公开(公告)号：US20170198073A1

公开(公告)日：2017-07-13

申请号：US15315588

申请日：2015-06-01

申请人： MARUZEN PETROCHEMICAL CO., LTD.

发明人： Takashi TAKAHASHI ,  Keisuke MATSUSHITA ,  Masaki SUGIYAMA ,  Norihiro YOSHIDA ,  Eiichi IKAWA ,  Takahito MITA ,  Masahiro ENDO

IPC分类号： C08F130/02 ,  C08F8/12

CPC分类号： C08F130/02 ,  C08F2/06 ,  C08F2/38 ,  C08F8/12

摘要： A method for producing poly(dimethyl vinylphosphonate) from a monomer component mainly containing dimethyl vinylphosphonate by anionic polymerization in the presence of an anionic polymerization initiator, the method being characterized in that an aliphatic ether is used as a polymerization solvent, and a method for producing poly(vinylphosphonic acid) characterized in that the poly(dimethyl vinylphosphonate) obtained by the former method is hydrolyzed in the presence of an acid are provided. The methods make it possible to easily produce a poly(dimethyl vinylphosphonate) which has a high molecular weight and in which the molecular weight is controlled, and make it possible to produce a poly(vinylphosphonic acid) which has a high molecular weight and in which the molecular weight is controlled corresponding to the poly(dimethyl vinylphosphonate).

公开(公告)号：US20180179305A1

公开(公告)日：2018-06-28

申请号：US15579301

申请日：2016-06-29

申请人： MARUZEN PETROCHEMICAL CO., LTD.

发明人： Shinji SUGIHARA ,  Norihiro YOSHIDA

IPC分类号： C08F16/26 ,  C08K3/18 ,  C09D11/00 ,  C09D129/10 ,  C09J129/10

CPC分类号： C08F16/26 ,  C08F4/04 ,  C08F116/14 ,  C08K3/18 ,  C09D11/00 ,  C09D129/10 ,  C09J129/10

摘要： A method for producing a hydroxyl group-containing vinyl ether polymer according to the present invention includes: a step of radical polymerizing at least one vinyl ether selected from vinyl ether having a hydroxyl group represented by the following formula (2): wherein R7 represents an alkylene group which is straight-chained, branched or comprises an alicyclic structure, and p is 1, 2, or 3, in the presence of water as a polymerization solvent and an azo compound represented by the following formula (1) as a polymerization initiator: wherein R1 to R4 each independently represent a hydrogen atom or an alkyl group and R5 and R6 each independently represent an alkoxy group optionally having a substituent group or an alkyl amino group optionally having a substituent group.

公开(公告)号：US20180371127A1

公开(公告)日：2018-12-27

申请号：US15780843

申请日：2016-12-14

申请人： MARUZEN PETROCHEMICAL CO., LTD.

发明人： Norihiro YOSHIDA ,  Shinji SUGIHARA

IPC分类号： C08F116/12 ,  C08F2/06 ,  C08F2/16 ,  C08F4/04

摘要： [Object] To provide a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, wherein the vinyl ether polymer having a low viscosity and excellent workability and processability is produced in a simple and efficient method.[Means for solving problem] The present invention relates to a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, characterized in that vinyl ether comprising a hydroxyl group is subjected to radical polymerization by using an oil-soluble azo polymerization initiator, in the presence of a mixed solvent comprising water and an organic solvent selected from alcohol or cyclic ether radical polymerization.

公开(公告)号：US20190091380A1

公开(公告)日：2019-03-28

申请号：US16080563

申请日：2017-01-24

申请人： Maruzen Petrochemical Co., Ltd. ,  National University Corporation Yamagata University

发明人： Masaru TANAKA ,  Norihiro YOSHIDA

IPC分类号： A61L33/06 ,  C08F216/18

摘要： A biocompatible material, which has excellent film formation properties and resistance to water dissolution, and is easily applied on various bases as a coating, while having excellent antithrombotic properties, and to provide an antithrombotic coating agent and an antithrombotic coating film produced by using the biocompatible material, and a medical device provided with the antithrombotic coating film. A copolymer, containing at least one repeating unit (A) represented by formula (1) (wherein, n represents an integer of 2 to 10 and R1 represents a methyl group or an ethyl group), and at least one repeating unit (B) represented by formula (2) (wherein R2 represents an aliphatic hydrocarbon group); an antithrombotic coating agent containing the copolymer and an organic solvent; an antithrombotic coating film formed of the copolymer; and a medical device provided with the coating film.

公开(公告)号：US20160208037A1

公开(公告)日：2016-07-21

申请号：US14914946

申请日：2014-09-02

申请人： MARUZEN PETROCHEMICAL CO., LTD.

发明人： Norihiro YOSHIDA

IPC分类号： C08F261/06

CPC分类号： C08F261/06 ,  C08F2/42 ,  C08F4/14 ,  C08F8/30 ,  C08F116/14 ,  C08F216/125 ,  C08F216/1416 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/50 ,  D06M15/347 ,  D06M2101/32 ,  D06M2200/11 ,  D06M2200/12 ,  C08F216/1458

摘要： Provided are a vinyl ether polymer which can exert temperature responsiveness even in the case of being supported on a highly hydrophobic fibrous substrate, an agent for controlling hydrophilicity and hydrophobicity containing the polymer, a method for controlling hydrophilicity and the hydrophobicity using the polymer, and a polymer-substrate composite having the polymer supported on a substrate.A star-shaped vinyl ether polymer which includes a central core and an arm portion bonded to the central core and in which the arm portion includes a repeating unit derived from a vinyl ether monomer and a structure represented by the following Formula (1) is included in the molecule: —Y—Ar1—N═N—Ar2   (1) in which Y represents an ether bond, a thioether bond, a group —NH—, or a group —OR1—* (R1 represents an alkylene group, * represents a position bonded to Ar1 in Formula (1)), Ar1 represents a substituted or unsubstituted divalent aromatic hydrocarbon group, and Ar2 represents a substituted or unsubstituted monovalent aromatic hydrocarbon group].

摘要翻译： 提供了即使在负载在高度疏水性纤维基材上的情况下也可以发挥温度响应性的乙烯基醚聚合物，用于控制亲水性的试剂和含有聚合物的疏水性，使用该聚合物控制亲水性和疏水性的方法，以及 聚合物 - 基底复合材料，其具有支撑在基底上的聚合物。 一种星形乙烯基醚聚合物，其包括中心芯和结合到中心芯的臂部分，其中臂部分包括衍生自乙烯基醚单体的重复单元和由下式（1）表示的结构的星形乙烯基醚聚合物 在分子中：-Y-Ar1-N = N-Ar2（1）其中Y表示醚键，硫醚键，基团-NH-或基团-OR1- *（R1表示亚烷基，* 表示与式（1）中的Ar 1键合的位置），Ar 1表示取代或未取代的二价芳香族烃基，Ar 2表示取代或未取代的1价芳香族烃基]。