公开(公告)号：US12043573B2

公开(公告)日：2024-07-23

申请号：US17365433

申请日：2021-07-01

Applicant: MATERIA, INC.

Inventor： Li-Sheng Wang ,  Anthony R. Stephen ,  Paul W. Boothe ,  Tessa Schulze ,  Michael A. Giardello ,  Mark S. Trimmer ,  Christopher J. Cruce ,  Farshad J. Motamedi ,  Brian Edgecombe

IPC: C03C25/30 ,  C08F32/02 ,  C08G61/08 ,  C08K5/00 ,  C08K5/14 ,  C08K5/29

CPC classification number: C03C25/30 ,  C08F32/02 ,  C08K5/0025 ,  C08K5/14 ,  C08K5/29 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C08K2201/014 ,  C08K5/14 ,  C08L65/00 ,  C08K5/29 ,  C08L65/00 ,  C08K5/0025 ,  C08L65/00

Abstract: This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyanate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel-modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：US09796889B2

公开(公告)日：2017-10-24

申请号：US14926830

申请日：2015-10-29

Applicant: MATERIA, INC.

Inventor： Michael A. Giardello ,  Christopher M. Haar ,  Brian Edgecombe ,  Anthony R. Stephen ,  Li-Sheng Wang ,  Diana Stoianova

IPC: C09J145/00 ,  C07C265/08 ,  C08F32/08 ,  C08F263/04 ,  C09J4/00 ,  C08G61/08 ,  C09J5/00 ,  C09J165/00

CPC classification number: C09J145/00 ,  C07C265/08 ,  C08F32/08 ,  C08F263/04 ,  C08G61/08 ,  C08G2261/142 ,  C08G2261/144 ,  C08G2261/3324 ,  C08G2261/418 ,  C09J4/00 ,  C09J5/00 ,  C09J165/00

Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

公开(公告)号：US20220089481A1

公开(公告)日：2022-03-24

申请号：US17365433

申请日：2021-07-01

Applicant: MATERIA, INC.

Inventor： Li-Sheng Wang ,  Anthony R. Stephen ,  Paul W. Boothe ,  Tessa Schulze ,  Michael A. Giardello ,  Mark S. Trimmer ,  Christopher J. Cruce ,  Farshad J. Motamedi ,  Brian Edgecombe

IPC: C03C25/30 ,  C08F32/02 ,  C08K5/00 ,  C08K5/14 ,  C08K5/29

Abstract: This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyanate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel-modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.