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    METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS
    1.
    发明申请
    METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS 有权
    生产循环碳酸酯合成催化剂的方法

    公开(公告)号：US20160108071A1

    公开(公告)日：2016-04-21

    申请号：US14786455

    申请日：2014-04-22

    申请人： MARUZEN PETROCHEMICAL CO., LTD. ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

    发明人： Masuo YAMAZAKI ,  Takashi NANIKI ,  Toshikazu TAKAHASHI ,  Hiroyuki YASUDA ,  Shouji YAMAMOTO

    IPC分类号： C07F9/54 ,  C07D317/36 ,  C07D317/38 ,  B01J31/02

    CPC分类号： C07F9/5414 ,  B01J21/08 ,  B01J27/08 ,  B01J27/182 ,  B01J31/0268 ,  B01J31/0269 ,  B01J31/0274 ,  B01J31/0275 ,  B01J31/069 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J2231/341 ,  C07D317/36 ,  C07D317/38

    摘要： The present invention provides a method for easily and inexpensively producing a heterogeneous catalyst used to synthesize a cyclic carbonate by reacting an epoxide with carbon dioxide and having excellent catalyst activity; a catalyst obtained using said manufacturing method; and a method for synthesizing a cyclic carbonate using said catalyst.A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b): (a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group by reacting a silane compound with a silica gel in the presence of xylene, the silane compound having a haloalkyl group or a haloaryl group and (b) a step of obtaining a catalyst for synthesizing a cyclic carbonate by reacting the catalyst precursor obtained in step (a) with a tertiary phosphine.

    摘要翻译： 本发明提供了一种用于通过环氧化物与二氧化碳反应并具有优异的催化剂活性而容易且廉价地生产用于合成环状碳酸酯的多相催化剂的方法; 使用所述制造方法获得的催化剂; 以及使用所述催化剂合成环状碳酸酯的方法。 一种制备用于通过使环氧化物与二氧化碳进行反应合成环状碳酸酯的催化剂的方法，所述方法包括以下步骤（a）和（b）：（a）获得 具有卤代烷基或卤代芳基的催化剂前体，其通过在二甲苯存在下使硅烷化合物与硅胶反应，所述硅烷化合物具有卤代烷基或卤代芳基，以及（b）获得用于合成环状 使步骤（a）中获得的催化剂前体与叔膦反应。

    METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS
    2.
    发明申请
    METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS 有权
    生产循环碳酸酯合成催化剂的方法

    公开(公告)号：US20160060242A1

    公开(公告)日：2016-03-03

    申请号：US14786334

    申请日：2014-04-22

    申请人： NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY ,  MARUZEN PETROCHEMICAL CO., LTD.

    发明人： Toshikazu TAKAHASHI ,  Hiroyuki YASUDA ,  Toshiyasu SAKAKURA ,  Shouji YAMAMOTO ,  Takashi NANIKI ,  Takuro FURUKAWA

    IPC分类号： C07D317/38 ,  B01J35/10 ,  C07D317/36 ,  B01J31/02

    CPC分类号： C07D317/38 ,  B01J21/08 ,  B01J27/08 ,  B01J27/182 ,  B01J31/0231 ,  B01J31/0267 ,  B01J31/0268 ,  B01J31/0269 ,  B01J31/0271 ,  B01J31/069 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J2231/341 ,  C07D317/36

    摘要： Provided are: a method for easily producing a heterogeneous catalyst having excellent catalytic activity at a low cost, said heterogeneous catalyst being used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide and carbon dioxide; a catalyst which is obtained by this production method; and a method for synthesizing a cyclic carbonate with use of this catalyst.A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b): (a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group, by subjecting to a reaction a silane compound having a haloalkyl group or a haloaryl group and a silica gel having an average pore diameter of from 3.5 to 50 nm, and (b) a step of obtaining a catalyst for cyclic carbonate synthesis, by subjecting to a reaction the catalyst precursor obtained in step (a) and a tertiary phosphine, in which the molar ratio of the halogen content to the phosphorus content, namely [halogen]/[phosphorus] is from 0.8 to 1.6.

    摘要翻译： 本发明提供一种易于制造低成本催化活性优异的多相催化剂的方法，所述多相催化剂用于通过环氧化物和二氧化碳的反应合成环状碳酸酯; 通过该制造方法得到的催化剂; 以及使用该催化剂合成环状碳酸酯的方法。 一种制备用于通过使环氧化物与二氧化碳进行反应合成环状碳酸酯的催化剂的方法，所述方法包括以下步骤（a）和（b）：（a）获得 具有卤代烷基或卤代芳基的催化剂前体通过使具有卤代烷基或卤代芳基的硅烷化合物和平均孔径为3.5至50nm的硅胶进行反应，和（b）步骤 通过使步骤（a）中得到的催化剂前体与卤素含量与磷含量的摩尔比即[卤素] / [磷]的叔膦反应，得到环状碳酸酯合成催化剂 从0.8到1.6。

    METHOD FOR PRODUCING CYCLIC CARBONATE
    3.
    发明申请
    METHOD FOR PRODUCING CYCLIC CARBONATE 有权
    生产循环碳酸盐的方法

    公开(公告)号：US20160145234A1

    公开(公告)日：2016-05-26

    申请号：US14904488

    申请日：2014-07-18

    申请人： NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY ,  MARUZEN PETROCHEMICAL CO., LTD.

