Abstract:
A non-aqueous electrolyte secondary battery comprises: a positive electrode sheet comprising a positive electrode mixture containing a lithium-containing transition metal oxide as an active material and a particulate binder; a negative electrode sheet comprising a negative electrode mixture containing a carbon material; a separator interposed between the positive electrode sheet and the negative electrode sheet; and a non-aqueous electrolyte containing a lithium salt, wherein the positive electrode sheet and the negative electrode sheet are wound with the separator interposed therebetween to form an electrode assembly, and the positive electrode mixture has an active material density of 3.0 to 4.0 g/ml. The battery has a long life, high energy density and high output.
Abstract:
An electrode for a battery superior in conductivity with small amount of conductive material, yet with high capacity is provided by a method comprising the steps of: (a) producing a masterbatch comprising at least carbon nanotubes and a resin; (b) blending an electrode material mixture containing at least the masterbatch and an electrode active material with a dispersion medium to prepare an electrode material mixture paste; (c) applying the electrode material mixture paste onto an electrode substrate and then drying and rolling the electrode material mixture paste coated on the electrode substrate to obtain an electrode plate; and (d) cutting the electrode plate to obtain an electrode with a predetermined shape.
Abstract:
A non-aqueous electrolyte battery is provided, which exhibits good high-rate discharge characteristics and low-temperature characteristics and ensures high safety when the negative electrode contains 0.6 to 1.7 parts by weight of a particulate modified styrene-butadiene rubber as a binder and 0.7 to 1.2 parts by weight of a thickening agent so that the total amount of the binder and thickening agent is 1.3 to 2.4 parts by weight per 100 parts by weight of a carbon material as an active material, and the concentration of LiPF6 in the non-aqueous electrolyte is 0.6 to 1.05 mole/liter. The surface area of the active material effectively contributable to charging and discharging reaction is sufficient when the surface area of the carbon material per 1 g of the binder contained in the negative electrode is 300 to 600 m2.
Abstract:
A non-aqueous electrolyte battery is provided, which exhibits good high-rate discharge characteristics and low-temperature characteristics and ensures high safety when the negative electrode contains 0.6 to 1.7 parts by weight of a particulate modified styrene-butadiene rubber as a binder and 0.7 to 1.2 parts by weight of a thickening agent so that the total amount of the binder and thickening agent is 1.3 to 2.4 parts by weight per 100 parts by weight of a carbon material as an active material, and the concentration of LiPF6 in the non-aqueous electrolyte is 0.6 to 1.05 mole/liter. The surface area of the active material effectively contributable to charging and discharging reaction is sufficient when the surface area of the carbon material per 1 g of the binder contained in the negative electrode is 300 to 600 m2.
Abstract:
Disclosed is a positive electrode for a non-aqueous electrolyte secondary battery, comprising: a positive electrode mixture layer; and a positive electrode current collector which carries the positive electrode mixture layer, with the positive electrode mixture layer comprising: at least one positive electrode active material; at least one conductive agent; at least one binder; and at least one thickening agent, and the thickening agent comprising a polymer containing at least one acrylonitrile unit and at least one null(CH2)nnull structure portion where 6nulln.
Abstract:
A method for producing a non-aqueous electrolyte secondary battery comprising the steps of: (i) mixing a positive electrode active material, a first binder A and a dispersion medium to prepare a paste A, the active material comprising a lithium-containing transition metal oxide; (ii) mixing a conductive agent, a second binder B and a dispersion medium to prepare a paste B, the conductive agent comprising carbon black; (iii) mixing the paste A and the paste B to prepare a positive electrode material paste C; (iv) applying the positive electrode material paste C onto a positive electrode core member and rolling and drying the resultant member to prepare a positive electrode; and (v) fabricating a battery using the positive electrode, a negative electrode and a non-aqueous electrolyte, wherein contact angle nullA between the non-aqueous electrolyte and the binder A and contact angle nullB between the non-aqueous electrolyte and the binder B satisfy the formula (1): nullBnullnullAnull15null.