公开(公告)号：US06586358B2

公开(公告)日：2003-07-01

申请号：US09804505

申请日：2001-03-12

申请人： Luis Mendez Llatas ,  Antonio Muñoz-Escalona Lafuente ,  Juan Campora Perez ,  Ernesto Carmona Guzman ,  Manuel Lopez Reyes

发明人： Luis Mendez Llatas ,  Antonio Muñoz-Escalona Lafuente ,  Juan Campora Perez ,  Ernesto Carmona Guzman ,  Manuel Lopez Reyes

IPC分类号： B01J3100

CPC分类号： C07F15/045 ,  C07F15/0066 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/09 ,  C08F2500/10 ,  C08F4/7006 ,  C08F4/7027 ,  C08F4/7037

摘要： The present invention relates to a bidenitate diimino-complex of nickel or palladium containing at least one group OSi(R)3 wherein each R, equal to or different from each other, is selected from the group consisting of: C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C2-C20 alkenyl, C7-C20 arylalkyl, C7-C20 alkylaryl, C8-C20 arylalkenyl, and C8-C20 alkenylaryl, linear or branched, preferably each R is independently methyl, ethyl or propyl. The present invention also relates to the process for the preparation of bidentate diimino complexes of nickel and palladium as well as the process for their use in olefin polymerization.

公开(公告)号：US06410768B1

公开(公告)日：2002-06-25

申请号：US09804370

申请日：2001-03-12

申请人： Luis Mendez Llatas ,  Antonio Muñoz-Escalona Lafuente ,  Juan Campora Perez ,  Ernesto Carmona Guzman ,  Manuel Lopez Reyes

发明人： Luis Mendez Llatas ,  Antonio Muñoz-Escalona Lafuente ,  Juan Campora Perez ,  Ernesto Carmona Guzman ,  Manuel Lopez Reyes

IPC分类号： C07F710

CPC分类号： C08F10/00 ,  C07F7/1804 ,  C08F110/02 ,  C08F2500/03 ,  C08F2500/10 ,  C08F4/7042 ,  C08F4/7006 ,  C08F4/7047 ,  C08F4/704

摘要： The present invention is related to diimino compounds of formulae (I) R2—N═C(R1)(R3)nC(R1)═N—R2 and (II) (R1)2C═N—(CR24)m—N═C(R1)2 functionalized with at least one siloxy group. Said diimino compounds are useful for obtaining a solid catalyst component for polymerizing olefins wherein the diimino compound of formulae (I) or (II) is bonded to a porous inorganic support and to a transition metal selected from groups 8, 9 and 10 of the periodic table. This invention also relates to a process for preparing said diimino compounds of formulae (I) or (II), to a process for obtaining said solid catalyst component comprising the combination of the diimino compound and a porous inorganic support. Further, the invention also relates to the use of said solid catalyst in combination with a cocatalyst to polirnenrze olefins.

摘要翻译： 本发明涉及式（I）的二亚氨基化合物：R2-N = C（R1）（R3）nC（R1）= N-R2和（Ⅱ）（R1）2C = N-（CR24）mN = C R1）2与至少一个甲硅烷氧基官能化。 所述二亚氨基化合物可用于获得用于聚合烯烃的固体催化剂组分，其中式（I）或（II）的二亚氨基化合物与多孔无机载体结合，并且选自周期表中第8,9和10族的过渡金属 表。 本发明还涉及一种制备所述式（I）或（II）二亚氨基化合物的方法，涉及获得所述固体催化剂组分的方法，所述固体催化剂组分包含二亚氨基化合物和多孔无机载体的组合。 此外，本发明还涉及所述固体催化剂与助催化剂组合以使烯烃反应的用途。