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    Process for the treatment of sulfonyl fluoride polymers
    1.
    发明授权
    Process for the treatment of sulfonyl fluoride polymers 有权
    磺酰氟聚合物的处理方法

    公开(公告)号：US08940846B2

    公开(公告)日：2015-01-27

    申请号：US13704335

    申请日：2011-06-22

    申请人： Luca Merlo ,  Alessandro Veneroni ,  Elvira Pagano ,  Claudio Oldani

    发明人： Luca Merlo ,  Alessandro Veneroni ,  Elvira Pagano ,  Claudio Oldani

    IPC分类号： C08F128/02 ,  C08F228/02

    CPC分类号： C08F116/14 ,  B01D71/32 ,  B01D71/68 ,  C08F128/02 ,  C08F214/182 ,  C08F228/02 ,  C08F261/06 ,  C08J5/18 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1027 ,  H01M2300/0082

    摘要： A process for reducing the amount of soluble polymeric fractions in a sulfonyl fluoride polymer. The process comprises contacting the sulfonyl fluoride polymer with a fluorinated fluid followed by separation of the polymer from the fluid. The fluorinated fluid is selected from hydrofluoroethers and hydrofluoropolyethers. The invention further relates to sulfonyl fluoride polymers obtainable by the process and having a heat of fusion not exceeding 4 J/g and containing less than 15% by weight of polymeric fractions having an average content of monomeric units comprising a sulfonyl functional group exceeding 24 mole %.The sulfonyl fluoride polymers so obtained are particularly suitable for the preparation of ionomeric membranes for use in electrochemical devices.

    摘要翻译： 用于减少磺酰氟聚合物中可溶性聚合物级分的量的方法。 该方法包括使磺酰氟聚合物与氟化流体接触，然后将聚合物与流体分离。 氟化流体选自氢氟醚和氢氟聚醚。 本发明还涉及通过该方法获得的磺化氟化物聚合物，其熔融热不超过4J / g，并且含有少于15％重量的具有包含超过24摩尔的磺酰基官能团的单体单元的平均含量的聚合物部分 ％。 如此获得的磺酰氟聚合物特别适用于制备用于电化学装置的离聚物膜。

    Fluoropolymers having diacrylate ends
    2.
    发明授权
    Fluoropolymers having diacrylate ends 失效
    具有二丙烯酸酯末端的含氟聚合物

    公开(公告)号：US08575300B2

    公开(公告)日：2013-11-05

    申请号：US13676201

    申请日：2012-11-14

    申请人： E I Du Pont De Nemours and Company ,  Le Centre National De La Recherche Scientifique

    发明人： Ming-Hong Hung ,  Bruno Ameduri ,  Georgi Kostov

    IPC分类号： C08G63/78

    CPC分类号： C08F261/06 ,  C08F214/18

    摘要： Disclosed herein is a telechelic diacrylate fluoropolymer and a process for manufacture of the fluoropolymer. The diacrylate copolymer is of formula CH2═CR′COO—(CH2)n—R—(CH2)n—OOCCR′═CH2, wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R′ is H or—CH3, n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons.

    摘要翻译： 本文公开了遥爪二丙烯酸酯含氟聚合物和制造含氟聚合物的方法。 二丙烯酸酯共聚物具有式CH2 = CR'COO-（CH2）nR-（CH2）n-OOCCR'= CH2，其中R选自i）包含偏二氟乙烯和全氟（甲基）丙烯的共聚单元的低聚物 乙烯基醚），ii）包含偏二氟乙烯和六氟丙烯的共聚单元的低聚物，iii）包含四氟乙烯和全氟（甲基乙烯基醚）的共聚单元的低聚物，和iv）包含四氟乙烯和烃烯烃的共聚单元的低聚物，R '是H或-CH 3，n为1-4，并且其中所述低聚物的数均分子量为1000至25,000道尔顿。

    Process of making polymeric hydrogels by reactive extrusion
    3.
    发明申请
    Process of making polymeric hydrogels by reactive extrusion 失效
    通过反应性挤出制备聚合物水凝胶的方法

    公开(公告)号：US20070032597A1

    公开(公告)日：2007-02-08

    申请号：US11545324

    申请日：2006-10-10

    申请人： Krystyna Plochocka ,  Timothy Bee

    发明人： Krystyna Plochocka ,  Timothy Bee

    IPC分类号： C08F8/00

    CPC分类号： C08L73/02 ,  A61L15/585 ,  C08F8/14 ,  C08F261/04 ,  C08F261/06 ,  C08F265/02 ,  C08F283/00 ,  C08F2810/20 ,  C08L71/02 ,  C08L2205/05 ,  C08L35/00 ,  C08L2666/04 ,  C08F222/06

    摘要： What is described is a reactive extrusion process of making a polymeric hydrogel of a polymeric anhydride or acid, e.g. maleic anhydride or maleic acid polymer, or copolymer thereof, crosslinked with a crosslinking agent containing at least 2 crosslinkable groups, particularly, —OH or —NH2, or both. The reaction product is a crosslinked polymeric ester or amide/imide, or both, suitably having a mole ratio of —OH, or —NH2, to —COOH, of 1:10 to 10:1, preferably 2:10 to 7:1. The hydrogel is particularly swellable in water, e.g. >100% in 1 hour in aqueous media; and forms a thin, tacky layer on a substrate, which property is useful in bioadhesive products.

