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1.发明授权Method and catalyst system for producing polyolefins with broadened molecular weight distributions 失效用于生产具有更宽分子量分布的聚烯烃的方法和催化剂体系公开(公告)号：US06384161B1
公开(公告)日：2002-05-07
申请号：US09474864
申请日：1999-12-30
IPC分类号： C08F402
CPC分类号： C08F110/02 , C08F4/65904 , C08F4/65912 , C08F4/65927 , Y10S526/943 , C08F4/65916 , C08F2500/04 , C08F2500/12
摘要： The present invention provides a process for preparing a supported metallocene catalyst system that can be used to catalyze formation of polyolefins having a wide molecular weight range. In accordance with the process of the present invention, a first portion of an inorganic oxide is dried under a first set of conditions, wherein upon treatment with an organoaluminoxide and a metallocene, a first catalyst system is formed usable to produce a polyolefin product having a first molecular weight average distribution. A second portion of an inorganic oxide under a second set of conditions, wherein upon treatment with an organoaluminoxane and a metallocene, a second catalyst system is formed usable to produce polyolefin product having a second molecular weight distribution. An amount of the first portion is mixed with an amount of the second portion to produce a final inorganic oxide support. The final inorganic oxide support is combined with an organoaluminoxane and a metallocene to produce a supported metallocene catalyst system usable to catalyze formation of polyolefins with a broadened molecular weight average distribution. In another aspect, the present invention provides a process for polymerizing polyolefins using the inventive supported metallocene catalyst system. The process comprises preparing the final catalyst as mentioned above and then contacting an olefin with the final metallocene catalyst system under conditions supporting polymerization.
摘要翻译： 本发明提供了一种制备负载型茂金属催化剂体系的方法，该体系可用于催化具有宽分子量范围的聚烯烃的形成。 根据本发明的方法，在第一组条件下将无机氧化物的第一部分干燥，其中在用有机铝氧化物和茂金属处理时，形成可用于生产聚烯烃产品的第一催化剂体系，所述聚烯烃产物具有 第一分子量平均分布。 在第二组条件下的无机氧化物的第二部分，其中在用有机铝氧烷和茂金属处理时，形成可用于制备具有第二分子量分布的聚烯烃产物的第二催化剂体系。 将第一部分的量与第二部分的量混合以产生最终的无机氧化物载体。 最终的无机氧化物载体与有机铝氧烷和茂金属组合以产生可用于催化分子量平均分布扩大的聚烯烃形成的负载金属茂催化剂体系。另一方面，本发明提供使用本发明聚合聚烯烃的方法 负载金属茂催化剂体系。 该方法包括如上所述制备最终催化剂，然后在支持聚合的条件下使烯烃与最终茂金属催化剂体系接触。
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2.发明授权公开(公告)号：US06509427B1
公开(公告)日：2003-01-21
申请号：US09690858
申请日：2000-10-18
申请人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
发明人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
IPC分类号： C08F202
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F4/65927
摘要： Metallocene having two cyclic dienyl groups connected by a single carbon having an aryl substituent and a terminally unsaturated hydrocarbyl substituent, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.
摘要翻译： 公开了具有由具有芳基取代基和末端不饱和烃基取代基的单个碳原子连接的两个环状二烯基的茂金属，由其制备的烯烃聚合催化剂体系，以及这种催化剂体系的用途。
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公开(公告)号：US06187880B1
公开(公告)日：2001-02-13
申请号：US09250963
申请日：1999-02-16
申请人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
发明人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
IPC分类号： C08F200
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F4/65927
摘要： Metallocene having two cyclic dienyl groups connected by a single carbon having an aryl substituent and a terminally unsaturated hydrocarbyl substituent, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.
摘要翻译： 公开了具有由具有芳基取代基和末端不饱和烃基取代基的单个碳原子连接的两个环状二烯基的茂金属，由其制备的烯烃聚合催化剂体系，以及这种催化剂体系的用途。
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公开(公告)号：US06992035B2
公开(公告)日：2006-01-31
申请号：US10251771
申请日：2002-09-23
申请人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
发明人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F4/65927
摘要： Metallocene having two cyclic dienyl groups connected by a single carbon having an aryl substituent and a terminally unsaturated hydrocarbyl substituent, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.
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公开(公告)号：US06221981B1
公开(公告)日：2001-04-24
申请号：US09152652
申请日：1998-09-14
申请人： Michael Jung , Helmut G. Alt , Bryan E. Hauger , M. Bruce Welch , David W. Dockter , Syriac J. Palackal , Antoni Jurkiewicz
发明人： Michael Jung , Helmut G. Alt , Bryan E. Hauger , M. Bruce Welch , David W. Dockter , Syriac J. Palackal , Antoni Jurkiewicz
IPC分类号： C08F444
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F4/65927
摘要： Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst system solution by combining an aluminoxane with a metallocene having a substituent which has olefinic unsaturation in a suitable liquid to form a liquid catalyst system, conducting prepolymerization of an olefin in the liquid catalyst system, and separating the resulting solid metallocene-containing catalyst system from the reaction mixture. Also polymerization of olefins using the inventive solid catalyst system is disclosed.
