：2009-03-18
申请人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Teresa Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
发明人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Teresa Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
IPC分类号： H01L31/0216 , H01B1/02
CPC分类号： B82Y30/00 , C01G23/0536 , C01P2002/76 , C01P2004/10 , C01P2004/64 , C01P2006/60
摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y−+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2.times.292 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2.times.3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.
摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘和两个相邻的八面体（2.282），以形成沿着纤维轴发展的无限链。 根据本发明，作为共享边缘的结果，两个相邻的链形成双线（2/3.27埃）。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。
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公开(公告)号：US07723610B2
公开(公告)日：2010-05-25
申请号：US12406760
申请日：2009-03-18
申请人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Teresa Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
发明人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Teresa Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
CPC分类号： B82Y30/00 , C01G23/0536 , C01P2002/76 , C01P2004/10 , C01P2004/64 , C01P2006/60
摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y−+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2.times.2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2.times.3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.
摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘，其中两个相邻的八面体（2. 2.92埃）以形成沿着纤维轴发展的无限链。 根据本发明，作为共享边缘的结果，两个相邻的链形成双线（2/3.27埃）。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。
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公开(公告)号：US07524482B2
公开(公告)日：2009-04-28
申请号：US10502399
申请日：2003-01-14
申请人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Teresa Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
发明人： Luc Brohan , Hari Sutrisno , Yves Piffard , Maria Teresa Caldes-Rouillon , Olivier Joubert , Eric Puzenat , Annabelle Rouet
CPC分类号： B82Y30/00 , C01G23/0536 , C01P2002/76 , C01P2004/10 , C01P2004/64 , C01P2006/60
摘要： The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z (x+y+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2×2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2×3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.
摘要翻译： 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘和两个相邻的八面体（2x2.92埃），以便形成沿着纤维轴发展的无限链。 根据本发明，由于共享边缘（2x3.27），两个相邻的链形成双线。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。
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5.发明申请公开(公告)号：US20100015495A1
公开(公告)日：2010-01-21
申请号：US12444976
申请日：2007-10-05
申请人： Philippe Stevens , Olivier Joubert , Yves Piffard , Maria Teresa Caldes-Rouillon , Thibaud Delahaye
发明人： Philippe Stevens , Olivier Joubert , Yves Piffard , Maria Teresa Caldes-Rouillon , Thibaud Delahaye
IPC分类号： H01M8/10
摘要： The invention relates to the use of a ceramic of formula Ba2(1−x)M2xIn2(1−y)M′2yO4+δ(OH)δ′ where M represents at least one metal cation with an oxidation number II or III or a combination thereof, M′ represents at least one metal cation with an oxidation number III, IV, V or VI or a combination thereof, 0
摘要翻译： 本发明涉及式Ba2（1-x）M2xIn2（1-y）M'2yO4 +δ（OH）δ'的陶瓷的用途，其中M表示至少一种氧化数为II或III的金属阳离子或 其组合，M'表示至少一种氧化数为III，IV，V或VI的金属阳离子或其组合，0
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公开(公告)号：US07956095B2
公开(公告)日：2011-06-07
申请号：US11886466
申请日：2006-03-09
IPC分类号： C08J5/20
CPC分类号： B01D67/002 , B01D67/0027 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/02 , B01D2323/08 , B01D2323/20 , B01D2323/21 , B01D2325/24 , C08J5/2256 , C08J2371/12 , C08J2379/06 , C08L71/00 , C08L81/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having acid ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having acid ionic groups and a plasticizer, in extruding the mixture obtained to form a film, then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译： 本发明涉及挤出具有酸性离子基团的热塑性聚合物的方法。 该方法包括制备由具有酸性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜，然后洗涤在水性介质中获得的膜以除去所述增塑剂。 增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物 通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。
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公开(公告)号：US20090131544A1
公开(公告)日：2009-05-21
申请号：US11886466
申请日：2006-03-09
IPC分类号： C08J5/20
CPC分类号： B01D67/002 , B01D67/0027 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/02 , B01D2323/08 , B01D2323/20 , B01D2323/21 , B01D2325/24 , C08J5/2256 , C08J2371/12 , C08J2379/06 , C08L71/00 , C08L81/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having acid ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having acid ionic groups and a plasticizer, in extruding the mixture obtained to form a film, then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译： 本发明涉及挤出具有酸性离子基团的热塑性聚合物的方法。 该方法包括制备由具有酸性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜，然后洗涤在水性介质中获得的膜以除去所述增塑剂。 增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物 通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。
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