    摘要翻译： 所描述的是制备聚合物酐或酸的聚合物水凝胶的反应挤出方法，例如。 马来酸酐或马来酸聚合物或其共聚物与含有至少2个可交联基团，特别是-OH或-NH 2或两者的交联剂交联。 反应产物是交联的聚合酯或酰胺/酰亚胺，或两者，适当地具有1:10至10:1的-OH或-NH 2，-COOH的摩尔比， 优选为2:10至7:1。 水凝胶在水中特别溶胀，例如 在水介质中1小时内> 100％ 并且在基底上形成薄的粘性层，该性质在生物粘附产品中是有用的。

    Polymeric hydrogels
    5.
    发明授权
    Polymeric hydrogels 失效
    聚合物水凝胶

    公开(公告)号：US06706817B2

    公开(公告)日：2004-03-16

    申请号：US10397900

    申请日：2003-03-26

    申请人： Krystyna Plochocka ,  Jeffrey A. Lynn

    发明人： Krystyna Plochocka ,  Jeffrey A. Lynn

    IPC分类号： C08F800

    CPC分类号： C08L73/02 ,  A61L15/585 ,  C08F261/04 ,  C08F261/06 ,  C08F265/02 ,  C08F283/00 ,  C08L71/02 ,  C08L2205/05 ,  C08L35/00 ,  C08L2666/04

    摘要： What is described is a polymeric hydrogel of a polymeric anhydride or acid, e.g. maleic anhydride or maleic acid polymer, or copolymer thereof, crosslinked with a crosslinking agent containing at least 2 crosslinkable groups, particularly, —OH or —NH2, or both. The reaction product is a crosslinked polymeric ester or amide/imide, or both, suitably having a mole ratio of —OH, or —NH2, to —COOH, of 1:10 to 10:1, preferably 2:10 to 7:1. The hydrogel is particularly swellable in water, e.g. >100% in 1 hour in aqueous media; and forms a thin, tacky layer on a substrate, which property is useful in bioadhesive products.

    摘要翻译： 所描述的是聚合物酐或酸的聚合物水凝胶，例如聚合物。 马来酸酐或马来酸聚合物或其共聚物与含有至少2个可交联基团，特别是-OH或-NH 2或两者的交联剂交联。 反应产物是交联的聚合酯或酰胺/酰亚胺或两者，适当地具有1:10至10:1，优选2:10至7:1的-OH或-NH 2与-COOH的摩尔比 。 水凝胶在水中特别溶胀，例如 在水介质中1小时内> 100％ 并且在基底上形成薄的粘性层，该性质在生物粘附产品中是有用的。

    Process for producing fluorine-containing block copolymer
    6.
    发明授权
    Process for producing fluorine-containing block copolymer 失效
    含氟嵌段共聚物的制造方法

    公开(公告)号：US6160051A

    公开(公告)日：2000-12-12

    申请号：US315771

    申请日：1999-05-20

    申请人： Haruyoshi Tatsu ,  Yasuyoshi Hisamatsu

    发明人： Haruyoshi Tatsu ,  Yasuyoshi Hisamatsu

    IPC分类号： C08F293/00 ,  C08F261/06 ,  C08F283/06

    CPC分类号： C08F261/06 ,  C08F214/22

    摘要： A fluorine-containing copolymer having a solvent resistance and a cold resistance is produced by subjecting vinylidene fluoride and at least one of other fluorine-containing monomers to copolymerization reaction in the presence of a polyfluoropolyether having iodo groups at both terminals, represented by the following formula:I(R)pCF(CF.sub.3)O[CF.sub.2 CF(CF.sub.3)O]mRf[OCF(CF.sub.3)CF.sub.2 ]nOCF(CF.sub.3)(R)pIwherein Rf: perfluoroalkylene group of C.sub.2 -C.sub.6 ; R: alkylene group or polyfluoroalkylene group of C.sub.2 -C.sub.8 ; these alkylene groups may contain an ether bond or may be an alkyleneamide-containing or phenylene diamide-containing group; m+n: 20 or more; and p: 0 or 1. The copolymerization reaction is carried out preferably in the presence of a bromine-containing or iodine-containing monomer compound.