摘要翻译： 公开了用于制备高活性固体茂金属催化剂体系及其在烯烃聚合中的应用的方法。 催化剂体系是通过在合适的液体中将铝氧烷与具有烯属不饱和键的取代基的茂金属组合形成液体催化剂体系，在液体催化剂体系中进行烯烃预聚合，并分离 从反应混合物中得到固体茂金属的催化剂体系。 还公开了使用本发明的固体催化剂体系的烯烃的聚合。
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6.发明授权公开(公告)号：US06239060B1
公开(公告)日：2001-05-29
申请号：US09224176
申请日：1998-12-31
IPC分类号： B01J3502
CPC分类号： B01J31/1616 , B01J31/128 , B01J31/143 , B01J31/1608 , B01J31/2295 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10S526/943 , C08F4/65916
摘要： The present invention provides a new type of supported metallocene catalyst system. In one aspect of the invention, an inorganic oxide support, such as silica, is impregnated with a Group XIII element such as B, Al or GA. The support is then contacted with a liquid catalyst system prepared by combining in a liquid an organo aluminoxane and a metallocene having two cyclopetadienyl-type ligands selected from substituted or unsubstituted cyclopentadienyl, indenyl, benzoindenyl, tetrahdroindenyl, benzofluorenyl, octahydrofluorenyl, and fluorenyl ligands to form a supported metallocene catalyst system. In preferred embodiments the process further includes conducting prepolymerization of at least one olefin in the presence of the supported metallocene catalyst system to produce a prepolymerized metallocene catalyst system. The prepolymerized metallocene catalyst system prepared in this manner yields substantially increased activity for the polymerization of olefins. In another aspect, the present invention also provides a method for polymerization of olefins using the inventive supported metallocene catalyst system.
摘要翻译： 本发明提供一种新型的负载型茂金属催化剂体系。 在本发明的一个方面，无机氧化物载体如二氧化硅用第ⅩⅢ族元素如B，Al或GA浸渍。 然后将载体与通过在液体中组合有机铝氧烷和具有选自取代或未取代的环戊二烯基，茚基，苯并茚基，四氢茚基，苯并芴基，八氢芴基和芴基配体的两个环戊二烯基型配体的金属茂接触而形成的液体催化剂体系形成 负载金属茂催化剂体系。 在优选的实施方案中，该方法还包括在负载的茂金属催化剂体系的存在下进行至少一种烯烃的预聚合，以产生预聚合的茂金属催化剂体系。 以这种方式制备的预聚合的茂金属催化剂体系产生了烯烃聚合的显着提高的活性。 另一方面，本发明还提供使用本发明的负载型茂金属催化剂体系聚合烯烃的方法。
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7.发明授权Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts 失效吡啶二亚胺与钒和其他过渡金属的络合物，以及它们作为烯烃低聚和聚合催化剂的用途公开(公告)号：US06458905B1
公开(公告)日：2002-10-01
申请号：US09640285
申请日：2000-08-16
申请人： Roland Schmidt , Ulrich Hammon , M. Bruce Welch , Helmut G. Alt , Bryan E. Hauger , Ronald D. Knudsen
发明人： Roland Schmidt , Ulrich Hammon , M. Bruce Welch , Helmut G. Alt , Bryan E. Hauger , Ronald D. Knudsen
IPC分类号： C08F416
CPC分类号： C08F10/00 , C07C2/32 , C07C2531/22 , C07F17/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/68 , C08F4/62 , C08F2500/04 , C08F210/14 , C08F4/68224 , C08F4/7042 , C08F4/64089 , C08F4/62089
摘要： A polymerization process for polymerizing at least one olefin in the presence of a pyridyldiimine metal complex as a catalyst having one of the following structures: The metal M of the complex is a transition metal from Group 4b, 5b or 6b of the Periodic Table such as vanadium. The invention also relates to the use of these metal complexes as olefin polymerization or oligomerization catalysts, optionally in combination with metal alumoxane and similar catalyst activators.
摘要翻译： 在具有以下结构之一的吡啶基二亚胺金属络合物作为催化剂的存在下聚合至少一种烯烃的聚合方法：络合物的金属M是周期表第4b，5b或6b族的过渡金属，例如 钒。 本发明还涉及这些金属络合物作为烯烃聚合或低聚催化剂，任选地与金属铝氧烷和类似的催化剂活化剂组合的用途。
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公开(公告)号：US06475947B1
公开(公告)日：2002-11-05
申请号：US09393796
申请日：1999-09-10
申请人： Erik Licht , Helmut G. Alt , M. Bruce Welch , Bryan E. Hauger
发明人： Erik Licht , Helmut G. Alt , M. Bruce Welch , Bryan E. Hauger
IPC分类号： B01J3100
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , Y10S526/943 , C08F4/65927 , C08F2500/03
摘要： A process for producing a new metallocene comprising reacting a first bridged metallocene which has an olefinically unsaturated with about two molar equivalents of an alkali metal alkyl, catalyst systems resulting from the combination of the resulting metallocenes and a cocatalyst, and polymerization processes using such catalyst systems are disclosed.
摘要翻译： 一种制备新的茂金属的方法，包括使具有烯属不饱和的第一桥接金属茂与约2摩尔当量的碱金属烷基反应，由所得金属茂和助催化剂的组合得到的催化剂体系，以及使用这种催化剂体系的聚合方法 被披露。
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公开(公告)号：US07157511B2
公开(公告)日：2007-01-02
申请号：US10719940
申请日：2003-11-21
IPC分类号： C08K5/527
摘要： The whiteness and stability after processing of a polyolefin have been found to be improved upon the addition of a combination of at least one high activity phosphite and at least one hydrolytically stable phosphite.
摘要翻译： 发现在加入至少一种高活性亚磷酸酯和至少一种水解稳定的亚磷酸酯的组合后，聚烯烃加工后的白度和稳定性得到改善。
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