    发明人： Toshikazu TAKAHASHI ,  Hiroyuki YASUDA ,  Shouji YAMAMOTO ,  Takashi NANIKI ,  Yasunori HAYASHI ,  Takeshi HARUNA ,  Takuro FURUKAWA

    IPC分类号： C07D317/38 ,  C07D317/36

    CPC分类号： C07D317/38 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0268 ,  B01J31/0269 ,  B01J2231/341 ,  C07D317/36 ,  Y02P20/142

    摘要： Provided is a method for producing a cyclic carbonate obtained by reacting epoxide and carbon dioxide, the method being capable of efficiently producing a cyclic carbonate at a high conversion rate and a high yield, in which degradation of the catalyst over time is suppressed and catalytic activity hardly decreases.A method for producing a cyclic carbonate by reacting epoxide and carbon dioxide in the presence of a quaternary onium salt selected from the group consisting of a quaternary ammonium salt having a halogenated anion as a counter ion and a quaternary phosphonium salt having a halogenated anion as a counter ion, or in the presence of a solid catalyst obtained by immobilizing the quaternary onium salt onto a carrier, wherein an organohalogen compound containing at least one halogen atom in one molecule is added to the reaction system.

    摘要翻译： 提供一种通过使环氧化物和二氧化碳反应得到的环状碳酸酯的制造方法，其能够以高转化率和高收率有效地制造环状碳酸酯，其中催化剂随时间的劣化被抑制，催化活性 几乎没有减少。 一种环状碳酸酯的制备方法，该方法是在季铵盐存在下，使环氧化物和二氧化碳反应，所述季铵盐选自具有卤化阴离子的季铵盐作为抗衡离子，和具有卤化阴离子的季鏻盐作为 或在通过将季铵盐固定在载体上而获得的固体催化剂的存在下，其中在一个分子中含有至少一个卤素原子的有机卤素化合物加入到反应体系中。

    METHOD FOR CONTINUOUSLY PRODUCING CYCLIC CARBONATE
    5.
    发明申请
    METHOD FOR CONTINUOUSLY PRODUCING CYCLIC CARBONATE 有权
    连续生产循环碳酸盐的方法

    公开(公告)号：US20160168112A1

    公开(公告)日：2016-06-16

    申请号：US14903225

    申请日：2014-07-18

    申请人： MARUZEN PETROCHEMICAL CO., LTD. ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

    发明人： Takashi NANIKI ,  Yasunori HAYASHI ,  Goro SAWADA ,  Takuro FURUKAWA ,  Takeshi HARUNA ,  Toshikazu TAKAHASHI ,  Hiroyuki YASUDA ,  Shouji YAMAMOTO

    IPC分类号： C07D317/38 ,  B01J31/02

    CPC分类号： C07D317/38 ,  B01J27/08 ,  B01J31/0231 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0268 ,  B01J31/0269 ,  B01J31/0271 ,  B01J2231/341 ,  B01J2531/90

    摘要： Provided is a method for continuously producing a cyclic carbonate, by which generation of a glycol in a reaction for synthesizing a cyclic carbonate is suppressed, and a cyclic carbonate having a high purity can be efficiently obtained even by simple purification.A method for continuously producing a cyclic carbonate, including filling a catalyst in a fixed-bed tube reactor, and continuously feeding carbon dioxide and an epoxide to the fixed-bed tube reactor to thereby bringing the carbon dioxide and the epoxide into contact with the catalyst, while continuously withdrawing the reaction liquid in the fixed-bed tube reactor, wherein the method includes a pre-treatment step in which a pre-treatment liquid containing a cyclic carbonate is brought into contact with the catalyst before feeding the carbon dioxide and the epoxide to the fixed-bed tube reactor, and the generated glycol is removed out of the system.

    摘要翻译： 提供一种连续制备环状碳酸酯的方法，通过在环状碳酸酯的合成反应中抑制二醇的生成，即使通过简单的纯化也能够有效地得到高纯度的环状碳酸酯。 一种连续生产环状碳酸酯的方法，包括在固定床管式反应器中填充催化剂，并将二氧化碳和环氧化物连续供给到固定床管式反应器中，从而使二氧化碳和环氧化物与催化剂接触 同时连续地取出固定床管式反应器中的反应液体，其中该方法包括预处理步骤，其中使含有环状碳酸酯的预处理液体在进料二氧化碳和环氧化物之前与催化剂接触 到固定床管式反应器中，并将生成的二醇从系统中除去。

    PRODUCTION METHOD OF CARBAMIC ACID ESTER
    6.
    发明申请
    PRODUCTION METHOD OF CARBAMIC ACID ESTER 审中-公开

    公开(公告)号：US20190185420A1

    公开(公告)日：2019-06-20

    申请号：US16328530

    申请日：2017-08-31

    申请人： NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

    发明人： Jun-Chul CHOI ,  Norihisa FUKAYA ,  Qiao ZHANG ,  Hiroyuki YASUDA

    IPC分类号： C07C269/04

    摘要： A method of production of carbamic acid ester has a high yield and high selectivity and is superior in economy. The method of production of a carbamic acid ester includes reacting an amine, carbon dioxide, and an alkoxysilane compound in the presence of a catalyst containing a zinc compound or an alkali metal compound or in the presence of an ionic liquid. A carbamic acid ester is produced, for example by reacting aniline, carbon dioxide, and tetramethoxysilane at a temperature of 150 to 180° C. in the presence of zinc acetate and 2,2′-bipyridine.