公开(公告)号：US10202227B2

公开(公告)日：2019-02-12

申请号：US15665810

申请日：2017-08-01

Applicant: MONOSOL, LLC

Inventor： Shinsuke Nii ,  Nathanael R. Miranda

IPC: B65D65/46 ,  B65D75/40 ,  C02F1/68 ,  C02F1/76 ,  C08J5/18 ,  C08K5/00 ,  C08K5/053 ,  C02F103/42

Abstract: Disclosed herein are water-soluble films comprising a mixture of a water-soluble polyvinyl alcohol copolymer including an anionic monomer having a pendant carboxyl group, and a plasticizer blend comprising a first plasticizer comprising sorbitol and a secondary plasticizer selected from the group consisting of glycerol, trimethylolpropane, diglycerol, glycerol propylene oxide polymers, glycerol diacetate, 2-methyl-1,3-propanediol and a combination thereof, wherein (i) when the total plasticizer in the film is less than 12 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer; (ii) when the total plasticizer in the film is at least 12 PHR and less than 20 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer selected from diglycerol, trimethylolpropane and a combination thereof; and (iii) when the total plasticizer in the film is 20 PHR or greater, then sorbitol comprises at least ⅓ of the total plasticizer.

公开(公告)号：US20170218146A1

公开(公告)日：2017-08-03

申请号：US15418318

申请日：2017-01-27

Applicant: MONOSOL, LLC

Inventor： Jennifer L. Childers ,  David M. Lee ,  Nathanael R. Miranda

IPC: C08J5/18 ,  C08L31/04 ,  C08L29/04 ,  B65D65/38 ,  C08K5/053 ,  B29C51/00 ,  B29C51/10 ,  C08K5/00 ,  C08L33/08

CPC classification number: C08J5/18 ,  B29C51/002 ,  B29C51/10 ,  B29K2029/04 ,  B29K2031/04 ,  B29K2995/0062 ,  B29L2031/7128 ,  B65D65/38 ,  C08J2300/14 ,  C08J2329/04 ,  C08J2331/04 ,  C08J2429/04 ,  C08J2433/08 ,  C08K5/0016 ,  C08K5/053 ,  C08L29/04 ,  C08L31/04 ,  C08L33/08 ,  C08L2203/16 ,  C08L2203/30 ,  C11D17/042 ,  C11D17/045

Abstract: The disclosure provides a water soluble film suitable for thermoforming deep-drawn profiles, the film including a mixture of a water soluble polyvinyl alcohol (PVOH) resin and a plasticizer, and the film being characterized by a storage modulus at 90° C. less than 1.5×108. The disclosure further provides a thermoformed article comprising the water soluble film according to the disclosure.

公开(公告)号：US20180029763A1

公开(公告)日：2018-02-01

申请号：US15665810

申请日：2017-08-01

Applicant: MONOSOL, LLC

Inventor： Shinsuke Nii ,  Nathanael R. Miranda

IPC: B65D65/46 ,  C02F1/76 ,  C02F1/68 ,  C08J5/18 ,  B65D75/40

CPC classification number: B65D65/46 ,  B65D75/40 ,  C02F1/687 ,  C02F1/76 ,  C02F2103/42 ,  C08J5/18 ,  C08J2329/04 ,  C08K5/0016 ,  C08K5/053 ,  C08L29/04

Abstract: Disclosed herein are water-soluble films comprising a mixture of a water-soluble polyvinyl alcohol copolymer including an anionic monomer having a pendant carboxyl group, and a plasticizer blend comprising a first plasticizer comprising sorbitol and a secondary plasticizer selected from the group consisting of glycerol, trimethylolpropane, diglycerol, glycerol propylene oxide polymers, glycerol diacetate, 2-methyl-1,3-propanediol and a combination thereof, wherein (i) when the total plasticizer in the film is less than 12 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer; (ii) when the total plasticizer in the film is at least 12 PHR and less than 20 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer selected from diglycerol, trimethylolpropane and a combination thereof; and (iii) when the total plasticizer in the film is 20 PHR or greater, then sorbitol comprises at least ⅓ of the total plasticizer.