    摘要翻译： 具有耐溶剂性和耐寒性的含氟共聚物通过在具有两端具有碘基的多氟聚醚的存在下，将下列式（1）表示的偏二氟乙烯和其它含氟单体中的至少一种进行共聚反应来制造： ：C（CF 3）O] m R f [OCF（CF 3）CF 2] n OCF（CF 3）（R）p I其中R 1表示C 1 -C 6的全氟亚烷基; R：C2-C8的亚烷基或多氟亚烷基; 这些亚烷基可以含有醚键，也可以是含有亚烷基酰胺或亚苯基二酰胺的基团。 m + n：20以上; 和p：0或1.共聚反应优选在含溴或含碘单体化合物的存在下进行。

    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase
    7.
    发明授权
    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase 失效
    具有改善接枝基质和接枝聚合物相之间的相结合的接枝共聚物

    公开(公告)号：US5384381A

    公开(公告)日：1995-01-24

    申请号：US152740

    申请日：1993-11-15

    申请人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    IPC分类号： C08F291/00 ,  C07C409/38 ,  C08F4/34 ,  C08F261/06 ,  C08F293/00 ,  C08F218/04

    CPC分类号： C08F261/06 ,  C08F293/00

    摘要： Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.9% by weight of one or more comonomers from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and/or vinyl ethers.The graft copolymers are useful as binders in the textile industry as heat stable binders, as adhesives in plasters and as binders in emulsion paints.

    摘要翻译： 具有改进的接枝基质和接枝聚合物之间的相结合的接枝共聚物由以下物质制备：a）接枝聚合物相，其含有一种或多种由具有1至10个碳的醇的（甲基）丙烯酸酯组成的组中的单体 原子，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基卤化物，苯乙烯和苯乙烯衍生物，和b）含有0.01-20重量％的烯属不饱和过氧化合物 其中R 1是化学键或具有1至10个碳原子的直链或支链烷基或具有3至10个碳原子的环烷基，所述通式I或II其中R 1， R2和R3是具有1至4个碳原子的烷基，R4是烷基或具有3-12个碳原子的烷基取代的苯基，R5是具有3-12个碳原子的环烷基，从80到 99.9重量％的一种或多种共聚单体f 由具有1-10个碳原子的（甲基）丙烯酸酯，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基芳族化合物，乙烯基卤化物和/或乙烯基醚构成的组中。 接枝共聚物可用作纺织工业中的粘合剂，作为热稳定粘合剂，作为膏药中的粘合剂和乳液涂料中的粘合剂。

    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase
    8.
    发明授权
    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase 失效
    具有改善接枝基质和接枝聚合物相之间的相结合的接枝共聚物

    公开(公告)号：US5304609A

    公开(公告)日：1994-04-19

    申请号：US967662

    申请日：1993-10-28

    申请人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    IPC分类号： C08F291/00 ,  C07C409/38 ,  C08F4/34 ,  C08F261/06 ,  C08F293/00 ,  C08F263/04

    CPC分类号： C08F261/06 ,  C08F293/00

    摘要： Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.9% by weight of one or more comonomers from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and/or vinyl ethers.The graft copolymers are useful as binders in the textile industry as heat stable binders, as adhesives in plasters and as binders in emulsion paints.

    摘要翻译： 具有改进的接枝基质和接枝聚合物之间的相结合的接枝共聚物由以下物质制备：a）接枝聚合物相，其含有一种或多种由具有1至10个碳的醇的（甲基）丙烯酸酯组成的组中的单体 原子，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基卤化物，苯乙烯和苯乙烯衍生物，和b）含有0.01-20重量％的烯属不饱和过氧化合物 通式I或II（*化学结构*）（I）或（*化学结构*）（II）其中R1是化学键或具有1-10个碳原子的直链或支链烷基链或具有 3〜10个碳原子，R2和R3为碳原子数1〜4的烷基，R4为碳原子数3〜12的烷基或烷基取代苯基，R5为碳原子数为3〜12的环烷基 原子，从80到99.9％ 一种或多种由具有1-10个碳原子的醇的（甲基）丙烯酸酯组成的组中的一种或多种共聚单体的重量，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基芳族化合物，乙烯基卤化物和/或乙烯基 醚类。 接枝共聚物可用作纺织工业中的粘合剂，作为热稳定粘合剂，作为膏药中的粘合剂和乳液涂料中的粘合剂。

    Polymer and process for making the same
    9.
    发明授权
    Polymer and process for making the same 失效
    聚合物和制造相同的方法

    公开(公告)号：US5098958A

    公开(公告)日：1992-03-24

    申请号：US675246

    申请日：1991-03-26

    申请人： Donn DuBois

    发明人： Donn DuBois

    IPC分类号： C08F261/06

    CPC分类号： C08F261/06

    摘要： Vinyl ether copolymers and a method of preparing the same. The vinyl ether is copolymerized with styrene, alkyl-substituted styrenes, alkoxy-substituted styrenes and mixtures thereof. In the process, a cadmium halide is used with hydrogen iodide or a suitable iodine containing electrophile, as the coinitiator.

    摘要翻译： 乙烯基醚共聚物及其制备方法。 乙烯基醚与苯乙烯，烷基取代的苯乙烯，烷氧基取代的苯乙烯及其混合物共聚。 在此过程中，卤化镉与碘化氢或合适的含碘亲电子试剂一起用作共引发剂。